Novel dinitroxide mediating agent for stable free‐radical polymerization

A novel dinitroxide mediating agent that was suitable for stable free‐radical polymerization was synthesized and used in the block copolymerization of styrene and t‐butyl styrene. Quantitative yields of a novel dinitroxide based on 1,6‐hexamethylene diisocyanate and 4‐hydroxy‐2,2,6,6‐tetramethyl‐1‐piperidinyloxy were obtained. Various experimental parameters, including the nitroxide‐to‐initiator molar ratio, were examined, and it was determined that the polymerization was most controlled under conditions similar to those of conventional 2,2,6,6‐tetramethyl‐1‐piperidinyloxy‐mediated stable free‐radical polymerization. Moreover, the dinitroxide mediator proved to be a viable route for the facile two‐step synthesis of triblock copolymers of styrene and t‐butyl styrene. However, the dinitroxide mediation process resulted in a higher than expected level of nitroxide decomposition, which resulted in polymers possessing a terminal alkoxyamine and an adjacent hydroxylamine rather than a preferred internal bisalkoxyamine. This decomposition resulted in the formation of diblock copolymer species during the triblock copolymer synthesis. Gel permeation chromatography was used to monitor the chain‐end decomposition kinetics, and the determined observed rate constant (5.89 × 10^?5 s^?1) for decomposition agreed well with previous studies for other dinitroxide mediating agents. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1547–1556, 2004     

强流离子束离子径向密度分布的模拟研究

对初始分布为K-V分布的离子束进行模拟研究.除观察到存在束晕现象外，还发现离子束在通 道内运行过程中，离子沿径向密度分布发生了变化. 通过延迟反馈控制，不仅可以消除束晕 ，而且只要控制参数适当，也可以使束中心部分呈均匀分布状态. 关键词： 强流离子束 束晕 填充因子 离子密度分布     

高功率飞秒脉冲激光器的进展

概述了超短激光脉冲技术发展的历程。详尽的论述了啁啾脉冲放大技术的原理和一些关键技术 ,并对当今飞秒激光器研究发展的状况进行了综述。在分析其应用前景的基础上 ,进一步指出了这一技术领域未来的发展趋势。结果表明 ,脉冲激光放大系统以后的发展方向是 :更短脉冲 ;追求更高峰值功率 ;连续光谱调谐化 ;向小型化乃至全光纤化发展。     

广义的一维Fibonacci结构

本文提出一维k组元的Fibonacci结构,它包含k个无公度的基本长度,是具有两个基本长度的标准Fibonacci结构的自然推广,投影理论被用来处理它的X射线衍射花样及其指标化问题,理论模拟被用于验证投影理论的结果,值得注意的是,对于有限的链长,当k足够大时,它的衍射谱将趋于混沌。 关键词：     

一种新型的二元光学器件——多位相光束分束器的制作

本文报道了用于多光束分束器的反射式16位相值二元光学器件的制作。该二元光学器件把一束光束分成5×5光束阵列。测量的衍射效率为76.16%,接近理论设计值79.68%。该二元光学器件的有效孔径为10mm×10mm。     

Effects of Substrate Temperature on Helium Content and Microstructure of Nanocrystalline Titanium Films

Helium-charged nanocrystalline titanium films have been deposited by HeAr magnetron co-sputtering. The effects of substrate temperature on the helium content and microstructure of the nanocrystalline titanium films have been studied. The results indicate that helium atoms with a high concentration are evenly incorporated in the deposited titanium films. When the substrate temperature increases from 60℃ to 350℃ while the other deposition＇parameters are fixed, the helium content decreases gradually from 38.6 at.% to 9.2at.%, which proves that nanocrystalline Ti films have a great helium storage capacity. The 20 angle of the Bragg peak of （002） crystal planes of the He-charged Ti film shifts to a lower angle and that of （100） crystal plane is unchanged as compared with that of the pure Ti film, which indicates that the lattice parameter c increases and a keeps at the primitive value. The grain refining and helium damage result in the diffraction peak broadening.     

Jensen’s Inequality for Backward Stochastic Differential Equations

Abstract Under the Lipschitz assumption and square integrable assumption on g, the author proves that Jensen’s inequality holds for backward stochastic differential equations with generator g if and only if g is independent of y, g(t, 0) ≡ 0 and g is super homogeneous with respect to z. This result generalizes the known results on Jensen’s inequality for g- expectation in [4, 7–9]. *Project supported by the National Natural Science Foundation of China (No.10325101) and the Science Foundation of China University of Mining and Technology.     

Dynamical Properties of Potassium Ion Channels with a Hierarchical Model

It is well known that potassium ion channels have higher permeability than K ions, and the permeable rate of a single K ion channel is about 108 ions per second. We develop a hierarchical model of potassium ion channel permeation involving ab initio quantum calculations and Brownian dynamics simulations, which can consistently explain a range of channel dynamics. The results show that the average velocity of K ions, the mean permeable time of K ions and the permeable rate of single channel are about 0.92nm/ns, 4.35ns and 2.30 ×10^8 ions/s, respectively.     

关于算子方程AX=XAX与AX=XA=XAX

用A的不变子空间作参数，给出了算子方程AX＝XAX的全部解。当A是单射或稠值域时，或者当A是正规算子时，给出了算子方程AX＝XA＝XAX的全部解。我们还给出正规算子X是算子方程AX＝XZ＝XAX的解的充分必要条件。