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排序方式: 共有125条查询结果,搜索用时 31 毫秒
61.
Hikov T Schroeter MK Khodeir L Chemseddine A Muhler M Fischer RA 《Physical chemistry chemical physics : PCCP》2006,8(13):1550-1555
A novel, non-aqueous, organometallic route to nanocomposite Cu@TiO2 materials is presented. TiO2 nanorods stabilized with oleic acid (OLA) were used as support for the photo-assisted deposition of Cu using the organometallic Cu(II) precursor [Cu(OCH(CH3)CH2N(CH3)2)2] (1). The copper precursor penetrates through the shell of OLA and is photo reduced to deposit Cu0 directly at the surface of the TiO2 rods. The obtained Cu decorated nanorods were still soluble in nonpolar organic solvents without change of the morphology of nanorods. The Cu@TiO2 colloid was characterized by means of UV-VIS, XRD, AAS, and HRTEM. FTIR CO adsorption studies provide evidence for Cu0 anchored at the titania surface by a characteristic absorption at 2084 cm-1. Comparative studies of Cu-deposition were performed using CuCl2 as simple Cu source which proved that the concept of organometallic disguise of the metal centre results in a higher reaction rate and the circumvention of non-selective reduction, parasitic side reactions and undesired agglomeration of the OLA stabilized titania nanorods. 相似文献
62.
Bouabdallah I M'Barek LA Zyad A Ramdani A Zidane I Melhaoui A 《Natural product research》2006,20(11):1024-1030
The evaluation of the cytotoxic properties in vitro of three synthetic tripods containing pyrazole: N,N-bis[(3,5-dimethylpyrazol-1-yl)methyl]aniline (1); N,N-tetrakis[(3,5-dimethylpyrazol-1-yl)methyl]-para-phenylenediamine (2); and N,N-tetrakis-[(1,5-dimethylpyrazol-3-yl)methyl]-para-phenylenediamine (3), was examined for their cytotoxic activity on two tumor cell lines: P815 (murin mastocytoma) and Hep (human laryngeal carcinome). While the compound 2 shows a small cytotoxic activity, compounds 1 and 3 are more cytotoxic against both cell lines. However, this cytotoxicity is more pronounced against Hep cell line (IC50: 3.25 microg mL(-1) for compound 1 and 6.92 microg mL(-1) for compound 3) than P815 cell line (IC50: 17.82 microg mL(-1) for compound 1 and 37.21 microg mL(-1) for compound 3). Statistical analysis shows that the compound 1 is two- to threefold more cytotoxic than compound 3 (P < 0.05). Interestingly, the cytotoxicity induced by compound 1 against Hep cell line is more important than that induced by adriamycin used as a positive control. 相似文献
63.
Oleochemical‐Tethered SBA‐15‐Type Silicates with Tunable Nanoscopic Order,Carboxylic Surface,and Hydrophobic Framework: Cellular Toxicity,Hemolysis, and Antibacterial Activity 下载免费PDF全文
Dr. Elżbieta Pędziwiatr‐Werbicka Dr. Katarzyna Miłowska M. Sc. Marta Podlas M. Sc. Monika Marcinkowska Małgorzata Ferenc M. Sc. Younes Brahmi Dr. Nadia Katir Dr. Jean‐Pierre Majoral Dr. Aleksandra Felczak Aleksandra Boruszewska Dr. Katarzyna Lisowska Dr. Maria Bryszewska Dr. Abdelkrim El Kadib 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(31):9596-9606
Novel silicates were prepared by using silylated natural fatty acids (derived from triglyceride renewable oils) as co‐condensing reagents in presence of tetraethyl orthosilicate (TEOS) and the triblock copolymer, pluronic P123, as a structure directing agent. A series of carboxylic acid functionalized SBA‐15‐type mesoporous silicates were obtained with tunable nanoscopic order and reactive functional groups that allow the conjugation of amino probes by peptide coupling. Photophysical studies of the covalently linked aminopyrene substantiated that the internal framework of these materials have pronounced hydrophobicity. Moreover, phase separation that can emanate from the bulkiness of the starting fatty silanes has been ruled out owing to the absence of excimers after aminopyrene grafting. The hemotoxicity, cytotoxicity, and antimicrobial activity of these novel silicates were then evaluated. Without discrimination, the functionalized silicates show a significant decrease of red blood cell hemolysis as compared to bare SBA‐15‐silica material. Within the modified silicate series, germanium‐free mesoporous silicates induce only a slight decrease in cell viability and, more interestingly, they exhibit negligible hemolytic effect. Moreover, increasing their concentration in the medium reduces the concentration of released hemoglobin as a result of Hb adsorption. Promising antimicrobial properties were also observed for these silicates with a slight dependency on whether phenylgermanium fragments were present within the silicate framework. 相似文献
64.
The condensation of a series of arylacetonitriles with aldehydes can be carried out by mixing equivalent amounts of reagents with neat powdered KOH at room temperature for 3-60 min depending on the aldehyde steric hindrance. At higher temperature (110 °C), yields were generally higher and purity increased within very short reaction times (1-5 min). With pentamethylphenylacetonitrile, a phase transfer agent was necessary to give a satisfactory yield. 相似文献
65.
66.
This study deals with the performance of projective interior point methods for linear semidefinite program. We propose a modification in the initialization phases of the method in order to reduce the computation time.This purpose is confirmed by numerical experiments showing the efficiency which are presented in the last section of the paper. 相似文献
67.
MOUSSAOUI Abdelkrim KHODJA Brahim 《偏微分方程(英文版)》2009,22(2):111-126
In this paper, we study the existence of nontrivial solutions for the problem
{-△u=f(x,u,v)+h1(x)in Ω
-△v=g(x,u,v)+h2(x)inΩ
u=v=0 onδΩ
where Ω is bounded domain in R^N and h1,h2 ∈ L^2 (Ω). The existence result is obtained by using the Leray-Schauder degree under the following condition on the nonlinearities f and g:
{lim s,|t|→+∞f(x,s,t)/s=lim |s|,t→+∞g(x,s,t)/t=λ+1 uniformly on Ω,
lim -s,|t|→+∞f(x,s,t)/s=lim |s|,-t→+∞g(x,s,t)/t=λ-,uniformly on Ω,
where λ+,λ-∈(0)∪σ(-△),σ(-△)denote the spectrum of -△. The cases (i) where λ+ = λ_ and (ii) where λ+≠λ_ such that the closed interval with endpoints λ+,λ_ contains at most one simple eigenvatue of -△ are considered. 相似文献
{-△u=f(x,u,v)+h1(x)in Ω
-△v=g(x,u,v)+h2(x)inΩ
u=v=0 onδΩ
where Ω is bounded domain in R^N and h1,h2 ∈ L^2 (Ω). The existence result is obtained by using the Leray-Schauder degree under the following condition on the nonlinearities f and g:
{lim s,|t|→+∞f(x,s,t)/s=lim |s|,t→+∞g(x,s,t)/t=λ+1 uniformly on Ω,
lim -s,|t|→+∞f(x,s,t)/s=lim |s|,-t→+∞g(x,s,t)/t=λ-,uniformly on Ω,
where λ+,λ-∈(0)∪σ(-△),σ(-△)denote the spectrum of -△. The cases (i) where λ+ = λ_ and (ii) where λ+≠λ_ such that the closed interval with endpoints λ+,λ_ contains at most one simple eigenvatue of -△ are considered. 相似文献
68.
In this paper, we study the existence of positive smooth solutions for a class of singular (p(x), q(x))-Laplacian systems using sub and supersolution methods. 相似文献
69.
Moulai Sarah Ghezini Rachid Hasnaoui Abdelkrim Bengueddach Abdelkader Weidler Peter G. 《Research on Chemical Intermediates》2019,45(3):1653-1668
Research on Chemical Intermediates - This work deals with the preparation of MAPO-5 zeolite by a hydrothermal method. In order to study the adsorption properties of this zeolite several transition... 相似文献
70.