A comparison of spin relaxation and local motion between symmetrically and asymmetrically ring-substituted bisphenol units in dissolved polycarbonates

Carbon-13 and proton spin-lattice relaxation times were measured at two field strengths on solutions 10% by weight of two polycarbonates in C₂D₂Cl₄ from ?20 to +120°C. The first polycarbonate is an asymmetrically substituted form with one chlorine on one of the two phenylene aromatic rings of the bisphenol unit, whereas the second polycarbonate is symmetrically substituted with two chlorines on each of the two rings. The nuclear spin relaxation data are interpreted in terms of several local motions likely in these polymers. Segmental motion was described by the Hall–Helfand correlation function. Segmental motion in the monosubstituted polycarbonate is somewhat slower than in unsubstituted polycarbonate, whereas segmental motion in the tetrasubstituted polycarbonate is considerably slower. Phenylene ring rotation is observed in unsubstituted polycarbonate and in the monosubstituted polycarbonate above 40°C. Below 40°C in the monosubstituted species, and at all temperatures in the tetrasubstituted species, ring rotation is replaced by ring libration as the predominant motion contributing to spin lattice relaxation. In addition, the rotational motion of the two types of rings in the asymmetric monosubstituted form are very similar although not identical. The substituted ring is slightly less mobile than the rings of unsubstituted polycarbonate. This indicates a strong coupling of ring motion, although the coupling leads to less than synchronous motion. Methyl group rotation is present in both polymers and is little affected by the various structural modifications.     

Multiphonon renormalization of the spectrum of two-dimensional excitons in a magnetic field

The renormalization of the dispersion law for two-dimensional excitons in a magnetic field is studied by the Green's-function method taking into account multiphonon processes.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 4, pp. 3–7, April, 1987.     

Coercivity analysis in R17Fe83−χBχ magnets

We studied the coercivity in magnets of composition R₁₇Fe_83−χB_χ (R = Nd, Pr and χ = 8, 30), using measurements of the coercive field H_c, its angular dependence, and the magnetic viscosity coefficient S_v, for temperatures between 4.2 and 500 K. The results are discussed in relation to a model which does not specifically consider the detailed mechanisms involved in magnetization reversal, but which provides information about the magnetic properties in the activation volume v where magnetization reversal is initiated. It is concluded that the ordering temperature in v tends to be slightly smaller than in the bulk and that the room temperature anisotropy in v is not strongly reduced with respect to the bulk value. Finally, a direct evaluation of the dipolar interactions is in good agreement with results obtained from H_c(T).     

Deuteron and neutron structure functions and the effect of relativistic Fermi motion

The deep-inelastic deuteron structure function (SF) F₂^D in the covariant approach in the light-cone variables is considered. The neutron SF F₂ⁿ is extracted from the deuteron and proton experimental data taking into account the relativistic deuteron model and the parametrization of F₂ⁿ is obtained. The effect of the relativistic Fermi motion is estimated to be 6% at x0.7. The extracted neutron SF is used to verify the Gottfried sum rule. It is shown that the violation of the flavour symmetry of the sea can be large with increasing Q².     

Ferroelectric polarization switching in nylon-11

Cold-drawn Nylon-11 films, which were prepared by stretching the melt-quenched films to a draw ratio of 2.8: 1 at room temperature, were found to exhibit an electric displacement versus electric field hysteresis loop. The results confirmed that the Nylon-11 film exhibited ferroelectric behavior at or below room temperature. The coercive fields were 65, 98, 125, 160, and 215 MV/m at 20, 0, ?20, ?40, and ?60°C and the remanent polarization at ?20°C (where there was considerably less dc conduction) was 56 mC/m². Switching of the polarization was almost completed within 20 ms.