用Eshelby理论研究复合材料线粘弹性本构关系

本文用Eshelby微力学理论分析,得到短纤维增强材料(SFRC)和基体材料两者的粘弹性本构方程之间存在简单的正比关系。发现体积含量为f的短纤维无序取向SFRC一维力学行为,等效于体积含量为F的短纤维单轴取向SFRC在取向轴上的力学行为。     

一类求设计变量最大可行区间的优化问题

在严格保证产品性能要求的前提下,为了合理地扩大模具的使用范围,本文提出了“一类求设计变量最大可行区间”的数学模型,文中引入条件预优概念,应用序列条件极值法,求解了这—摸型,从而解决了模具的共享设计问题。由于这一方法成功地提出和着手求解区间扩张的逆问题,所以从工程优化的观点来看,它既具有实用意义又具有一定的理论探讨价值。     

非线性拟协调元与杂交／混合元：：I.关于Hellinger—Rei…

给出了非线性拟协调有限元列式方法，将非线性拟协调有限元与基于Ｈｅｌｌｉｎｇｅｒ－Ｒｅｉｓｓｎｅｒ变分原理的杂交／混合有限元进行了比较。     

Dynamic coloration of polymerized cholesteric liquid crystal networks by infiltrating organic compounds

We demonstrate the dynamic coloration of polymerized cholesteric liquid crystal(PCLC) networks templated by the“wash-out/refill” method in the presence of organic compounds. The reflection colors were modulated by two key approaches, that is, the injection of mutually soluble organic fluids into a microfluidic channel and the diffusion of volatile organic compounds(VOCs). The reversible tuning of reflected colors with central wavelengths between ～450 nm and ～600 nm was achieved by alternative in...     

有机场效应晶体管材料及器件研究进展

有机场效应晶体管（organic field-effect transistor, OFET）作为新一代半导体晶体管因其广阔的应用前景和近年来技术上的突飞猛进,使之成为微电子和信息领域科学研究和产品开发中热门的话题之一.文章概述了有机场效应晶体管的材料研究、器件制备技术以及有机场效应晶体管在各领域中应用的最新进展.     

Microencapsulation of n-Eicosane as Energy Storage Material

For heat energy storage application, polynrea microcapsules containing phase change material, n-eicosane, were synthesized by using interfacial polymerization method with toluene-2,4-diisocyanate (TDI) and diethylenetriamine(DETA) as monomers in an emulsion system. Poly(ethylene glycol)octyl-phenyl ether (OP), a nonionic surfactant,was the emulsifier for the system. The experimental result indicates that TDI was reacted with DETA in a mass ratio of 3 to 1. FF-IR spectra confirm the formation of wall material, polyurea, from the two monomers, TDI and DETA.Encapsulation efficiency of n-eicosane is about 75%. Microcapsule of n-eicosane melts at a temperature close to that of n-eicosane, while its stored heat energy varies with core material n-eicosane when wall material fixed.Thermo-gravimetric analysis shows that core material n-eicosane, micro-n-eicosane and wall material polyurea can withstand temperatures up to 130, 170 and 250℃, respectively.     

苯甲酸分子印迹聚合物的制备及其吸附性能

以苯甲酸为模板分子,4-乙烯基吡啶为功能单体,乙二醇二甲基丙烯酸酯为交联剂,采用本体聚合法制备了高选择性识别的分子印迹聚合物。利用合成的聚合物作为吸附剂填充制备气体浓缩针装置,并用于挥发性有机化合物(VOCs)的气相色谱分析。实验结果表明:60℃下恒温聚合反应6h,模板分子、功能单体、交联剂的物质量比为1∶4∶20,预聚合时间为3h,溶剂为乙腈,模板分子为苯甲酸时,合成的分子印迹聚合物对苯系物的吸附量最大。     

制备二氮杂冠醚和三氮杂冠醚的新方法

以糖精为原料合成二氮杂冠醚和三氮杂冠醚。使糖精与二甘醇或三甘醇二氯化物和N,N-二(β-氯乙基)丁胺的DMF溶液在少量碘化钾存在下烃化、氨解,再用二甘醇或三甘醇的二对甲苯磺酸酯烃化生成保护的冠醚环。后者与20％盐酸作用除去保护基生成游离的环体。此法合成路线短原料价廉易得。二氮杂18-冠-6总产率37％左右。     

POSS聚合物及其新进展

POSS 作为一种特殊的有机/无机杂化纳米构件备受关注。本文总结了近几年有关探索POSS聚合物结构与性能之间关系的研究进展,并重点综述了POSS在有机半导体材料领域的应用。