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461.
Steam distilled oils of some species of the genus Citrus and Cymbopogon citratus were analyzed by GC-MS. It is observed that citral b was the most common constituent of the oils, which could be a good inhibitor of beta-glucuronidase as all the tested essential oils showed significant inhibition of beta-glucuronidase. IC50 values of a mixture of citral a and b also proved the hypothesis. The same oils also exhibited positive response against tested microbes. 相似文献
462.
463.
The densities, ρ, and ultrasonic speeds, u, have been measured in the binary liquid mixtures of acetonitrile (ACN) with 1‐hexanol, 1‐octanol and 1‐decanol, and in the pure components, as a function of composition at 25, 30, 35, 40 and 45 °C. The deviations in isentropic compressibility, Δκs, excess molar volume, VE, deviations in ultrasonic speed, Δu, apparent molar compressibility, K?2, apparent molar volume, V?2, partial molar compressibility, $ {\rm \bar K}^\circ _{\phi,2} $, and partial molar volume, $ {\rm \bar V}^\circ _2 $, of 1‐alkanols in ACN have been calculated from the experimental data of densities and ultrasonic speeds. The variations of these parameters with composition of the mixtures indicate that the structure‐breaking effect dominates over that of the hydrogen‐bonding effect between unlike molecules, suggesting that ACN‐alkanol interaction is weaker than ACN‐ACN and alkanol‐alkanol interactions, and that the interaction (ACN‐alkanol) follows the order: 1‐hexanol > 1‐octanol > 1‐decanol. The excess molar volume data have been analysed by using Flory and Prigogine‐Flory‐Patterson theories. Further, the ultrasonic speeds in these mixtures were theoretically calculated with the help of several theories and empirical relations using the pure component data. The validity and relative merits of these theories and relations have been discussed. 相似文献
464.
In this paper free acid and uranium present together in the range of 0.05–3.0 meq and 20–250 mg, respectively, have been determined by potentiometric titration, using Na2SO4 and (NH4)2SO4 complexants and NaOH and Na2CO3 as titrants. The results are presented as percentage recovery of free acidity and uranium over the range studied. It has been shown that percentage recovery of free acidity suggests a bias which varied from –5% to +74% at different free acidity and uranium concentrations for the Na2SO4–NaOH, Na2SO4–Na2CO3 and (NH4)2SO4–NaOH complexant — titrant combinations. The percentage recovery of uranium always showed a positive bias which could be up to +8% for extreme free acidity — uranium ratios in the case of Na2SO4–Na2CO3 complexant — titrant combination. For the other Na2SO4–NaOH and (NH4)2SO4–NaOH complexant — titrant combinations a positive bias of up to only +4% has been noticed. 相似文献
465.
Suchada Chantrapromma Anwar Usman Hoong‐Kun Fun 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(11):m534-m536
The molecule of the title compound {systematic name: di‐μ‐sulfido‐bis[diaqua(1,4,7,10,13,16‐hexaoxacyclooctadecane‐κ6O)barium(II)] bis[1,2‐benzisothiazol‐3(2H)‐one 1,1‐dioxide]}, [Ba2S2(C12H24O6)2(H2O)4](C7H5NO3S)2, lies on an inversion centre. The BaII atom encapsulated by the 18‐crown‐6 ring is coordinated by the six O atoms of the crown, two water O atoms and two bridging S atoms. The four‐membered ring composed of the BaII atoms and the bridging S atoms makes a dihedral angle of 67.1 (1)° with the crown‐ether ring. The aromatic ring system of the saccharin moiety is essentially planar. The packing is built up from layers of the molecules and is stabilized by three intermolecular O—H?O hydrogen bonds. 相似文献
466.
We show that Stanley's conjecture holds for a polynomial ring over a field in four variables. In the case of polynomial ring in five variables, we prove that the monomial ideals with all associated primes of height two, are Stanley ideals. 相似文献
467.
Surat Laphookhieo Chatchanok Karalai Suchada Chantrapromma Hoong-Kun Fun Anwar Usman Yanisa Rat-a-pa Kan Chantrapromma 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(11):1352-1353
The molecule of the title compound, methyl 1-formyl-6-oxa-6H-indene-4-carboxylate, C11H8O4, is planar. There are weak C—H⋯O intramolecular interactions and an intermolecular hydrogen bond in the structure, and these influence the crystal packing. 相似文献
468.
Shahid Anwar 《Journal of solid state chemistry》2008,181(5):997-1004
The structural variants and their coexistence across the antiferroelectric phase transition in Sr0.60Ca0.40TiO3 ceramic has been studied through transmission electron microscopy (TEM) at room temperature and ∼100 °C. A clear evidence of the presence of superlattice reflections, corresponding to the cell doubling along the c-axis of Pbnm (or b-axis along Pnma), occurring during paraelectric to antiferroelectric transition, has been obtained through selected area electron diffraction, convergent beam electron diffraction and lattice-resolution imaging. Coexistence of the Pbnm and Pbcm phases at room temperature has been observed and attributed to the strain/disorder-induced broadening of the first-order antiferroelectric phase transition. Drastic changes in the domain structure during Pbnm to Pbcm transformation have been observed. This clearly indicates that the antiferrodistortive transition responsible for the occurrence of the antiferroelectric phase is of completely different origin and it is not just an additional follow-up of the already-existing ordering due to a−a−c+ tilt schemes in the Pbnm domain. Thermal cycling studies on microstructural changes indicate some kind of memory mechanism, which retains the memory of the original a−a−c+ tilt schemes in the Pbnm phase. This has been attributed to the symmetry conforming short-range order (SC-SRO) of the point defects. 相似文献
469.
Murtaza Saleem Saadat A. Siddiqi Shahid Atiq M. Sabieh Anwar Saira Riaz 《化学物理学报(中文版)》2010,23(4):469-472
Mn doped ZnO nano-crystallites were synthesized by state of the art sol-gel derived auto-combustion technique. As-burnt powder was investigated with different characterization techniques to explore the properties of Mn doped ZnO dilute magnetic semiconductor. X-ray diffraction measurements indicate that Mn doped ZnO retain wurtzite type hexagonal crystal structure like ZnO. Compositional and morphological studies were carried out by energy dispersive X-ray analysis and scanning electron microscopy, respectively. Tempera-ture dependent resistivity of the sample exhibited the semiconducting behavior of the DMS material. Room temperature magnetic properties determined by vibrating sample magne-tometer, revealed the presence of ferromagnetic and diamagnetic contributions in Mn doped ZnO. 相似文献
470.
We study theoretically and computationally the incompressible, non-conducting, micropolar, biomagnetic (blood) flow and heat
transfer through a two-dimensional square porous medium in an (x,y) coordinate system, bound by impermeable walls. The magnetic field acting on the fluid is generated by an electrical current
flowing normal to the x–y plane, at a distance l beneath the base side of the square. The flow regime is affected by the magnetization B
0 and a linear relation is used to define the relationship between magnetization and magnetic field intensity. The steady governing
equations for x-direction translational (linear) momentum, y-direction translational (linear) momentum, angular momentum (micro-rotation) and energy (heat) conservation are presented.
The energy equation incorporates a special term designating the thermal power per unit volume due to the magnetocaloric effect.
The governing equations are non-dimensionalized into a dimensionless (ξ,η) coordinate system using a set of similarity transformations. The resulting two point boundary value problem is shown to
be represented by five dependent non-dimensional variables, f
ξ
(velocity), f
η
(velocity), g (micro-rotation), E (magnetic field intensity) and θ (temperature) with appropriate boundary conditions at the walls. The thermophysical parameters controlling the flow are the
micropolar parameter (R), biomagnetic parameter (N
H
), Darcy number (Da), Forchheimer (Fs), magnetic field strength parameter (Mn), Eckert number (Ec) and Prandtl number (Pr). Numerical solutions are obtained using the finite element method and also the finite difference method for Ec=2.476×10−6 and Prandtl number Pr=20, which represent realistic biomagnetic hemodynamic and heat transfer scenarios. Temperatures are shown to be considerably
increased with Mn values but depressed by a rise in biomagnetic parameter (N
H
) and also a rise in micropolarity (R). Translational velocity components are found to decrease substantially with micropolarity (R), a trend consistent with Newtonian blood flows. Micro-rotation values are shown to increase considerably with a rise in
R values but are reduced with a rise in biomagnetic parameter (N
H
). Both translational velocities are boosted with a rise in Darcy number as is micro-rotation. Forchheimer number is also
shown to decrease translational velocities but increase micro-rotation. Excellent agreement is demonstrated between both numerical
solutions. The mathematical model finds applications in blood flow control devices, hemodynamics in porous biomaterials and
also biomagnetic flows in highly perfused skeletal tissue.
Dedicated to Professor Y.C. Fung (1919-), Emeritus Professor of Biomechanics, Bioengineering Department, University of California
at San Diego, USA for his seminal contributions to biomechanics and physiological fluid mechanics over four decades and his
excellent encouragement to the authors, in particular OAB, with computational biofluid dynamics research. 相似文献