一种新型的蓝光发射材料δ-Alq3的制备与光谱分析

制备了一种新型的蓝光发射材料δ-Alq3,测试了其红外吸收光谱、X射线衍射谱、紫外-可见光吸收光谱、光致发光光谱和电致发光光谱,并通过与δ-Alq3的光谱性能的比较,研究了Alq3分子空间结构与光谱性能之间的关系.结果表明:δ-Alq3分子空间结构经过真空加热发生变化,生成对称性较差的δ-Alq3;分子空间结构的改变引起Alq3分子中酚环电子云密度的降低和相邻分子间的共轭效应的减弱,导致在紫外-可见吸收光谱中δ-Alq3长波段的π-π*电子跃迁吸收峰向短波方向的移动,在光致发光光谱中δ-Alq3的最大发射峰波长为480 nm,比α-Alq3的最大发射峰波长(515 nm)蓝移35 nm,在电致发光光谱中α-Alq3和δ-Alq3的最大发射峰波长都为520 nm.     

Improved light extraction of organic light emitting diodes with a nanopillar pattering structure

We have investigated the properties of organic light emitting diodes(OLEDs)with a nanopillar patterning structure at organic–metal or organic–organic interfaces.The results demonstrate that the introduction of a nanopillar structure can improve the light extraction efficiency greatly.We also find that the number,height,and position of nanopillars all affect the light extraction of OLEDs.The maximum power efficiency of a device with an optimized nanopillar patterning mode can be improved to 2.47 times that of the reference device.This enhancement in light extraction originates from the improved injected carriers,the broadened charge recombination zone,and the intensified wave guiding effects.     

Landau Damping of Collective Modes in a Disc-Shaped Bose-Einstein Condensate

We investigate the Landau damping of collective modes in an anisotropic Bose Einstein condensate （BEC）, Based on divergence-free analytical solutions for the ground state wavefunction of the condensate and all eigenvalues and eigenfunctions for thermal excited quasiparticles, we make a detailed analytical calculation on coupling matrix elements. We evaluate the Landau damping of a quadrupole collective mode in the BEC with a disc-shaped trap and discuss its dependence on temperature and particle number of the system.     

具有二阶和三阶非线性一维光子晶体中的耦合模孤子

研究同时具有二阶和三阶非线性的一维光子晶体中的耦合孤子动力学. 从Maxwell方程出发,利用多重尺度法,导出了光学整流场与两个基频电场包络的非线性耦合模方程组,给出了耦合模方程组的孤子解. 结果表明,由于二阶非线性导致的光学整流场对基频电场有调制作用,使得两个基频电场分量可以呈现为亮孤子-亮孤子、暗孤子-暗孤子及亮孤子-暗孤子对;当两个基频电场的振动频率趋于光子晶体频带的带边频率时,光学整流场消失.     

Magnetic Properties of Exchange-Coupled Dual-Layer SmTbCo Thin Films

Exchange-coupled SmTbCo dual-layer media are prepared by an r.f magnetron sputtering system and their magnetic properties are investigated. The prepared SmTbCo dual layer is composed of a 340 emu/cm^3 TM-rich readout layer and a 5.80 kOe RE-rich memory layer, meeting the requirements of high saturation magnetization and large coercivity for hybrid recording. Through exchange coupling, the coercivity of the high-saturation- magnetization SmTbCo layer is greatly enhanced from 1.85 to 5.96 kOe. The calculated interface wall energy for Sm6.65Tb12.35Co81 （20nm）/Sm1.22Tb42.16Co56.62 （20hm） is about 3.85erg/cm62. The reversal magnetization of the SmTbCo exchange-coupling dual-layer films is analysed based on a micro-magnetic model.     

常规压缩机混合工质循环气体液化系统研究

小型混合工质低温气体液化系统具有结构简单紧凑、尺寸小型化、投资省、易撬装化、易操作、应用灵活、安全性好等优点,其驱动采用全封闭油润滑压缩机,为常规制冷部件,制造工艺成熟,可市场化采购,成本大大降低。文中介绍搭建的常规压缩机驱动的混合工质低温气体液化实验台,进行了多次实验,并对系统的降温特性、能耗、压缩机性能等进行了测试。实验测试结果表明,常规油润滑压缩机性能稳定、耐用可靠,作为低温气体液化系统的驱动动力是可行的。     

Ultraslow optical solitons via electromagnetically induced transparency: a density-matrix approach

We study the ultraslow optical solitons in a resonant three-level atomic system via electromagnetically induced transparency under a density-matrix (DM) approach. The results of linear and nonlinear optical properties are compared with those obtained by using an amplitude variable (AV) approach. It is found that the results for both approaches are the same in the linear regime if the corresponding relations between the population-coherence decay rates in the DM approach and the energy-level decay rates in the AV approach are appropriately imposed. However, in the nonlinear regime there is a small difference for the self-phase modulation coefficient of the nonlinear Schr\"{o}dinger equation that governs the time evolution of probe pulse envelope. All analytical predicts are checked by numerical simulations.     

具有穿插界面结构的高效绿光有机电致磷光器件

以传统有机电致磷光器件ITO/NPB/CBP∶Ir(ppy)₃/BAlq/Alq₃/LiF/Al为研究对象,在NPB/CBP∶Ir(ppy)₃、CBP∶Ir(ppy)₃/BAlq及BAlq/Alq₃界面处构造交互穿插结构。器件的光电性能测试表明:交互穿插结构一方面能够降低电流密度,减少高电流密度下磷光猝灭中心的形成;另一方面能增加载流子复合界面面积,从而分散界面三线态激子,降低三线态-三线态激子的猝灭。此外,界面凸起的存在还有利于器件的光耦合输出。实验结果表明:当穿插厚度为10 nm,器件的最大电流效率达到34.0 cd/A,与传统器件的电流效率18.7 cd/A相比,提高了55%。     

Local Density of States Modulated by Strain in Marginally Twisted Bilayer Graphene

In marginally twisted bilayer graphene, the Moiré pattern consists of the maximized AB(BA) stacking regions,minimized AA stacking regions and triangular networks of domain walls. Here we realize the strain-modulated electronic structures of marginally twisted bilayer graphene by scanning tunneling microscopy/spectroscopy and density functional theory(DFT) calculations. The experimental data show four peaks near the Fermi energy at the AA regions. DFT calculations indicate that the two new peaks ...     

漆酶催化氧化水中有机污染物*

漆酶是一种含铜的多酚氧化酶, 属于铜蓝氧化酶蛋白, 能催化氧化多种难降解的有机污染物。漆酶催化氧化水中有机污染物具有底物广泛、能耗低、易操作、环境友好等优点,是一项前景广阔的生物处理技术。本文综述了漆酶对水中有机污染物的催化降解,主要从漆酶的化学组成、结构、催化降解机理、漆酶的固定化、影响因素（溶液pH值、温度、金属离子、营养因子、有机溶剂、漆酶的浓度、底物的初始浓度等）、降解的动力学以及漆酶在处理水中有机污染物的应用等五个方面介绍了相关的研究进展。漆酶催化氧化有机物的机理主要表现在底物自由基中间体的产生和氧气还原成水两个方面。本文提出了目前漆酶催化氧化水中有机污染物存在的主要问题,并展望了漆酶降解水体中有机污染物的发展方向。