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961.
Granular films prepared from well-defined In clusters embedded in Kr (? 10-40 at % Kr) show sharp resistance anomalies very close to the superconducting transition temperature. The observed resistance peak(s), which go(es) above the normal state resistance RN and which can be as high as ? 1.5 RN, can be explained by a “mesoscopic” effect: Superconducting percolation aggregates of size ξρ, larger than the superconducting coherence length ξS, but smaller than the quasiparticle relaxation length λQ*, have a superconducting gap, but are not yet able to carry a supercurrent. 相似文献
962.
We study the critical behavior of certain two-parameter families of correlated percolation models related to the Ising model on the triangular and square lattices, respectively. These percolation models can be considered as interpolating between the percolation model given by the + and – clusters and the Fortuin-Kasteleyn correlated percolation model associated to the Ising model. We find numerically on both lattices a two-dimensional critical region in which the expected cluster size diverges, yet there is no percolation. 相似文献
963.
I. A. Melamed 《Journal of Mathematical Sciences》1992,59(4):960-970
Translated from:Problemy Ustoichivosti Stokhasticheskikh Modelei, Trudy Seminara, 1989, pp. 93–103. 相似文献
964.
G. A. Kohring 《Journal of statistical physics》1992,66(3-4):1177-1184
A hydrodynamic cellular automata (HDCA) for simulating two-dimensional fluids with large viscosities is proposed. The model is characterized by a mean free path which is of the same size as in the FHP-II model, but with a viscosity more than 10 times larger. This new model should make simulations of flows at low Reynolds number more efficient. 相似文献
965.
R. Szymczak K. Zaveta H. Szymczak H. -Q. Guo H. Kronmü ller 《Journal of magnetism and magnetic materials》1994,130(1-3):363-366
The temperature dependence of magnetization of a nanocrystalline Fe60Co30Zr10 alloy annealed at various temperatures to varying crystal sizes was investigated down to 5 K in the field range up to 5 T. The fitting procedure gave T3/2 as the leading term irrespective of the crystal size. We suggest that the increase of the coefficient by this term for smaller crystals may be connected to an increased relative volume of their surface. 相似文献
966.
Sulfide cluster-derived ensembles are promising models of the active sites in commercial hydrotreatment catalysts. A series of sulfide clusters were adsorbed intact onto high-surface-area γ-alumina, magnesium oxide and activated carbon supports, then pretreated to produce highly dispersed catalytic ensembles with sizes similar to those of their precursor clusters. The activities of the bimetallic cluster-derived catalysts were significantly higher than those of the monometallic catalysts. We took this as evidence that direct interactions between molybdenum and the promoter element cause the promotional effect observed in commercial hydrotreatment catalysts. The hydrodesulfurization and hydrodenitrogenation activities correlated with the extent of molybdenum reduction. Our results suggested that the active sites in promoted hydrotreatment catalysts are centered on molecular-scale ensembles containing molybdenum, sulfur and the promoter element. 相似文献
967.
968.
969.
M. D. Zipper G. P. Simon P. Cherry A. J. Hill 《Journal of Polymer Science.Polymer Physics》1994,32(7):1237-1247
Homopolymers and blends of polycarbonate/ThermX have been investigated by differential scanning calorimetry, dynamic mechanical analysis, density measurements, and positron annihilation lifetime spectroscopy. The study focuses on the chain mobility and free volume in the amorphous miscible regions of the blends and how this mobility and free volume are affected by increasing crystallinity. It is proposed that judicious annealing, which results in increasing crystallinity (while avoiding ageing or transesterification), induces a constraint on the amorphous region leading to an increase in Tg and coalescence of free volume sites. © 1994 John Wiley & Sons, Inc. 相似文献
970.
Thermal diffusivity, heat capacity, and density of polyvinyl chloride/polycaprolactone (PVC/PCL) blends were measured by the laser flash method, DSC, and pycnometry, respectively. The thermal conductivity of the PVC/PCL blends was determined from the results. The miscibility of the blend and crystallinity of PCL were determined by DSC. The effect of blend structure on thermal conductivity is discussed. The phase compositions of the PVC/PCL blends are of three types depending on PCL content: i.e., up to 33%, from 33 to 70%, and above 70% PCL by weight. Thermal conductivity, thermal diffusivity, and heat capacity of the PVC/PCL blends are strongly affected by the phase composition of the blend, which changes in a complicated way with PCL content. © 1994 John Wiley & Sons, Inc. 相似文献