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41.
Ray MS Ghosh A Das A Drew MG Ribas-Arino J Novoa J Ribas J 《Chemical communications (Cambridge, England)》2004,(9):1102-1103
[Cu(4)L(2)(bpy)(4)(H(2)O)(3)](ClO(4))(4).2.5H(2)O, 1, a new tetranuclear Cu(II) cluster showing square planar geometry, formed with aspartate bridging ligand (L) has been synthesized. The global magnetic coupling is ferromagnetic but theoretical DFT/B3LYP calculations are necessary to assign which Cu-L-Cu side is ferro or antiferromagnetically coupled. 相似文献
42.
Summary A method for the determination of free formaldehyde in nonwovens in the presence of interfering components is described.After RP-HPLC separation the water extracted formaldehyde reacts with acetylacetone in a knitted open tube reactor to form a lutidine derivative which is measured, even at low concentrations, by the UV detector. The minimum detectable concentration is 25 g/kg. 相似文献
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44.
V. E. Lyubovitskij Th. Gutsche Amand Faessler R. Vinh Mau 《Physics letters. [Part B]》2001,520(3-4):204-212
We apply the perturbative chiral quark model to give predictions for the electromagnetic O(p2) low-energy couplings of the ChPT effective Lagrangian that define the electromagnetic mass shifts of nucleons and first-order (e2) radiative corrections to the πN scattering amplitude. We estimate the leading isospin-breaking correction to the strong energy shift of the π−p atom in the 1s state, which is relevant for the experiment “Pionic Hydrogen” at PSI. 相似文献
45.
Abstract Using a stochastic model for the evolution of discrete characters among a group of organisms, we derive a Markov chain that simulates a Bayesian posterior distribution on the space of dendograms. A transformation of the tree into a canonical cophenetic matrix form, with distinct entries along its superdiagonal, suggests a simple proposal distribution for selecting candidate trees “close” to the current tree in the chain. We apply the consequent Metropolis algorithm to published restriction site data on nine species of plants. The Markov chain mixes well from random starting trees, generating reproducible estimates and confidence sets for the path of evolution. 相似文献
46.
Nguyen Mau Nam Maria Cristina Villalobos Nguyen Thai An 《Journal of Optimization Theory and Applications》2012,154(3):768-791
The smallest enclosing circle problem introduced in the nineteenth century by Sylvester asks for the circle of smallest radius enclosing a given set of finite points in the plane. An extension of this problem, called the smallest intersecting ball problem, was also considered recently: given a finite number of nonempty closed subsets of a normed space, find a ball with the smallest radius that intersects all of the sets. In this paper, we initiate the study of minimal time functions generated by unbounded dynamics and discuss their applications to further extensions of the smallest enclosing circle problem. This approach continues our effort in applying convex and nonsmooth analysis to the well-established field of facility location. 相似文献
47.
R. Jaćimović M. Maučec A. Trkov 《Journal of Radioanalytical and Nuclear Chemistry》2003,257(3):513-517
An experimental verification of Monte Carlo neutron flux calculations in typical irradiation channels in the TRIGA Mark II reactor at the Joef Stefan Institute is presented. It was found that the flux, as well as its spectral characteristics, depends rather strongly on the position of the irradiation channel. Comparison of the results for parameter f (thermal-to-epithermal flux ratio), experimentally obtained by the Cd ratio multi-monitor method and Monte Carlo simulations shows relatively good agreement for most studied configurations except for the channel IC40 in the carousel facility, where differences are relatively large and not understood. 相似文献
48.
The neutron spectrum and asymmetry have been calculated for 40Ca with different wave functions for the bound proton and the emitted neutron. The asymmetry is shown to be very sensitive to the behaviour of the wave functions near the nuclear surface while the spectrum is mostly sensitive to the strength of the real part of the neutron optical potential. 相似文献
49.
Set-Valued and Variational Analysis - In this paper, we study bornological generalized differential properties of sets with nonsmooth boundaries, nonsmooth functions, and set-valued mappings in... 相似文献
50.