Electron transfer at lanthanum endohedral fullerenes

The aim of this contribution is to study lanthanum containing fullerenes produced and treated under different conditions. The work was done using solid soot extract giving poorly resolved ESR spectra or separated lanthanofullerenes in solution showing well resolved ESR spectra. ESR experiments in connection with the mass spectrometry give information on the electronic states due to the electron transfer from the endohedral metal to the fullerene cage and the influence of oxygen on endohedral lanthanofullerene. The analysis of ESR spectra indicates the presence of up to nine octets of lanthanum containing fullerenes. These species have different stabilities. Furthermore, a very narrow single ESR line in the lanthanofullerene spectrum was detected having a linewidth ΔB=0.008 mT and ag-factor 2.0025. The electron transfer to the endohedral La@C₈₂ molecule studied by voltammetry and electrochemicalin situ ESR experiments is described. The interaction of the lanthanofullerene with oxygen in solution is also studied. In different solvents the influence of oxygen on line broadening in the ESR spectra of La@C₈₂ was observed.     

Exciton molecules and exciton liquids in semiconductors

Excitons in many-valley semiconductors form molecules consisting of four and more excitons. The degeneracy factor g of the conduction band in germanium is 8, and in silicon g=12. As in acceptors, the hole ground state in excitons is fourfold degenerate. The same is valid for exciton molecules, because they are quantum objects with spherical symmetry. The exciton binding energy in molecules is close to that in exciton-liquid droplets. Experimental evidence is considered for the existence, besides biexcitons, of stable exciton molecules consisting of three and four, and, possibly, 11 and 12 excitons. Molecules containing from five to ten excitons are apparently unstable. Fiz. Tverd. Tela (St. Petersburg) 40, 929–931 (May 1998)     

Hydrogel composition based on carboxymethylcellulose and agar-agar

The results are given of a study of the rheological properties of concentrated solutions of CNC and agar-agar and the influence of their quantitative ratio on the anomalous flow behavior of their solutions. A hypothesis is put forward of the formation of intermolecular associates from CMC and agar-agar which leads to the formation of a stronger structural network of solutions of the initial polysaccharides.Institute of the Physics and Chemistry of Polymers, Academy of Sciences of the Republic of Uzbekistan, Tashkent, fax (371) 1 44 26 61. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 357–361, May–June, 1998.     

Modeling of heat transfer in a melt in growing single crystals by the stockbarger method using the accelerated crucible rotation technique (ACRT)

In model experiments, the layer of melt bounded by the crystallization front and the heater for heating the diaphragm in a growing furnace is shown to determine crystal growth by the Stockbarger method under conditions of induced convection and also to control the crystallization process. The free volume of the melt exerts no effect on its hydrodynamic and thermal structures. Optimum values of the exposure time are estimated for constant maximum and minimum velocities of modulated rotation of the growing ampoule. Institute of Mineralogy and Petrography, Siberian Division, Russian Academy of Sciences, Novosibirsk 630090. Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 39, No. 1, pp. 98–104, January–February, 1998.     

Gas transport through homogeneous and asymmetric polyethersulfone membranes

Both homogeneous and asymmetric polyethersulfone (PES) membranes were prepared by solvent casting. The sorption and permeation behavior of CO₂, O₂, and N₂ using these two kinds of cast PES membranes and commercially available homogeneous PES film was investigated to extract the pressure dependence of gas permeability and the permselectivity for CO₂ relative to N₂, and to confirm the validity of the working assumption that a skin layer in an asymmetric membrane can be essentially replaced by a thick homogeneous dense membrane. The pressure dependence of the mean permeability coefficient to CO₂ in homogeneous membranes obeys the dual-mode mobility model. The ideal separation factor for CO₂ relative to N₂ at an upstream pressure of 0.5 MPa attains ca. 40, while the permeability to CO₂ is about 2.7 Barrer at the same upstream pressure. The same separation factor in asymmetric membranes amounts to 35. The diffusion behavior for the skin layer in an asymmetric membrane with a thin skin layer can be simulated approximately by that in a homogeneous dense membrane. © 1993 John Wiley & Sons, Inc.     

Circulatory flow in the inter-jet zone of a system of free turbulent jets

Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, No. 4, pp. 97–99, July–August, 1993.     

Poisson-Lie T-duality and complex geometry in N = 2 superconformal WZNW models

Poisson-Lie T-duality in N = 2 superconformal WZNW models on the real Lie groups is considered. It is shown that Poisson-Lie T-duality is governed by the complexifications of the corresponding real groups endowed with Semenov-Tian-Shansky symplectic forms, i.e. Heisenberg doubles. Complex Heisenberg doubles are used to define on the group manifolds of the N = 2 superconformal WZNW models the natural actions of the isotropic complex subgroups forming the doubles. It is proved that with respect to these actions N = 2 superconformal WZNW models admit Poisson-Lie symmetries. The Poisson-Lie T-duality transformation maps each model onto itself but acts non-trivially on the space of classical solutions.