反应溅射沉积技术制备燃料电池催化层的模拟

反应溅射沉积技术(RSDT)可以生成纳米大小的颗粒并有效溅射形成性能稳定的催化层,是一项崭新的催化层制备技术。为从理论上研究RSDT过程的复杂物理化学过程,本文提出了RSDT过程的三维综合数学模型,模型描述了流体流动、热/质传递,并与燃料气的化学反应和液滴的燃烧相耦合。RNGκ-ε模型用于描述湍动燃烧气流,液滴的跟踪和分析在拉格朗日框架下进行,并利用Monte Carlo方法生成了催化层的表面结构。计算结果可以为该技术的优化提供一定的参考。     

温度对吡啶离子液体性质影响的分子动力学模拟研究

运用分子动力学模拟方法研究了温度对三种吡啶离子液体[BPy][BF_4]、[HPy][BF_4]、[OPy][BF_4]热力学性质的影响,得到了每个体系的密度、自扩散系数、电导率和黏度等.研究结果表明:随着温度升高,同一种离子液体的密度减小,阴阳离子的自扩散系数明显增大,电导率升高,而黏度降低.在同一温度下,随着阳离子上烷基链的增长,离子液体的密度减小,但热力学性质的变化规律并不完全同步.烷基链长最短的[BPy][BF_4]的自扩散系数和电导率在每个温度下均为最大,而黏度最小;但烷基碳链更长的[OPy][BF_4]和[HPy][BF_4]的各种性质相差不大,甚至当温度大于323 K时,烷基链较长的[OPy][BF_4]的自扩散系数比[HPy][BF_4]的大.     

Random shortcuts induce phase synchronization in complex Chua systems

This paper studies how phase synchronization in complex networks depends on random shortcuts, using the piecewise-continuous chaotic Chua system as the nodes of the networks. It is found that for a given coupling strength, when the number of random shortcuts is greater than a threshold the phase synchronization is induced. Phase synchronization becomes evident and reaches its maximum as the number of random shortcuts is further increased. These phenomena imply that random shortcuts can induce and enhance the phase synchronization in complex Chua systems. Furthermore, the paper also investigates the effects of the coupling strength and it is found that stronger coupling makes it easier to obtain the complete phase synchronization.     

Topological probability and connection strength induced activity in complex neural networks

Recent experimental evidence suggests that some brain activities can be assigned to small-world networks. In this work, we investigate how the topological probability p and connection strength C affect the activities of discrete neural networks with small-world (SW) connections. Network elements are described by two-dimensional map neurons (2DMNs) with the values of parameters at which no activity occurs. It is found that when the value of p is smaller or larger, there are no active neurons in the network, no matter what the value of connection strength is; for a given appropriate connection strength, there is an intermediate range of topological probability where the activity of 2DMN network is induced and enhanced. On the other hand, for a given intermediate topological probability level, there exists an optimal value of connection strength such that the frequency of activity reaches its maximum. The possible mechanism behind the action of topological probability and connection strength is addressed based on the bifurcation method. Furthermore, the effects of noise and transmission delay on the activity of neural network are also studied.     

基于微分几何方法的永磁同步电动机的混沌运动的控制

永磁同步电动机(PMSM)在某些参数及工作条件下会出现混沌运动，这将危及电机传动系统的稳定运行，因此如何抑制或消除PMSM中的混沌成为保持其稳定性的关键问题.利用微分几何控制理论，首先从解析上推导出PMSM混沌运动控制律的表达式，然后对控制过程进行仿真.理论分析及数值仿真结果表明：该控制策略不仅行之有效，而且相对其他控制方法具有一定的优越性.研究结果对保证电机传动系统的稳定运行具有较好的参考价值. 关键词： 混沌控制 微分几何 准确线性化 永磁同步电动机     

Identification of denatured and normal biological tissues based on compressed sensing and refined composite multi-scale fuzzy entropy during high intensity focused ultrasound treatment

In high intensity focused ultrasound(HIFU)treatment,it is crucial to accurately identify denatured and normal biological tissues.In this paper,a novel method based on compressed sensing(CS)and refined composite multi-scale fuzzy entropy(RCMFE)is proposed.First,CS is used to denoise the HIFU echo signals.Then the multi-scale fuzzy entropy(MFE)and RCMFE of the denoised HIFU echo signals are calculated.This study analyzed 90 cases of HIFU echo signals,including 45 cases in normal status and 45 cases in denatured status,and the results show that although both MFE and RCMFE can be used to identify denatured tissues,the intra-class distance of RCMFE on each scale factor is smaller than MFE,and the inter-class distance is larger than MFE.Compared with MFE,RCMFE can calculate the complexity of the signal more accurately and improve the stability,compactness,and separability.When RCMFE is selected as the characteristic parameter,the RCMFE difference between denatured and normal biological tissues is more evident than that of MFE,which helps doctors evaluate the treatment effect more accurately.When the scale factor is selected as 16,the best distinguishing effect can be obtained.     

概率方法在布尔函数相关免疫性研究中的应用

本文揭示了布尔函数的Ｗａｌｓｈ谱及“相关度”的概率实质，证明了Ｗａｌｓｈ谱的两条重要性质，正确地揭示了多维布尔向量函数的相关免疫性与其各分量的相关免疫性之间的关系；定义了布尔向量函数的Ｗａｌｓｈ变换及Ｗａｌｓｈ谱，并由此给出了与Ｘｉａｏ－Ｍａｓｓｅｙ定理相应的判别条件。     

Controlling chaos in permanent magnet synchronous motor based on finite-time stability theory

This paper reports that the performance of permanent magnet synchronous motor (PMSM) degrades due to chaos when its systemic parameters fall into a certain area. To control the undesirable chaos in PMSM, a nonlinear controller, which is simple and easy to be constructed, is presented to achieve finite-time chaos control based on the finite-time stability theory. Computer simulation results show that the proposed controller is very effective. The obtained results may help to maintain the industrial servo driven system's security operation.     

用BP神经网络模型评价养殖区水域的富营养化——以湖州地区为例

根据养殖区水域富营养化程度主要影响因素和评价标准,用足够多的BP神经网络训练样本、检验样本和测试样本进行模拟学习,给出了区分养殖区富营养化程度的分界值,能够直观地进行不同等级富营养化程度的划分.所得到的神经网络模型具有较好的泛化能力和预测能力,减少了人为主观因素的影响,该模型有一定的客观性、通用性和实用性.实例分析表明,湖州地区养殖区外荡水域富营养化程度比较严重,处于富营养化和重富营养化状态.     

One- and Two-Photon Excited Fluorescence of CdSe and CdSe/ZnS Quantum Dots in n-Hexane

One- and two-photon absorption and excited fluorescence of the CdSe and the core-shell structure CdSe/ZnS quantum dots （QDs） in n-hexane is investigated. The linear and nonlinear absorption coefficients are measured and the two-photon-absorption cross sections of the QDs are also obtained. For both one-photon fluorescence and two-photon fluorescence, the emission efficiency of CdSe/ZnS is much higher than that of CdSe, originating from the effective surface passivation of the core-shell structure.