Ionization potentials and geometrical structure of pure and oxygenated barium clusters

In this article, we present results obtained on structures of small bare and oxygenated barium clusters produced by the laser vaporization technique. Contrary to the very weak Ba—Ba binding (0.202 eV), the Ba—O binding is rather strong (5.8 eV). As a consequence, extremely small amounts of oxygen in the cluster source are sufficient to induce the nucleation of oxygenated barium clusters. Surprisingly, at least for substoechiometric systems, Ba_nO_m clusters exhibit the same icosahedral structure as bare clusters do. Mass spectra seem to indicate that replacing a barium atom with a strongly polar BaO molecule does not affect the geometrical structure of the cluster. This aspect is more easily understandable if we assume that the oxygen atom takes place inside the structure of the Ba_n cluster without significant distortions. Ab-initio calculations have been undertaken in order to give a satisfactory account of this hypothesis.     

Some characteristic features of layered ferroelectrics of the type A m−1Bi2MmO3m+3

The values of the Curie temperatures of bismuth-containing layered ferroelectrics and deformations of the pseudoperovskite cell, distinguished in the perovskite-like layer of these compounds, are discussed. It is shown that the perovskite-like layers play an important role in the appearance of the ferroelectric state. Fiz. Tverd. Tela (St. Petersburg) 39, 135–136 (January 1997)     

Energetics of an adiabatically-loaded excited anharmonic oscillator

The dependence of the energy characteristics on an adiabatically slowly increasing external force is determined analytically for an anharmonic oscillator. The analytical results are confirmed by a numerical calculation. The nature of the force dependences of the energy characteristics are determined and discussed. Fiz. Tverd. Tela (St. Petersburg) 39, 153–157 (January 1997)     

Existence regions of regimes with anomalously high rates of plasma generation in grid plasma switch elements

Results are presented from a systematic investigation of the conditions under which anomalously high rates of plasma generation are observed in the anode region of a low-voltage Knudsen arc in grid plasma switch elements. The phenomenon develops over a wide range of currents and switched voltages under conditions for which the plasma density in the cathode-grid region is noticeably higher than the density in the anode region. and its onset is characterized by a pronounced pressure threshold of ∼2×10⁻² Torr. The results are analyzed from the standpoint of the possible mechanisms for anomalous plasma generation — collisional nonresonance diffusion of electrons in velocity space, leading to enrichment of the distribution function in fast particles, and the collapse of Langmuir waves in the gap at the high energies of the beam produced when the wires of the grid are bridged by the quenching pulse and and the current is blocked. Zh. Tekh. Fiz. 67, 15–21 (June 1997)     

Characteristics of nonlinear reflection of radiation associated with waverfront reversal by a surface

The dependence of the nonlinear reflection coefficient R of a mirror with a wavefront reversing surface on the intensity I of the reference wave is analyzed in terms of a phenomenological model of a medium having a nonlinear Fresnel reflection amplitude coefficient φ. Substantial differences are revealed for media having different signs of the nonlinearity coefficient β=(dφ/dI). It is shown that R is related to the magnitude D of the dynamic range of the wavefront reversing mirror by the expression RD=Q_s' where Q_s is a parameter which defines the “quality” of the nonlinear medium. Far-Eastern State Academy of Communications. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 8, pp. 68–70, August, 1997.     

Propagation of magnetostatic waves in unsaturated ferrite films with a strip domain structure

The propagation of surface and volume magnetostatic waves in unsaturated films of yttrium iron garnet is studied experimentally for the case when the wavelength greatly exceeds the domain width, while the domain width is comparable to the film thickness. The characteristics of these waves are examined for symmetric linear, asymmetric linear, and symmetric zigzag strip domain structures in the films. These characteristics cannot be explained by a theory based on averaging the magnetization over all the domains. Zh. éksp. Teor. Fiz. 111, 1016–1031 (March 1997)     

Electron-stimulated desorption of potassium and cesium atoms from an oxidized molybdenum surface

The yield and energy distributions of potassium and cesium atoms emitted in electron-stimulated desorption (ESD) from a molybdenum surface, oxidized to different extent and maintained at 300 K, have been measured by the time-of-flight technique with a surface ionization detector. The ESD threshold for potassium and cesium atoms lies around 25 eV, irrespective of molybdenum oxidation state. In the case of molybdenum coated by an oxygen monolayer, secondary thresholds at ∼40 and ∼70 eV have been observed, as well as atomic energy distribution tailing down to very low energies. The most probable kinetic energies of the atoms are a few tenths of one eV. The results are explained within a model involving Auger neutralization of the adsorbed alkali metal ions after the filling of the 2s O, 4s Mo, and 4p Mo core holes. The possibility of ESD of a neutral species as a result of oxide-cation core-level ionization has been demonstrated for the first time. Fiz. Tverd. Tela (St. Petersburg) 39, 758–761 (April 1997)