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931.
932.
Our research group has been interested in synthesis of proton transfer compounds as new supramolecular synthons for the onepot preparation of self-assembled transition metal complex-organo-networks since 2000. We have focused on the proton delivery from acids, which are considered as suitable proton donors, to amines as proton acceptors. The results were production of several proton transfer ion pairs possessing some remaining donor sites applied for coordination to metallic centers in preparation of metal-organic structures. Some of the complexes showed contributions of both cationic and anionic fragments of the starting ion pair, while some others contained only one of these species as ligand. Much of the investigations on reviewed compounds focused on the concept of supramolecular systems, co-crystallization, stereochemically active lone pairs, coordination polyhedron and mainly on various interactions involve including van der Waals, ion pairing, hydrogen bondings, face to face π-π stackings and edge to face C-H...π, C-O...π, N-H...π, S-O...π, Ti...π and Hg-Cl...π interactions. The mentioned interactions are the most commonly used strategies in the extension of supramolecular structures. 相似文献
933.
934.
935.
936.
A. I. Kolesnikov I. A. Kaplunov I. V. Talyzin S. A. Tret’yakov O. V. Gritsunova E. Yu. Vorontsova 《Crystallography Reports》2008,53(7):1144-1149
A computer simulation and measurements of the light transmittance of germanium and paratellurite crystals of different thickness
were used to show that, at scattering probabilities of photons comparable to their absorption probabilities, the standard
methods for calculating light extinction coefficients on the basis of the Bouguer law lead to rough errors in estimation of
the optical quality of a material. 相似文献
937.
A. P. Dudka 《Crystallography Reports》2008,53(2):351-355
The methods of automation of the procedure for crystal structure model refinement from experimental diffraction data, implemented in the ASTRA program package, are described. Such tools as statistical tests, parameter scanning, and data scanning reduce the time necessary for structural investigation. At strong correlations between parameters, especially when the data set is limited, parameter scanning has an advantage over the full-matrix refinement. 相似文献
938.
A mathematical model of the formation of primary grown-in microdefects on the basis of dissociation diffusion is presented.
Cases of “vacancy-oxygen” (V + O) and “carbon-interstitial” (C + I) interaction near the crystallization front are considered
for dislocation-free Si single crystals grown by the floating-zone and Czochralski methods. The approximate analytical expressions
obtained by setting 1D and 2D temperature fields in a crystal are in good agreement with the heterogeneous mechanism of formation
of grown-in microdefects. 相似文献
939.
The types of quartz textures found in a large collection of multiphase rocks from different regions of the earth are analyzed. Crystallographic textures of granulite, amphibolite, slate, and gneiss samples are measured, classified, and compared with the similar textures of monomineral rocks. 相似文献
940.
The effect of the temperature factor, that is, the ratio of the body temperature to the freestream stagnation temperature, on the structure of the separated flow formed in the presence of a concave corner in a supersonic stream is studied. The strong influence of the temperature factor on the separation zone length and the flow-generated aerodynamic characteristics is established. It is shown that for fairly large deflection angles this flow cannot be described by free interaction, or triple deck, theory. 相似文献