基于酸度诱导的HSA与BDE154的光谱和计算模拟研究

在不同酸度条件下（pH＝3.0,6.0,7.4,9.0）诱导人血清白蛋白（HSA）进行质子化或去质子化,以研究其与小分子2,2',4,4',5,6'-六溴联苯醚（BDE154）的结合情况.首先将HSA与BDE154进行半柔性对接,发现BDE154与HSA周围的残基,如：酪氨酸150、赖氨酸195、赖氨酸199等存在较强的疏水相互作用.然后通过分子动力学模拟技术研究HSA在不同质子化状态下的动力学行为和热力学性质,可知过多的正电荷使HSA或者HSA-BDE154的系统稳定性变差.最后对HSA-BDE154的结合自由能进行预测,并对分子动力学模拟结果进行二级结构分析,结果表明HSA-BDE154复合物体系中随着酸度的增大,配体的结合对HSA的去螺旋过程有促进的作用.     

具奇系数发展型p-Laplace不等方程整体解的不存在性

考虑两类带奇性系数发展型p-Laplace不等方程整体非负解的不存在性,也即要证明某些拟线性抛物型方程的非线性Liouville定理.通过先验估计,证明了整体解在某个带参数的函数空间中的不存在性.当只考虑连续整体解时,可选取不带参数的函数空间并证明整体解在其中的不存在性.     

Three-dimensional size and orientation of the precipitates in AZ91 magnesium alloys measured by TEM techniques

Knowledge of the microscopic structure, including three-dimensional (3-D) size and orientation of the precipitates, is essential to fully understand the mechanical properties of the magnesium alloys and designing the alloys with better performance. Analytical TEM with high spatial resolution offers the simultaneous measurements of 3-D size, structure, orientation, composition of the precipitates from one typical sample along an established crystallographic axis. Besides popular Burgers orientation relationship (OR), other ORs such as Pitsch--Schrader OR, Crawley OR, Potter OR and a new OR with the form of [0001]_α 1.0° from [311]_γ and (11\bar 20)_α 2.0° from (03\bar 3)_γ between the magnesium matrix and the precipitate γ -Mg₁₇Al₁₂ are identified by TEM imaging and diffraction techniques. As a case study, the thicknesses of the individual precipitates with Burgers OR are further measured to be 100--200~nm through both electron energy-loss spectroscopy and x-ray energy dispersive spectroscopy combining differential x-ray absorption and extrapolation, which are in agreement with the overall 3-D size statistic distribution results obtained through analysing various samples along various directions. Furthermore, the fabricated wedge-shape structure provides a platform on which to study the dependence of the interfacial strain on the variation of the thickness.     

计算全息检测非球面干涉场的理论分析与实验结果

本文应用光学全息术及傅里叶光学的理论对计算全息图干涉检测非球面面形的光路及干涉场进行了理论分析,提出了其干涉场为不定域干涉的观点,并在实验中予以证实.     

光纤化学传感技术研究近况

光纤化学传感器作为传感器的一个重要分支,结合了化学和光学的相关技术,将化学制膜、光纤技术以及化学分析中的分光光度法、拉曼光谱、荧光光谱、折射率检测等方法相融合,以其微型化,抗电磁干扰,传输信息量大,拥有自身参比等特点不断向前发展。简要综述了光纤化学传感技术研究近况和未来的发展趋势。重点对光纤pH化学传感器、光纤离子化学传感器和光纤气体化学传感器进行了介绍。简要分析了常见的敏感膜制备方法如化学键合法和溶胶凝胶(sol-gel)等方法。新型光纤——微结构光纤的出现为光纤化学传感器开辟了新的发展方向。由于其具有大的内表面积,结构设计灵活多样,光纤内部提供感应场所等特点,快速度成为光纤化学传感器的重要发展方向和研究热点。对微结构光纤衍生而来的新型光纤化学传感器进行了详细评述, 最后对光纤化学传感器的未来进行展望。     

磁逆多光子非线性Compton散射的谱功率

相对论电子在强磁场中的磁逆Compton散射是一种重要的γ射线辐射机制。虽然对该问题的研究已有二十多年的历史，但对磁逆多光子非线性Compton散射谱功率的研究尚未见报道。本文采用电子与光子非弹性碰撞模型，首次给出了磁逆多光子非线性Compton散射的谱功率。     

Electrical characteristics of AlInN/GaN HEMTs under cryogenic operation

Electrical properties of an AlInN/GaN high-electron mobility transistor (HEMT) on a sapphire substrate are investi-gated in a cryogenic temperature range from 295 K down to 50 K. It is shown that drain saturation current and conductance increase as transistor operation temperature decreases. A self-heating effect is observed over the entire range of temperature under high power consumption. The dependence of channel electron mobility on electron density is investigated in detail. It is found that aside from Coulomb scattering, electrons that have been pushed away from the AlInN/GaN interface into the bulk GaN substrate at a large reverse gate voltage are also responsible for the electron mobility drop with the decrease of electron density.     

三波长激光雷达拟合卷云的粒子形状

卷云在全球出现的概率可达30%,其散射特性在气候模式、光辐射传输和遥感领域都具有非常重要的意义。卷云的散射特性主要由冰晶粒子形状、尺度谱、折射率等因素所决定。利用355, 532和1 064 nm三个波长激光雷达数据反演卷云的后向散射系数颜色比,利用模拟计算获得不同形状冰晶粒子的卷云在上述三个波长上的后向散射系数颜色比,通过拟合得出被测卷云的冰晶粒子形状。拟合结果表明,合肥上空卷云中冰晶粒子大部分可能呈聚合物状。