Time Evolution of Vibration-Induced Excited State Decay

A simple model consisting of two electronic levels and one vibrational mode (phonon) was theoretically studied. The electronic-vibrational interaction was linear in the vibrational displacement. The vibrational mode was taken in the harmonic approximation and was attached to the thermal bath formed by the ambient environment. The kinetic constants of the vibrational dissipation were of the second order in the vibrational-bath coupling and were taken in the Markovian limit. Although, depending on the parameters of the model, different curves of the non-radiative vibration-induced excited state decay were obtained, in general, three time intervals, corresponding to different physical behaviour, were found. In the short-time interval, small oscillations superimposed on the excited state decay were observed. They were determined by the vibrational frequency and influenced by electronic-vibrational coupling. In the middle-time interval, almost quasi-exponential decay was detected; its rate constant increased with stronger electronic-vibrational interaction and speed of vibrational relaxation. In the long-time interval, the decay was very slow and, under special conditions, even an asymptotic non-zero excited state population was observed. Its value increased with the strength of the off-diagonal electron-vibrational coupling. Links of the parameters of the model with quantum chemical terms were estimated.     

Chaos, fractals, and atomic flights in cavities

A semiclassical study is carried out of the nonlinear interaction dynamics between two-level atoms and a standing-wave field in a high-finesse cavity. As a result of atomic movement or wave amplitude modulation, a dynamic local instability occurs in a strongly coupled atom-field system. The appearance of dynamical Hamiltonian chaos, fractals, and Lévy flights is demonstrated for the models of two experimental devices: a (micro)maser with thermal Rydberg atoms and a microlaser with cold atoms. Numerical simulation showed that the manifestations of classical chaos, atomic fractals, and flights can be observed in the appropriate real experiments. Attention is drawn to the prospects provided by work on the atom-field systems in the coupling-modulated high-finesse cavities for further investigation of the quantum-classical correspondence, quantum chaos, and decoherence.     

Beta-exposure in a neutron activation laboratory

Summary In virtually all neutron activation analysis laboratories, researchers are given film badges known as thermoluminescence dosimeters (TLD's) that are monitored on a monthly basis. Sometimes additional pocket dosimeters are worn to get a daily reading of exposure, while in other instances ring badges are worn to assess beta doses. However, more than often little consideration is given to beta-exposure rates that arise from the plethora of radionuclides produced in the many types of samples irradiated. A common mistake is to assess gamma-exposures of activated samples that rely on the use of a beta-shield on the survey meter. Our experimental results have shown that there are many high energy beta-particles from neutron activated samples that can easily penetrate the beta-shield and thus give an underestimation of the total beta-exposure.     

GaAsN/AlAs/AlGaAs double barrier quantum wells grown by molecular beam epitaxy as an alternative to infrared absorption below 4 μm

In this work, we report on the design, growth and characterization of GaAsN/AlAs/AlGaAs double barrier quantum well infrared detectors to achieve intraband absorption below 4 μm. Due to the high effective mass of N-dilute alloys, it is common for these N-containing double barrier quantum well structures to have more than one bound state within the quantum well, enabling the possibility of achieving multispectral absorption from these confined levels to the quasi-bound. Based on a transfer matrix calculation we will study the influence of the potential parameters, in particular the well width and the introduction of a GaAs spacer layer in between the N-well and the AlAs barriers. We will compare the case in which there are two confined levels with the case in which only one level is bound, like in the conventional AlGaAs/AlAs/GaAs structures. On the basis of the simulation, we have grown and characterized some N-containing double barrier detectors. Moreover, an optimization of the post-growth annealing treatments of the GaAsN quantum well structures has also been performed. Finally, room temperature absorption measurements of both as-grown and annealed samples are presented and analyzed.     

Modified Three-Dimensional Formulations of Bending Problems of Homogeneous Plates and Beams under Complex Fixing Conditions

Modified three-dimensional formulations of bending problems of homogeneous elastic plates and beams are considered. Modification of the known three-dimensional formulations reduces to using additional constraints imposed on displacement functions. An advantage of the formulations proposed is that complex fixing conditions of plates and beams can be taken into account.     

Sub-Doppler and Doppler spectroscopy of DCN isotopomers in the terahertz region: ground and first excited bending states (v1v2v3)=(0 1 0)

The rotational spectra of the deuterium cyanide isotopic species DCN, D¹³CN, DC¹⁵N, and D¹³C¹⁵N were recorded in the vibrational ground and first excited bending state (v₂=1) up to 2 THz. The R-branch transitions from J=3←2 to J=13←12 were measured with sub-Doppler resolution. These very high resolution (∼70 kHz) and precise (±3-10 kHz) saturation dip measurements allowed for resolving the underlying hyperfine structure due to the ¹⁴N nucleus in DCN and D¹³CN for transitions as high as J=10←9. Additional high JR-branch (J=25←24 to J=28←27) transitions around 2 THz and direct l-type (ΔJ=0, J=19 to J=25) transitions from 66 to 118 GHz were recorded in Doppler-limited resolution. For the ground state of D¹³C¹⁵N, the J=1←0 transition was measured for the first time. The transition frequency accuracies for the other deuterated species were significantly improved. These new experimental data, together with the available infrared rovibrational data and previously measured direct l-type transitions, were subjected to a global least squares analysis for each isotopomer. This yielded precise sets of molecular constants for the ground and first excited vibrational states, including the nuclear quadrupole and magnetic spin-rotation coupling constants of the ¹⁴N nucleus for DCN and D¹³CN. The hyperfine structure due to the D, ¹³C, and ¹⁵N nuclei have not been resolved, but led to a broadening of the observed saturation dips.     

Ricci and Matter Collineations of Locally Rotationally Symmetric Space-Times

A new method is presented for the determination of Ricci Collineations (RC) and Matter Collineations (MC) of a given spacetime, in the cases where the Ricci tensor and the energy momentum tensor are non-degenerate and have a similar form with the metric. This method reduces the problem of finding the RCs and the MCs to that of determining the KVs whereas at the same time uses already known results on the motions of the metric. We employ this method to determine all hypersurface homogeneous locally rotationally symmetric spacetimes, which admit proper RCs and MCs. We also give the corresponding collineation vectors. These results conclude a long due open problem, which has been considered many times partially in the literature.     

Application of quasi-steady-state plasma streams for simulation of ITER transient heat loads

The paper presents experimental investigation of energy characteristics of the plasma streams generated with quasi—steady—state plasma accelerator QSPA Kh-50 and adjustment of plasma paramenters from the point of view its applicability for simulation of transient plasma heat loads expected for ITER disruptions and type I ELMs. Possibility of generation of high-power magnetized plasma streams with ion impact energy up to 0.6 keV, pulse length 0.25 ms and heat loads varied in wide range from 0.5 to 30 MJ/m² has been demonstrated and some features of plasma interaction with tungsten targets in dependence on plasma heat loads are discussed.     

Vacuum ultraviolet absorption in Xe+CF4 and Kr+CF4 mixtures

The absorption spectra of Xe + CF₄ and Kr + CF₄ mixtures in the vacuum ultraviolet region are presented. A considerable broadening of the short-wavelength wings of the atomic absorption lines is explained by a repulsive character of the Rg*-CF₄ interaction potential. This repulsive character is also considered to be the most probable reason for the anomalously small cross sections of the quenching of electronically excited atoms of rare gases by CF₄ molecules. The influence of CF₄ on the emission rate of the trapped resonance radiation of Xe from the cell is discussed.