近红外光谱的水稻抗性淀粉含量测定研究

用化学法测定水稻抗性淀粉含量耗时长、成本高,为此,探索了基于近红外光谱技术(NIRS)的水稻抗性淀粉含量测定新途径。首先,采集了62份抗性淀粉含量差异较大的水稻的光谱数据,将光谱数据和已测定的化学值数据导入化学计量学软件,采用偏最小二乘法(PLS)建立了抗性淀粉含量的近红外定标模型,对不同预处理得到的预测模型进行了内部验证和外部验证。结果如下：内部交叉验证方面,未处理、MSC+1thD预处理、1thD +SNV预处理的决定系数(R2)分别为0.920 2,0.967 0,0.976 7,预测均方根误差(RMSEP)分别为1.533 7,1.011 2,0.837 1。外部验证方面,未处理、MSC+1thD预处理和1thD +SNV预处理的决定系数(R2)分别为0.805,0.976,0.992,绝对误差平均值分别为1.456,0.818,0.515,预测值和化学值之间没有显著差异(Turkey法多重比较),说明以近红外光谱分析法代替化学测定法是有可能的。在不同预处理方法之中,1thD+SNV的预处理方法无论内部验证还是外部验证都具有较高的决定系数和较低的误差值,定标模型精度更高,误差更小。     

射频交替溅射法制备的NiZn铁氧体薄膜的结构与磁性

使用交替靶射频溅射的方法在不同基底上制备得到了成分为NixZn1-xFe2O4的铁氧体薄膜,研究了NiZn铁氧体薄膜的生长条件,探讨了不同工艺条件对薄膜性能的影响,目的是提高薄膜饱和磁化强度Ms,降低薄膜矫顽力Hc,改善薄膜的软磁性能,以满足其在高频薄膜器件应用方面的需要．实验表明：沉积态薄膜即为尖晶石结构．并且通过不同实验条件对NiZn铁氧体薄膜性能影响的研究,得到了最佳的NiZn铁氧体薄膜的制备条件．     

Orbital effect in the stationary axisymmetric field

This paper uses an elegant mathematical method to calculate the orbital effects in the axisymmetric field created by the spinning mass with electric charge and a large number of magnetic monopoles. In comparison with that in the Reissner-Nordstroem （R-N） field, the correction terms caused by the spinning mass decrease the advanced effect as the revolution direction of the test particle coincides with that of the Kerr field, however, the correction terms caused by the spinning charged mass increase the advance effect as the revolution direction of the test particle coincides with that of the Kerr-Newman-Kasnya （KNK） field. Generalizing the effect in the axisymmetric field, it obtains interesting results by discussing the parameters of the celestial body, these parameters provide a feasible experimental verification of the general relativity.     

过渡流下近壁插入圆柱对壁面强化传热的影响

本文利用基于复合网格系统的计算方法,对Re=50～1200的近壁插入圆柱流场进行数值模拟,研究过渡流状态下在壁面附近插入圆柱对下游壁面传热强化的影响。并基于低速循环水槽流动实验台,采用粒子成像测试法(PIV)对Re=100～500的近壁插入圆柱流场进行可视化实验研究,验证了数值模拟方法的可靠性。研究结果表明:近壁插入圆柱流场在Re=100时进入过渡流状态;Re直接影响圆柱尾流中周期性涡脱和壁面涡岛的发生位置及其洗刷效应的大小,随着Re的增大,洗刷效应明显增强,因而,过渡流范围内Re越大,圆柱下游壁面传热强化越大。     

用拉曼光谱研究抗癌药物落羽松醇和它的类似体

用拉曼光谱研究抗癌药物落羽松醇和它的类似体郑思定，舒莲美，洪田博喜（复旦大学分析测试中心上海２００４３３）（日本岗山理科大学）ＲａｍａｎＳｐｅｃｔｒｏｓｃｏｐｉｃＩｎｖｅｓｔｉｇａｔｉｏｎｏｆｔａｘｏｌａｎｄＩｔｓＡｎａｌｏｇｕｅｓ￥ＺｈｅｎｇＳｉｄ...     

在黑龙江省珠算协会四届三次理事会议上的讲话

各位领导、各位理事、同志们: 今天,省珠协在这里召开四届三次理事会议,总结1995年工作.安排部署1996年工作,并且表彰珠算技术等级鉴定工作先进单位,这对于珠算协会的发展和促进我省珠算科学事业的蓬勃发展具有重要意义。我代表黑龙江省科协对会议的召开表示热烈祝贺！向出席会议的全体同志并通过大家向全省广大珠算科学工作者致以亲切的问候！     

多分支中性受体的合成及αω-二羧酸阴离子识别研究

Two new multi-armed neutral receptors 1 and 2 containing thiourea and amide groups were synthesized by simple steps in good yields. Receptors 1 and 2 have a better selectivity and higher association constants for malonate anion than other anions examined by the present work. In particular, distinct color changes were observed upon addition of dicarboxylate anions to the solution of 1 in DMSO. The UV-Vis and fluorescence spectra data indicate that a 1 ： 2 stoichiometry complex was formed between compound 1 or 2 and dicarboxylate anions of shorter carbon chain, and a 1 ： 1 stoichiometry complex was formed between compound 1 or 2 and dicarboxylate anions of longer carbon chain through hydrogen bonding interactions.     

Study on Syntheses and Anti-bacterial Activities of Some New Transition Metal Complexes with Schiff Base Ligand Containing Pyridine and Amide Moieties

Several new transition metal complexes using Schiff base containing pyridine and amide moieties (N, N′-bis(β-salicylaliminoethyl)-2, 6-pyridinedicarboxylic amide, H4L) as the ligand have been prepared. Their compositions and structures are corroborated by elemental analysis, IR, UV, ^1H NMR, DTA-TG and molar conductivity data.Their anti-bacterial activities have been studied by microcalorimetry. The result shows that the ligand and all complexes are potential anti-bacteria reagent and their inhibitory capacities are concentration-depended. The Mn complex has the strongest inhibitory capacity.     

Selective Synthesis of [2＋2] Macrocyclic Schiff Bases from Chiral 1,4-Diamines

[2＋2] macrocyclic Schiff bases of three kinds have been synthesized from chiral 1,4-diamines by use of different methods. Macrocyclic Schiff bases 1a-1c have been selectively obtained based on a non-templated dilution method from chiral 1,4-diamines a-c and dialdehyde DA1, whereas macrocycles 2a-2c have been selectively produced from reaction of diamines a-c and dialdehyde DA2 in the presence of boric acid as templates. Macrocyclic Schiff bases 3a-3c have been afforded in high selectivity from diamines a-c and dialdehyde DA3 by means of sodium-template. All the titled compounds have been confirmed by ^1H NMR and ESI-MS analyses.