Studies on the inhibitive effect of potassium ferrocyanide on the corrosion of steel in phosphoric acid

In this work, the effect of potassium ferrocyanide (Pf) on the corrosion of mild steel in solutions of phosphoric acid (H₃PO₄) has been investigated in relation to the concentration of the inhibitor by weight loss, potentiodynamic polarization and AC impedance (EIS) measurements. The results obtained revealed that this compound is good a mixed-type inhibitor. The effect of temperature on the corrosion behavior with the addition of optimal concentration of Pf was studied in the temperature range 298–328 K. The value of inhibition efficiency decreases slightly with the increase in temperature. Changes in impedance parameters (charge transfer resistance, R _t, and double layer capacitance, C _dl) were indicative of adsorption of Pf on the metal surface, leading to the formation of a protective film. Adsorption of Pf on the C38 steel surface was found to obey the Langmuir adsorption isotherm. Some thermodynamic functions of dissolution and adsorption processes were also determined.     

Sur un problème de capitulation du corps ℚ\sqrt {p_1 p_2 } , i dont le 2-groupe de classes est élémentaire

Let p ₁ ≡ p ₂ ≡ 1 (mod 8) be primes such that \(\left( {\tfrac{{p_1 }} {{p_2 }}} \right) = - 1\) and \(\left( {\tfrac{2} {{a + b}}} \right) = - 1\) , where p ₁ p ₂ = a ²+b ². Let \(i = \sqrt { - 1} \) , d = p ₁ p ₂, \(\Bbbk = \mathbb{Q}(\sqrt {d,} i),\Bbbk _2^{(1)} \) be the Hilbert 2-class field and \(\Bbbk ^{(*)} = \mathbb{Q}(\sqrt {p_1 } ,\sqrt {p_2 } ,i)\) be the genus field of \(\Bbbk \) . The 2-part \(C_{\Bbbk ,2} \) of the class group of \(\Bbbk \) is of type (2, 2, 2), so \(\Bbbk _2^{(1)} \) contains seven unramified quadratic extensions \(\mathbb{K}_j /\Bbbk \) and seven unramified biquadratic extensions \(\mathbb{L}_j /\Bbbk \) . Our goal is to determine the fourteen extensions, the group \(C_{\Bbbk ,2} \) and to study the capitulation problem of the 2-classes of \(\Bbbk \) .     

The \bar{\partial }-Equation on an Annulus Between Two Strictly q-Convex Domains with Smooth Boundaries

In this paper, we study the global boundary regularity of the \(\bar{\partial }\) - equation on an annulus domain \(\Omega \) between two strictly \(q\) -convex domains with smooth boundaries in \(\mathbb{C }^n\) for some bidegree. To this finish, we first show that the \(\bar{\partial }\) -operator has closed range on \(L^{2}_{r, s}(\Omega )\) and the \(\bar{\partial }\) -Neumann operator exists and is compact on \(L^{2}_{r,s}(\Omega )\) for all \(r\ge 0\) , \(q\le s\le n-q- 1\) . We also prove that the \(\bar{\partial }\) -Neumann operator and the Bergman projection operator are continuous on the Sobolev space \(W^{k}_{r,s}(\Omega )\) , \(k\ge 0\) , \(r\ge 0\) , and \(q\le s\le n-q-1\) . Consequently, the \(L^{2}\) -existence theorem for the \(\bar{\partial }\) -equation on such domain is established. As an application, we obtain a global solution for the \(\bar{\partial }\) equation with Hölder and \(L^p\) -estimates on strictly \(q\) -concave domain with smooth \(\mathcal C ^2\) boundary in \(\mathbb{C }^n\) , by using the local solutions and applying the pushing out method of Kerzman (Commun Pure Appl Math 24:301–380, 1971).     

On the maximal unramified pro-2-extension of certain cyclotomic $$\mathbb {Z}_2$$ Z 2 -extensions

Periodica Mathematica Hungarica - In this paper, we establish a necessary and sufficient criterion for a finite metabelian 2-group G whose abelianized $$G^{ab}$$ is of type $$(2, 2^m)$$ , with...     

Argan hulls extract: green inhibitor of mild steel corrosion in 1?M HCl solution

Argan hulls extract (AHE) was tested as corrosion inhibitor for mild steel in 1?M HCl. Weight loss measurements, potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) revealed that inhibiting action increased with increasing concentration of the inhibitor. The highest efficiency 97.3% was obtained at 5?g/L AHE. There was good agreement between gravimetric and electrochemical methods (potentiodynamic polarization and EIS). Results obtained from EIS measurements were analyzed to model the corrosion-inhibition process by use of the appropriate equivalent circuit model; a constant phase element was used. Polarization measurements show also that AHE acts as good mixed inhibitor. AHE is adsorbed on the steel surface in accordance with a Langmuir isotherm adsorption model.     

Off-lattice pattern recognition scheme for kinetic Monte Carlo simulations

We report the development of a pattern-recognition scheme for the off-lattice self-learning kinetic Monte Carlo (KMC) method, one that is simple and flexible enough that it can be applied to all types of surfaces. In this scheme, to uniquely identify the local environment and associated processes involving three-dimensional (3D) motion of an atom or atoms, space around a central atom is divided into 3D rectangular boxes. The dimensions and the number of 3D boxes are determined by the accuracy with which a process needs to be identified and a process is described as the central atom moving to a neighboring vacant box accompanied by the motion of any other atom or atoms in its surrounding boxes. As a test of this method to we apply it to examine the decay of 3D Cu islands on the Cu(100) and to the surface diffusion of a Cu monomer and a dimer on Cu(111) and compare the results and computational efficiency to those available in the literature.     

Metallization of the β-SiC(100) 3 × 2 surface: A DFT investigation

Using density functional theory (DFT) we report results for the electronic structure and vibrational dynamics of hydrogenated silicon carbide (001) (3 × 2) surfaces with various levels of hydrogenation. These results were obtained using density functional theory with a generalized gradient exchange correlation function. The calculations reveal that metallization can be achieved via hydrogen atoms occupying the second silicon layer. Further increase of hydrogen occupation on the second silicon layer sites results in a loss of this metallization. For the former scenario, where metallization occurs, we found a new vibrational mode at 1870 cm^? 1, which is distinct from the mode associated with hydrogen atoms on the first layer. Furthermore, we found the diffusion barrier for a hydrogen atom to move from the second to the third silicon layer to be 258 meV.     

A review on silicene — New candidate for electronics

Silicene-the silicon-based counterpart of graphene-has a two dimensional structure that is responsible for the variety of potentially useful chemical and physical properties. The existence of silicene has been achieved recently owing to experiments involving epitaxial growth of silicon as stripes on Ag(001), ribbons on Ag(110), and sheets on Ag(111). The nano-ribbons observed on Ag(110) were found-by both high definition experimental scanning tunneling microscopy images and density functional theory calculations-to consist of an arched honeycomb structure. Angle resolved photo-emission experiments on these silicene nano-ribbons on Ag(110), along the direction of the ribbons, showed a band structure which is analogous to the Dirac cones of graphene. Unlike silicon surfaces, which are highly reactive to oxygen, the silicene nano-ribbons were found to be resistant to oxygen reactivity.On the theoretical side, recent extensive efforts have been deployed to understand the properties of standalone silicene sheets and nano-ribbons using both tight-binding and density functional theory calculations. Unlike graphene it is demonstrated that silicene sheets are stable only if a small buckling (0.44 Å) is present. The electronic properties of silicene nano-ribbons and silicene sheets were found to resemble those of graphene.Although this is a fairly new avenue, the already obtained outcome from these important first steps in understanding silicene showed promising features that could give a new future to silicon in the electronics industry, thus opening a promising route toward wide-range applications. In this review, we plan to introduce silicene by presenting the available experimental and theoretical studies performed to date, and suggest future directions to be explored to make the synthesis of silicene a viable one.     

Electron–Phonon Superconductivity in Boron-Based Chalcogenide (X= S,Se) Monolayers

Electron–phonon mediated superconductivity is deeply investigated in two boron based monolayer materials, namely, $B_{3}S$, a metal exhibiting the ability to superconduct, and a new metal, $B_{3}Se$, presenting perfect kinetic stability. Calculations based on density functional perturbation theory combined with the maximally localized Wannier function also reveal that both materials exhibit anisotropic planar hexagonal structure like graphene. The key parameters involved in the superconductor behavior are all calculated. The electronic density in the Fermi surface is given to provide the environment for enhanced electron–phonon coupling. The longitudinal and transverse vibration modes of optical phonons mainly contribute to the electron–phonon coupling strength. Furthermore, the binding energy between the bosonic Cooper pair superfluid is quantified and determined. The critical temperature for the two materials is 20 and 10.5 K, respectively. The results obtained show the potential use of such materials for superconducting applications.     

A new synthesis of alkane and polyfluoroalkanesulfonyl chlorides

This study describes a new and advantageous procedure for the synthesis of alkanesulfonyl chlorides ( 2 ) by the reaction of alkyl thiocyanates ( 1 ) with sulfuryl chloride in a mixture of acetic acid and water. The alkanesulfonyl chlorides were obtained in good yields. © 2009 Wiley Periodicals, Inc. Heteroatom Chem 20:355–361, 2009; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20559