Zn and Zr co-doped M-type strontium hexaferrite: Synthesis,characterization and hyperthermia application

In the present study, hard ferromagnetic (M-type strontium hexaferrite) SrFe₁₂O₁₉ was co-doped by Zn and Zr for magnetic hyperthermia applications. As a result of the high concentration of single domain SrFe₁₂O₁₉ nanoparticles (suspended in the ferrofluid), they found a large hydrodynamic diameter, which caused a long-time Brownian relaxation under the AC magnetic field. On the other hand, increasing the Zn-Zr content (low concentration of SrFe₁₂O₁₉) led to a drop in anisotropy, which coincided with a short-time N´eel relaxation. All of the substituted samples with a multi-disperse state in ferrofluid exhibited an almost equal amount of the N´eel and Brownian effects. Consequently, the magnetic saturation (M_s) was considered as the dominant factor in the specific absorption rate (SAR) of the substituted samples. Transformation to the mono-disperse state was followed by the decrease of the Brownian relaxation time and hence the increase of the SAR. The interesting point in mono-disperse state was the heat generation of pure SrFe₁₂O₁₉ under the AC magnetic field as a result of the decrement of the Brownian relaxation time.     

Studies on recoil proton tracks in NTA films with the T(d,n)He reaction

Recoil proton tracks in nuclear emulsion are counted by scanning them using strip, square or circular field of view of optical microscope. In this paper, the overestimate due to the edge effects in counting recoil proton tracks at different neutron energies produced from the T(d,n)⁴He reaction has been determined by measuring the true track density in NTA film. The overestimate has also been calculated using the measured value of the mean projected track length (L) in the film. The percentage of measured overestimates has been compared with those obtained by calculation and the results agree reasonably well. Fading effect in NTA film has been studied and found to be 22% more in the summer than in the winter season. A great reduction in fading rate could be achieved if the films are desiccated and sealed in highly pure dry nitrogen maintained at an over-pressure of 1000 Pa to reduce water vapour ingress. After the edge effect correction, the sensitivity of NTA film has been calculated from (1.72±0.08)×10⁻³ tracksn⁻¹ to (1.97±0.16)×10⁻³ tracksn⁻¹ in the neutron energy ranges from 15.91 to 18.88 MeV. The response was found to be from 0.24±0.02 trackscm⁻² permSv to 0.26±0.01 trackscm⁻² permSv in the same energy range.     

Ultrasound-assisted photochemical oxidation of unsymmetrically substituted 1,4-dihydropyridines

The combination of ultrasound and photochemistry has been used for the oxidation of unsymmetrical 1,4-dihydropyridines to the pyridine derivatives. An ultrasonic probe of 24 kHz frequency and a Hg-lamp of 100 W have been used for this study. The effect of parameters such as ultrasonic intensity, the presence of oxygen and argon atmospheres and also the separate usage of one of these irradiation sources have been studied. Whereas sonication of these compounds alone did not result in the oxidation of them, the use of ultrasound increases the rate of photo-oxidation. The presence of oxygen decreases or increases the rate of reaction, depending on the type of excited state of 1,4-dihydropyridines involved in the reaction.     

Design of A Wood’s Metal Grip in Torsion

Experimental Techniques -     

Multi-enzyme electrodes for the determination of starch by flow injection

A tri-enzyme electrode has been developed for determining starch in a flowing stream based on amperometric monitoring of hydrogen peroxide at a potential of +600 mV versus a silver--silver chloride reference electrode. The nylon-based starch-sensing membranes (over a platinum electrode) were prepared from an enzyme cocktail containing various ratios of amyloglucosidase (AMG), mutarotase (MUT) and glucose oxidase (GO). The best starch-sensing membrane (to give the type A electrode) was made from an enzyme cocktail of AMG--MUT--GO (2000 + 100 + 100 U; where 1 U = 16.67 nanokatals), i.e., containing a high level of AMG. In this system, starch samples were first incubated with soluble alpha-amylase (alpha-AMY) (1000 U) for 1 h at room temperature prior to analysis with the tri-enzyme electrode. Attempts were also made to immobilize alpha-AMY on to nylon net, either alone or as a component of a four-membrane starch-enzyme electrode but starch signals were weak compared with those generated by starch pre-treated with soluble alpha-AMY. This system, associated with the type A starch electrode, not only exhibited a calibration of wide linear range (1 x 10(-4)-0.1% m/v starch) but also showed promising operational properties. It has excellent thermal stability over the range 30-70 degrees C.     

Nano-[Mn-PSMP]Cl2 as a new Schiff base complex and catalyst for the synthesis of N,N'-alkylidene bisamides

Research on Chemical Intermediates - Nano-Mn-[phenyl-salicylaldimine-methyl-pyranopyrimidinedione]Cl2 {Nano-[Mn-PSMP]Cl2} as a new Schiff base complex was prepared and characterized by various...     

A novel secure image transmission scheme based on synchronization of fractional-order discrete-time hyperchaotic systems

In this paper, a secure image transmission scheme based on synchronization of fractional-order discrete-time hyperchaotic systems is proposed. In this scheme, a fractional-order modified-Hénon map is considered as a transmitter, the system parameters and fractional orders are considered as secret keys. As a receiver, a step-by-step delayed observer is used, and based on this one, an exact synchronization is established. To make the transmission scheme secure, an encryption function is used to cipher the original information using a key stream obtained from the chaotic map sequences. Moreover, to further enhance the scheme security, the ciphered information is inserted by inclusion method in the chaotic map dynamics. The first contribution of this paper is to propose new results on the observability and the observability matching condition of nonlinear discrete-time fractional-order systems. To the best of our knowledge, these features have not been addressed in the literature. In the second contribution, the design of delayed discrete observer, based on fractional-order discrete-time hyperchaotic system, is proposed. The feasibility of this realization is demonstrated. Finally, different analysis are introduced to test the proposed scheme security. Simulation results are presented to highlight the performances of our method. These results show that, our scheme can resist different kinds of attacks and it exhibits good performance.     

Lie superalgebras whose enveloping algebras satisfy a non-matrix polynomial identity

Let L be a Lie superalgebra with its enveloping algebra U(L) over a field F. A polynomial identity is called non-matrix if it is not satisfied by the algebra of 2×2 matrices over F. We characterize L when U(L) satisfies a non-matrix polynomial identity. We also characterize L when U(L) is Lie solvable, Lie nilpotent, or Lie super-nilpotent.     

The Aim of Justification and Epistemic Difference-Making Principles

The idea that truth is the aim of justification is one that is often defended by theorists who uphold different views about the nature of epistemic justification. Despite its prevalence, however, it is not quite clear how one is to cash out the metaphor that justification aims at truth. Some theorists, for example, have objected that the thesis would leave no room for justified false beliefs and unjustified true beliefs. In this paper, I offer an account of what it is for justification to aim at truth using the recently revived idea of difference-making according to which facts often make a difference to other facts. It will be argued that, thus understood, the thesis can illuminate a number of controversial debates in epistemology and that, given its explanatory power, it has a lot to recommend it.