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901.
Preparative-grade bonded β- and γ-cyclodextrin stationary phases were used as the packing material of liquid chromato-graphic analytical microcolumns. Although the resulting columns are characterized by relatively low efficiency, the high selectivity of the cyclodextrin phases nevertheless allows their successful use for the separation of different classes of isomeric compounds that are difficult to resolve on conventional LC stationary phases. Examples of baseline (or almost baseline) separations of a number of isomeric compounds, including isomeric polycyclic aromatic hydrocarbons, are presented to demonstrate the analytical potential of such columns. Retention behavior of the separated isomers is discussed based on the structure of the solute molecule and the possibility of its inclusion into the molecular cavity of cyclodextrin stationary phases. 相似文献
902.
S. M. Abdul Karim Ryoji Nomura Hirotake Kajii Rahmat Hidayat Katsumi Yoshino Toshio Masuda 《Journal of polymer science. Part A, Polymer chemistry》2000,38(Z1):4717-4723
The metathesis polymerization of an anthrylacetylene bearing an alkyl ester group, 9‐(10‐hexoxycarbonyl)anthrylacetylene ( 1 ), was conducted with various transition‐metal catalysts. A completely soluble black polymer was obtained from 1 in a good yield when W‐based catalysts were employed. The polymerization at a high monomer concentration (1 M) and a high temperature (80 °C) led to the formation of poly( 1 ) with a weight‐average molecular weight of 297 × 103 in an 80% yield. The use of cocatalysts unexpectedly decreased both the yield and molecular weight of poly( 1 ). Rh‐catalyzed and Mo‐catalyzed polymerizations, however, resulted in poor yields of the polymer. The ultraviolet–visible spectrum of poly( 1 ) showed a significantly redshifted absorption (λmax = 571) with a cutoff at 780 nm, which verified the very high order of conjugation of the main chain. Poly( 1 ) exhibited the largest third‐order nonlinear optical susceptibility [χ(3) (−ω; ω, 0, 0) = − 1.9 × 10−10 esu] among the polymers from the monosubstituted polyacetylenes synthesized so far. The electrical conductivity of poly( 1 ) in an I2‐doped state was 8.77 × 10−4 at 293 K. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 4717–4723, 2000 相似文献
903.
Effect of diluent and reaction parameter on selective oxidation of propane over MoVTeNb catalyst using nanoflow catalytic reactor 下载免费PDF全文
The selective oxidation of propane to acrylic acid over an MoVTeNb mixed oxide catalyst, dried and calcined before reaction has been studied using high-throughput instrumentation, which is called nanoflow catalytic reactor. The effects of catalyst dilution on the catalytic performance of the MoVTeNb mixed oxide catalyst in selective oxidation of propane to acrylic acid were also investigated. The effects of some reaction parameters, such as gas hourly space velocity (GHSV) and reaction temperature, for selective oxidation of propane to acrylic acid over diluted MoVTeNb catalyst have also been studied. The configuration of the nanoflow is shown to be suitable for screen catalytic performance, and its operating conditions were mimicked closely to conventional laboratory as well as to industrial conditions. The results obtained provided very good reproducibility and it showed that preparation methods as well as reaction parameters can play significant roles in catalytic performance of these catalysts. 相似文献
904.
Vaiyazhipalayam Murugaiyan Sivakumar Abdul Rahman Mohamed Ahmad Zuhairi Abdullah Siang-Piao Chai 《Chemical Papers》2010,64(6):799-805
In our experimental work on carbon nanotubes synthesis, the influence of pre-treatment and reaction temperature conditions
over Fe catalyst loaded on low-cost activated carbon (AC) in the catalytic chemical vapor deposition of methane was studied.
Catalyst with the metal concentration of 5 mass % calcined at 350°C and reduced at 450°C was effective in CH4 decomposition giving 98 % conversions. TEM images showed that thin multi-walled carbon nanotubes (MWNTs) with the average
internal diameter of ∼ 8 nm and the wall thickness of ∼ 2.5 nm were obtained over unreduced Fe/AC catalyst at the reaction
temperature of 850°C. On the other hand, broader filamentous nanostructures with the diameter of ∼ 22 nm and the wall thickness
of ∼ 3.72 nm were observed over reduced catalyst. 相似文献
905.
As a contribution to the development of novel vanadium complexes with pharmacologically interesting properties, two neutral dioxovanadium(V) complexes [VO2(Hpydx-sbdt)] (1) and [VO2(Hpydx-smdt)] (3) [H2pydx-sbdt (I) and H2pydx-smdt (II) are the Schiff bases derived from pyridoxal and S-benzyl- or S-methyldithiocarbazate] have been synthesized by the reaction of [VO(acac)2] and the potassium salts of the ligands in methanol followed by aerial oxidation. Heating of the methanolic solutions of these complexes yields the oxo-bridged binuclear complexes [{VO(pydx-sbdt)}2mu-O] (2) and [{VO(pydx-smdt)}2mu-O] (4). The crystals and molecular structures of 1, 3 x 1.5H2O, and 4 x 2CH3OH have been determined, confirming the ONS binding mode of the dianionic ligands in their thioenolate form. The ring nitrogen of the pyridoxal moiety is protonated in complexes 1 and 3. Acidification of 1 and 3 with HCl dissolved in methanol afforded oxohydroxo complexes, while in a methanolic KOH solution, the corresponding dioxo species K[VO2(pydx-sbdt/smdt)] are formed. Treatment of 1 and 3 with H2O2 yields (unstable) oxoperoxovanadium(V) complexes, the formation of which has been established spectrophotometrically. In vitro antiamoebic activities (against HM1:1MSS strain of Entamoeba histolytica) were established for all of the dioxo- and oxovanadium(V) complexes. The complexes 1, 2, and 4 were more effective than metronidazole, a commonly used drug against amoebiasis, suggesting that oxovanadium(V) complexes derived from thiohydrazones may open a new dimension in the therapy of amoebiasis. 相似文献
906.
We explore the quantum dynamical behavior of the Morse oscillator in the phase space using the Wigner function. For an initial wave packet excited with Gaussian probability distribution, we calculate the associated Wigner function and compute its time evolution. By calculating the marginal probabilities, we study the formation of quantum carpets both in the position space and in the momentum space. In addition, in view of these probabilities, we present the time evolution of the position and momentum expectation values. The structure of quantum carpets and the time-evolved expectation values mimic the emergence of quantum revivals and fractional revivals. 相似文献
907.
In this paper we prove someL
P inequalities for polynomials, wherep is any positive number. They are related to earlier inequalities due to A Zygmund, N G De Bruijn, V V Arestov, etc. A generalization
of a polynomial inequality concerning self-inversive polynomials, is also obtained. 相似文献
908.
Journal of Nanoparticle Research - Highly sensitive low-cost non-enzymatic glucose sensor of copper oxide (CuO) nanorods (NRs) was successfully fabricated using a two-step anodization method with... 相似文献
909.
Alharbi F. F. Nisa Mehar Un Hassan Hassan Mohamed Ahmed Manzoor Sumaira Ahmad Zahoor Abid Abdul Ghafoor Aman Salma Ashiq Muhammad Naeem El-Nasser Karam S. Taha Taha Abdel Mohaymen 《Journal of Solid State Electrochemistry》2022,26(10):2171-2182
Journal of Solid State Electrochemistry - Metal sulfide and oxides have drawn interest as economical substitutes to noble metal catalysts due to their ability for oxygen evolution reaction (OER)... 相似文献
910.
Khan Ihtisham Wali Naeem Abdul Farooq Muhammad Mahmood Tahira Saeed Tooba Parveen Fouzia Malik Tabassum 《Catalysis Surveys from Asia》2022,26(3):144-160
Catalysis Surveys from Asia - The over-consumption of petroleum fuel due to the progressive increase in population, transportation, industrialization, modernization as well as improvement in the... 相似文献