首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   820824篇
  免费   6846篇
  国内免费   2390篇
化学   408130篇
晶体学   11969篇
力学   43350篇
综合类   34篇
数学   126564篇
物理学   240013篇
  2021年   6589篇
  2020年   7231篇
  2019年   8208篇
  2018年   20163篇
  2017年   20022篇
  2016年   20866篇
  2015年   9322篇
  2014年   14618篇
  2013年   33953篇
  2012年   28806篇
  2011年   39631篇
  2010年   27562篇
  2009年   27969篇
  2008年   34219篇
  2007年   35817篇
  2006年   25937篇
  2005年   24210篇
  2004年   22796篇
  2003年   21189篇
  2002年   20013篇
  2001年   21061篇
  2000年   16397篇
  1999年   12645篇
  1998年   10760篇
  1997年   10632篇
  1996年   10120篇
  1995年   9097篇
  1994年   9062篇
  1993年   8683篇
  1992年   9665篇
  1991年   9923篇
  1990年   9642篇
  1989年   9527篇
  1988年   9398篇
  1987年   9142篇
  1986年   8744篇
  1985年   11250篇
  1984年   11647篇
  1983年   9606篇
  1982年   9940篇
  1981年   9548篇
  1980年   9017篇
  1979年   9816篇
  1978年   10077篇
  1977年   10077篇
  1976年   9943篇
  1975年   9419篇
  1974年   9198篇
  1973年   9446篇
  1972年   6858篇
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
31.
Crystalline materials that are transparent in the vacuum UV spectral region and currently used have been reviewed. Transmission of crystals of solid solutions with the fluorite structure Ca1?x R xF2+x (R = Sc, Y, La, Yb, Lu) in the UV and vacuum UV spectral regions has been investigated. It is shown that application of different methods of purification of fluorides from some impurities can significantly improve the optical quality of fluoride multicomponent crystals in the short-wavelength spectral region.  相似文献   
32.

A method for calculating the parameters of formation of vacancies in crystals formed by spherically symmetrical atoms was developed. Both quantum effects at low temperatures and the possibility of the delocalization of atoms at high temperatures were studied. The parameters of formation of vacancies in carbon subgroup element crystals C-diam, Si, Ge, α-Sn, and Pb were calculated. The inclusion of the delocalization of atoms was shown to increase the enthalpy, entropy, and volume of vacancy formation. At low temperatures, the parameters of vacancy formation were found to depend strongly on the temperature, and the entropy of vacancy formation became negative. At high temperatures, close agreement with experimental data and theoretical estimates reported by other authors was obtained. The temperature dependence of vacancy parameters was studied for diamond heated isobarically from 100 to 4500 K. The applicability scope of the Arrhenius equation with a temperature-independent activation energy is discussed. The validity of the “compensation rule” (correlation between the entropy and enthalpy of vacancy formation) was demonstrated. It was also shown that the volume and entropy of vacancy formation were correlated over the whole temperature range studied.

  相似文献   
33.
34.
A three-dimensional examination of blood vessels is provided using MR data from seven cases. The vascular surfaces are constructed with an algorithm that automatically follows the selected artery or vein and generates a projected three-dimensional gradient shaded image. Fast 3DFT pulse sequences were optimized to enhance the time-of-flight contrast of the intravascular region. By increasing the surface threshold value in a three-dimensional head study, the flesh of a patient's face was peeled away to demonstrate the superfacial temporal artery. Gated cardiac images show the great vessels and cardiac chambers. A three-dimensional view of the aorta shows an irregular surface in the vicinity of an adrenal tumor. 3D MR exams provide a non-invasive technique for assessing vascular morphology in a clinical setting.  相似文献   
35.
    
The diversity of products in the reaction of diethyl azodicarboxylate (DEAD)/diisopropyl azodicarboxylate (DIAD) and activated acetylenes with PIII compounds bearing oxygen or nitrogen substituents is discussed. New findings that are useful in understanding the nature of intermediates involved in the Mitsunobu reaction are highlighted. X-ray structures of two new compounds (2-t-Bu-4-MeC6H3O)P (μ-N-t-Bu)2P+[(NH-t-Bu)N[(CO2]-i-Pr)(HNCO2-i-Pr)]](Cl-)(2-t-Bu-4-MeC6H3OH)(23)and [CH2(6-t-Bu-4-Me-C6H2O)2P(O)C(CO2Me)C-(CO2Me)CClNC(O)Cl] (33) are also reported. The structure of23 is close to one of the intermediates proposed in the Mitsunobu reaction.  相似文献   
36.
37.
It is shown that, if t is an integer ≥3 and not equal to 7 or 8, then there is a unique maximal graph having the path Pt as a star complement for the eigenvalue ?2. The maximal graph is the line graph of Km,m if t = 2m?1, and of Km,m+1 if t = 2m. This result yields a characterization of L(G ) when G is a (t + 1)‐vertex bipartite graph with a Hamiltonian path. The graphs with star complement PrPs or PrCs for ?2 are also determined. © 2003 Wiley Periodicals, Inc. J Graph Theory 43: 137–149, 2003  相似文献   
38.
The effect of space- and time-dependent random mass density, velocity, and pressure fields on frequencies and amplitudes of acoustic waves is considered by means of the analytical perturbative method. The analytical results, which are valid for weak fluctuations and long wavelength sound waves, reveal frequency and amplitude alteration, the effect of which depends on the type of random field. In particular, the effect of a random mass density field is to increase wave frequencies. Space-dependent random velocity and pressure fields reduce wave frequencies. While space-dependent random fields attenuate wave amplitudes, their time-dependent counterparts lead to wave amplification. In another example, sound waves that are trapped in the vertical direction but are free to propagate horizontally are affected by a space-dependent random mass density field. This effect depends on the direction along which the field is varying. A random field, which varies along the horizontal direction, does not couple vertically standing modes but increases their frequencies and attenuates amplitudes. These modes are coupled by a random field which depends on the vertical coordinate, but the dispersion relation remains the same as in the case of the deterministic medium.  相似文献   
39.
40.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号