High damping and mechanical properties of hydrogen-bonded polyethylene materials with variable contents of hydroxyls: Effect of hydrogen bonding density

Hydrogen bonding is considered to have significant effect on the interaction between polymeric chains and on the viscoelasticity of the polymeric materials. In this paper, we attempt to discuss the relationship between hydrogen bonding density and damping behavior and mechanical properties of polyethylene-based polymeric materials. For this reason, a series of pendant chain hydrogen bonding polymers(PCHBP) with different hydrogen bonding density(HBD) were prepared by quantitatively changing the content of pendent hydroxyl groups on the main chain of polyethylene. It was found that PCHBP with low HBD showed similar properties to polyethylene, indicating that the property of the materials was dependent mainly on the structure of the main chain. However, PCHBP with high HBD exhibited two tanδ peaks and a platform of loss modulus as well as a high storage modulus(about 400 MPa) at the second tanδ peak temperature, demonstrating that a polymeric material with high strength and damping properties was obtained. More importantly, the maximum of loss modulus showed a linear increase with the HBD, indicating that a higher HBD greatly improved the damping properties of the polymeric materials.     

六甲基磷酰胺在有机合成中的应用

综述了近20年来六甲基磷酰胺(HMPA)作为溶剂对有机反应的显著影响, 并着重总结HMPA所发生的化学反应及其在有机合成中的应用．     

多孔介质中两相不可压缩不易混溶渗流问题的特征配置法

多孔介质中两相不可压缩不易混溶渗流问题是非线性偏微分方程的耦合系统,其中压力方程是椭圆的用配置法逼近,而饱和度方程是对流占优的抛物方程,用特征配置法来逼近,并且证明了数值解的存在唯一性,最后得到了最优的误差估计.     

薄壁弯曲结构有限元计算精度研究

基于h-p型有限元精度计算法,以薄壁弯曲结构为研究对象,系统地介绍了实体单元常见的分类方法及优缺点;通过理论公式推导了薄壁弯曲结构发生弹性和弹塑性变形时的位移和应力理论解;采用有限元法计算数值解,研究了影响有限元计算精度的因素和规律,并用算例证实了研究结果的合理性。研究结果表明:当单元类型、积分方式、阶次、长高比相同时,只有1层实体单元情况下得到的计算误差总是大于多层单元;只要严格控制单元长高比为1左右,单元层数不小于4层,采用一阶全积分六面体单元就可以控制位移及应力误差在5%以内;当采用一阶减缩积分六面体单元,只需2层单元就可以控制弹性位移误差在1%左右,但此时应力误差达30%以上,对于塑性变形,单元层数达6层时其位移误差仍达8%以上;对于二阶六面体及二阶四面体单元,只需2层单元,且不需严格控制单元长高比为1左右就可以使位移及应力计算误差在5%以内。     

企业与高校联手,产品与教改结合共同推进光电学科实验教学

分析了当前高校实验教学特别是在光信息及光电子领域中存在的现状,探讨了现阶段在实验室建设和实验教学改革方面需要解决的问题,结合大恒公司光电研究所开发实验的理念和实验特色,提出了建立、加强企业与高校的交流与合作,使企业搭建一个更好的平台去为高校教学及科研服务。详细阐述了大恒光电实验产品的主题前沿、结构开放、注重基础、突出应用这四个方面的开发理念,并结合具体的实例展示了大恒光电的最新进展。     

飞秒强激光对二氧化钛金红石晶体相变的影响

该文章报道了利用显微激光拉曼光谱仪研究近红外飞秒强激光脉冲诱导二氧化钛金红石单晶所引起的相变.实验辐照时间为60s,当激光辐照平均功率增加时,锐钛矿相的拉曼振动模式强度增强,金红石相的拉曼振动模式强度减弱.通过金红石相和锐钛矿相粉体等拉曼光谱的实验,肯定了随着辐照激光功率的增大,.可以通过拉曼光谱中锐钛矿A1g B1g(515 cm-1)振动模式标志峰和金红石相Eg(445 cm-1)振动标志峰分别对应面积的比判断其相变量.     

Femtosecond pulse laser-induced self-organized nanostructures on the surface of ZnO crystal

This paper reports self-organized nanostructures observed on the surface of ZnO crystal after irradiation by a focused beam of a femtosecond Ti：sapphire laser with a repetition rate of 250kHz. For a linearly polarized femtosecond laser, the periodic nanograting structure on the ablation crater surface was promoted. The period of self-organization structures is about 180 nm. The grating orientation is adjusted by the laser polarization direction. A long range Bragglike grating is formed by moving the sample at a speed of 10μm/s. For a circularly polarized laser beam, uniform spherical nanoparticles were formed as a result of Coulomb explosion during the interaction of near-infrared laser with ZnO crystal.     

Theoretical Study of the Influence of Femtosecond Laser Wavelength on the Evolution of a Double-Minimum Electronic Excited State Wave Packet for NaRb

Employing the two-state model and the time-dependent wave packet method, the influence of femtosecond laser wavelength on the evolution of the double-minimum electronic excited state wave packet is numerically investigated. For different laser wavelengths, evolutions of the double-minimum electronic excited state wave packet with time and internuclear distance are different. One can control the evolution of the wave packet by varying the laser wavelength appropriately, which will benefit the light manipulation of atomic and molecular processes. Furthermore, study of the dynamics of the NaRb molecule may yield clues to creating an ultracold molecule.     

席夫碱大环双核锌配合物的合成与表征

本文用丙酮和乙二胺在高氯酸催化下合成了四氮杂十四环席夫碱(1),并用此化合物(1)与氧化锌和叠氮化钠反应,生成锌的双核大环配合物。通过X-射线单晶衍射和红外光谱对其进行了结构表征。该配合物属单斜晶系,C2/c空间群,晶胞参数为a=2.4914(2)nm,b=1.4 9748(13)nm,c=1.26800(11)nm;β=102.1900(10)°;v=4.6240(7)nm3,Z=4,Dc=1.482Mg/m3,Mr=1032.03,F(000)=2160,最终R=0.0506,wR=0.1434。该配合物中锌原子是五配位,它们分别和大环配体上的4个氮原子及叠氮根负离子两端的氮原子配位形成畸变的三角双锥构型。