A New Procedure to Measure Near Yield Residual Stresses Using the Deep Hole Drilling Technique

Mechanical strain relief techniques for estimating the magnitude of residual stress work by measuring strains or displacements when part of the component is machined away. The underlying assumption is that such strain or displacement changes result from elastic unloading. Unfortunately, in components containing high levels of residual stress, elastic-plastic unloading may well occur, particularly when the residual stresses are highly triaxial. This paper examines the performance of one mechanical strain relief technique particularly suitable for large section components, the deep hole drilling (DHD) technique. The magnitude of error is calculated for different magnitudes of residual stress and can be substantial for residual stress states close to yield. A modification to the technique is described to allow large magnitudes of residual stress to be measured correctly. The new technique is validated using the case of a quenched cylinder where use of the standard DHD technique leads to unacceptable error. The measured residual stresses using the new technique are compared with the results obtained using the neutron diffraction technique and are shown to be in excellent agreement.     

PEPT study of particle motion for different riser exit geometries

Laboratory and industrial risers are equipped with exits of many different layouts, and numerous publications discuss the influence of riser exit geometry on local and overall solids hydrodynamics in the riser. The present paper reviews literature findings--mostly based upon indirect experimental techniques and often somewhat contradictory, Direct measurement of particle velocity and particle occupancy near and in the riser exit provide a better indication of the effect of riser exit geometry. Positron Emission Particle Tracking （PEPT） was used in this work for the first time to investigate the exit region of the riser, An abrupt or sharp exit causes particles to be knocked out of the gas flow, so forming a recirculation or reflux region in the upper part of the riser. This is much less pronounced with a curved or gradual exit.     

Antibacterial and antioxidant properties of phyto-synthesized silver nanoparticles using Lavandula stoechas extract

Due to environmentally friendly and cost- effective issues, biological methods for silver nanoparticles (AgNPs) synthesis are advantageous over chemical and physical ones. In this study, AgNPs synthesized using Lavandula stoechas extract as a reductant and its antioxidant capacity, antibacterial property and cytotoxicity effect were investigated. The phyto-synthesized AgNPs were characterized using various analyses such as transmission electron microscopy (TEM), scanning electron microscopy (SEM), x-ray diffraction (XRD) as well as Fourier transform infrared (FT-IR). The prepared nanoparticles were spherical on shape with the size about 20–50 nm. Antibacterial studies through agar disk diffusion method confirmed the antibacterial potential of phyto-synthesized AgNPs toward two clinical Staphylococus aureus and Pseudomonas aeruginosa bacteria, although MTT assay demonstrated that S. aureus (MIC = 125 μg/ml) was more susceptible to AgNPs than P. aeruginosa (MIC = 250 μg/ml). Moreover, the cytotoxicity assay of phyto-synthezied AgNPs showed a low cytotoxic effect on RAW264 cell line at 62.5 μg/ml as an effective concentration. Also the considerable antioxidant capacity of the AgNPs confirmed through DPPH assay. Great antibacterial and antioxidant properties along with biocompatibility make the suggested phyto-synthesized AgNPs a great candidate for different biomedical applications including wound healing.     

Ligand exchange method for determination of mole ratios of relatively weak metal complexes: a comparative study

Ligand exchange method is introduced as an alternative to Job’s and mole ratio methods for studying the stoichiometry of relatively weak metal complexes in solutions. The method involves adding varying amounts of a ligand (L) to an excess constant amount of a colored complex (MX) with appropriate stability and molar absorptivity. The absorbance of each solution is measured at the λ_max of the initial complex, MX, and plotted against the concentration of the studied ligand, L. If the newly formed complex ML does not absorb at the λ_max of the initial complex, then attenuation of the absorbance of the initial complex on adding varying quantities of the investigational ligand gives an inverse calibration line that intersects with the calibration curve of initial complex at a given point. If a line parallel to the ordinate is drawn from this point to the x-axis, the ratio of the two parts of the x-axis to the left and to the right (α/β) gives the metal to ligand molar ratio in the complex formed, ML. The new method has been applied to the study of the composition of iron (III) complexes with three bisphosphonate drugs: alendronate, etidronate, and ibandronate. The mole ratio was found to be 1:1 with the three investigated bisphosphonates and results were further confirmed by Job’s and mole ratio methods. The ligand exchange method is simpler, quicker, easier to perform and more accurate than Job’s and mole ratio methods for studying weak and relatively weak complexes.

Open image in new window

     

ACTIVATED NITRILES IN HETEROCYCLIC SYNTHESIS: NOVEL SYNTHESIS OF PYRROLO[1,2-c]IMIDAZOLE AND PYRANO[2,3-d]IMIDAZOLE DERIVATIVES

Abstract

Several new pyrrolo[1,2-ylidene ethyl cyanoacetate (lc, d) with each of (2) and (11) afforded the 5-ylidene-2-thiohydantoins (Sa, b), (Wn. b) respectively. Compounds Sn, b react with each of malononitrile and ethyl cyanoacet-ate to give the corresponding pyrroloimidazole derivatives (h,b) and (an, b) respectively. The structure of the isolated products were established by elemental analyse and spectral data studies.     

Chromium-Assisted Oxidations with Sodium Perborate by Phase Transfer Catalysis

Oxidation by sodium perborate of selected alcohols and unsaturated compounds to ketones and acids was achieved at 60–80°C in the presence of catalytic amounts of chromium(VI) oxide and methyltridecylammonium chloride.     

G-, F-, and σ-Matrices for XY5Z2 Molecules of D5h Symmetry

XY₅Z₂ molecules or ions of D_5h symmetry are very rare. For this reason, up to now, little work was done on the interpretation of their vibrational spectra.     

Stability of roll waves in open channel flowsStabilité de trains d'ondes dans un canal découvert

The stability of finite amplitude roll waves that may develop at a liquid free surface in inclined open channels of arbitrary cross-section is studied. In the framework of shallow water theory with turbulent friction the modulation equations for wave series are derived and a nonlinear stability criterion is obtained. To cite this article: A. Boudlal, V.Yu. Liapidevskii, C. R. Mecanique 330 (2002) 291–295.