重离子核反应中丰中子余核产额的标度规律

在重离子碰撞（HICs）的实验数据和动力学模拟的反应中发现了丰中子余核产额的标度现象。在这种标度现象中,两个同位旋不同的炮弹碎裂反应产生的余核中,不同中子丰度差的余核的信息熵不确定度的差具有一致的分布。利用反对称化分子动力学模型（AMD）模拟并联合退激发模型（GEMINI）模拟了140 AMeV 58,64Ni+9Be碰撞体系中余核的产额,并展示了实验测量的余核已经理论模拟得到的余核的标度现象。由于信息熵方法对反应系统是否处于平衡状态没有要求,不仅可以用于处于平衡态系统的核物质研究,也可以用于动力学变化过程中的核物质性质研究。信息熵方法将为HICs中的核物质演化研究提供新的理论分析方法。A scaling phenomena has been discovered for fragments produced in heavy-ion collisions both in the measured experiments and in the simulated reactions by transport model. In this scaling phenomena, the information entropy uncertainty difference between isobars with different neutron-excess has a uniform distribution between two reactions. The simulated reactions of 140 AMeV 58,64Ni+9Be by using the asymmetric molecular dynamics(AMD) model plus the sequential decay code GEMINI are analyzed to show the scaling phenomena of fragments. Since the application of information entropy theory does not require the system to be in equilibrium, it can be used both in the analysis of transport model and thermodynamics models. The advantage of the information entropy theory provides a new method to study the dynamical evolution of nuclear matter inheavy-ion collisions.     

MTsPc催化H2S还原硝基苯反应性能的研究

就工业气休中有害物质Ｈ２Ｓ的综合利用开发进行了有益的探索,采用ＭＴｓＰｃ（Ｍ＝Ｆｅ,Ｃｏ,Ｎｉ,Ｃｕ）做催化剂,水做溶剂,研究了催化剂物种及浓度、碱浓度反应温度对Ｈ２Ｓ还原硝基苯制备苯胺反应性能的影响。结果表明,在诸多催化剂中双核磺化酞菁钴（ＣｏＰｃ－ＰｃＣｏ）催化活性最高,且得到最佳反应条件为：氨水浓度０．６ｍｏｌ／Ｌ,反应温度４０℃,催化剂质量浓度１ｇ／Ｌ,在此条件下苯胺的产率达３５．９％,表明在传统的脱硫工艺上加以技术改造不仅是可行的,而且是有效的。     

液晶光学相控阵可编程光束偏转研究

研究了一种一维透射式向列相液晶光学相控阵.建立了器件的数学模型,根据Frank-Oseen液晶连续体弹性形变理论计算了电场作用下液晶指向矢分布,定量分析了器件的相位延迟及衍射特性.研制了含1 024个驱动电极的实际器件,由FPGA对电极驱动电压进行可编程控制.经实验测试,该器件可以实现60个角度的准连续随机可编程电控偏转与扫描,最大偏转角度为2.001 4°.根据器件的理论模型,对光束偏转的衍射效率进行了定性讨论,发现电极之间形成的“相位凹陷”是形成衍射旁瓣的直接原因.     

QuEChERS-液相色谱-串联质谱法测定蔬菜中105种农药残留

通过优化QuEChERS前处理方法并结合液相色谱-串联质谱（LC-MS/MS）技术建立了蔬菜中105种典型杀虫剂、杀菌剂、除草剂、植物生长调节剂的多残留测定方法。目标化合物使用乙腈提取,以150 mg乙二胺-N-丙基硅烷（PSA）、150 mg封端十八烷基键合硅胶吸附剂（EC-C₁₈）、30 mg石墨化炭黑（GCB）作为基质提取液净化剂。实验结果表明,在0.010~0.200 mg/L范围内,105种目标化合物的线性相关系数（r）>0.99,方法定量限为0.010 mg/kg;3个添加水平的回收率范围为68.2%~108%,相对标准偏差（RSD）为1.02%~11.8%。该方法快速简便,净化效果好,可用于蔬菜中日常农药残留的测定。     

气相中卤代苯离子-分子反应产物的串联质谱研究

应用碰撞诱导解离技术研究了氯代苯、溴代苯和碘代苯离子-分子反应产物的碎裂反应特性,与联苯的分子离子和质子化溴代联苯的碰撞诱导解离谱比较获得了产物离子的结构信息.     

2-(2′-噻唑偶氮)-5-二乙胺基酚的晶体结构

用 Philips PW-1100型单晶衍射仪收集了2-(2′-噻唑偶氮)-5-二乙胺基酚晶体的三维衍射数据.应用最小函数法和直接法测定了晶体结构.在衍射仪上测得晶胞常数 a=20. 018(±0. 005),b=8. 894(±0. 03) (?),c=7. 658(±0. 002) ,z=4. 空间群为P2_12_12_1. 原子的坐标参数、温度因子参数及非氢原子的各向异性温度因子参数一起进行了全矩阵最小二乘修正,最后 R 因子为0. 072,加权以后 R_W 为0. 051. 晶体结构分析结果表明:二乙胺基有效地参与了共轭体系,使二乙胺基的强助色性能得到了很好的解释.     

核子-核子碰撞截面的参数化公式

核子-核子碰撞截面(σ_NN)是描述原子核反应模型中的重要物理量。 核子-核子碰撞截面包括质子-质子碰撞截面（σ_pp）、中子-中子碰撞截面（σ_NN）和中子 质子碰撞截面（σ_np）, 它们随着核子能量与核物质密度的改变而变化。人们在目前研究中提出了多种核子-核子碰撞截面关于能量和核物质密度的参数化公式,通过计算12C+12C的完全反应截面,比较了不同入射能量下使用各种核子-核子碰撞截面参数化公式对12C完全反应截面的影响。 The nucleus-nucleus cross sections(σ_NN) include the proton-proton cross section, neutron-neutron cross section, and neutron-proton cross section. σ_NN change with the variations of the incident energies and the densities. Some parameterizations of σ_NNas a function of incident energy and density have been proposed in the theoretical and experimental study of nuclear reactions. Through the calculation of reaction cross sections of 12C+12C at different energies, the effect of different σ_NN parameterizations in the reaction cross sections of 12 are studied.      

液相沉积法制备可磁分离复合光催化剂纳米球及其催化性能

采用反胶束和液相沉积法制备了一种可磁分离的复合光催化剂纳米球TiO2@SiO2@NiFe2O4,并运用X射线衍射和透射电镜对样品进行了表征.结果表明,NiFe2O4纳米粒子被包裹在SiO2内形成磁性SiO2@NiFe2O4纳米球载体,纳米TiO2粒子沉积于其表面,形成TiO2光催化壳层.光降解实验结果表明,当沉积液中硼酸与六氟钛酸铵的摩尔比为4,焙烧温度为300C时,制备的纳米球催化剂表现出最佳的光催化活性.     

High-pressure effect on inverse spinel LiCuVO4:X-ray diffraction and Raman scattering

The effect of external quasi-hydrostatic pressure on the inverse spinel structure of LiCuVO 4 was studied in this paper. High-pressure synchrotron X-ray diffraction and Raman spectroscopy measurements were carried out at room temperature up to 35.7 and 40.3 GPa, respectively. At a pressure of about 20 GPa, both Raman spectra and X-ray diffraction results indicate that LiCuVO4 was transformed into a monoclinic phase, which remained stable up to at least 35.7 GPa. Upon release of pressure, the high-pressure phase returned to the initial phase. The pressure dependence of the volume of low pressure orthorhombic phase and high-pressure monoclinic phase were described by a second-order Birch-Murnaghan equation of state, which yielded bulk modulus values of B 0 = 197(5) and 232(8) GPa, respectively. The results support the empirical suggestion that the oxide spinels have similar bulk modulus around 200 GPa.