酸处理对碳纳米管电子自旋共振谱的研究

采用浓硫酸与硝酸混酸对碳纳米管的进行了酸氧化处理,并采用TEM,FTIR和ESR对处理后的碳纳米管的形貌,官能团类型和电子自旋状态进行了表征。结果表明:酸处理能够切断碳纳米管,并且使其管径变小,同时可以使碳纳米管的C-C键发生断裂,产生-COOH。ESR图谱显示电子自旋谱的峰高比随酸处理时间增加而增加,意味着增加碳纳米管中未成对电子和导带电子数量有所增加。同时酸处理后的碳纳米管的g因子和线宽都随着酸处理时间增加而增加,g因子从2.012增加到2.018,线宽从19×10-4增加到26×10-4,意味着缺陷能够影响电子自旋状态。     

6H-SiC硅面S钝化工艺研究

采用(NH4)2S溶液钝化SiC的Si面,借助反向I-V特性间接表征钝化效果,得到了SiC表面最佳的钝化参数:钝化温度60 ℃、钝化时间30 min、NH3·H2O浓度为2.4 mol/L、(NH4)2S浓度为0.22 mol/L.XPS测试结果表明钝化后的6H-SiC表面形成了Si-S键,反向饱和I-V特性表明S钝化降低了表面的态密度.实验结果与第一性原理计算结果相吻合.     

制备乙酰胆碱酯酶脂质体用于甲基对硫磷的电化学检测

随着农业发展,农产品生产越来越依赖于农药的使用,农药的不合理使用使得水体、土壤和农产品污染严重超标,农药残留引起的中毒事故频繁发生.我国农产品往往因农药残留超标难以跨越国外"绿色壁垒",给企业带来巨大的经济损失.为了保障人民的身体健康,满足进出口贸易的需要,研究农药残留速测技术具有重要的意义~([1]).     

聚乙烯吡咯烷酮分子量对LiFePO4/C形貌及电化学性能的影响

以价廉、低毒的无机盐为原料、去离子水为溶剂,通过简易可行的络合溶胶-凝胶法合成了LiFePO4/C复合正极材料.利用XRD、SEM、EIS及恒流充放电测试考察了聚乙烯吡咯烷酮(PVP)分子量对试样的形貌及电化学性能的影响.结果表明,以PVP-k30为表面活性剂所合成的试样颗粒均匀细小、形貌较规则且单分散性良好;该试样具有优良的电化学性能,0.1C的放电比容量为155.7 mAh/g,3C倍率下放电比容量依然能保持112.4 mAh/g,明显优于其它分子量PVP所制备的试样.     

Enhanced thermoelectric performance in p-type Mg_3Sb_2 via lithium doping

The Zintl compound Mg_3Sb_2 has been recently identified as promising thermoelectric material owing to its high thermoelectric performance and cost-effective,nontoxicity and environment friendly characteristics.However,the intrinsically p-type Mg_3Sb_2 shows low figure of merit(z T = 0.23 at 723 K) for its poor electrical conductivity.In this study,a series of Mg_(3-x)Li_xSb2 bulk materials have been prepared by high-energy ball milling and spark plasma sintering(SPS) process.Electrical transport measurements on these materials revealed significant improvement on the power factor with respect to the undoped sample,which can be essentially attributed to the increased carrier concentration,leading to a maximum z T of0.59 at 723 K with the optimum doping level x = 0.01.Additionally,the engineering z T and energy conversion efficiency are calculated to be 0.235 and 4.89%,respectively.To our best knowledge,those are the highest values of all reported p-type Mg_3Sb_2-based compounds with single element doping.     

Quality control and database on resistive plate chambers for the BESⅢ experiment

The chamber production and installation of the BESⅢ MUON identifier system have been finished. The cosmic ray test result after installation shows that the average efficiency is bigger than 95% and can meet the requirement of the design report. A database including all the chamber parameters and performance data has been constructed and is accessible online. The quality control procedures during the production and the database are described.     

Test of BESⅢ RPC in the avalanche mode

The installation of the BESⅢ RPC system has been completed. Cosmic ray test results show that they perform very well in streamer mode and meet the BESⅢ requirements. We have tested several RPCs in the avalanche mode with the addition of extra SF₆ in the gas mixture. We find an efficiency plateau that reaches ～95%, and a time resolution of 1.8 ns. This demonstrates that the BESⅢ-type RPC can work in the avalanche mode as well.     

BESⅢ μ探测器阻性板模型室的性能研究

对基于酚醛树脂的阻性板室(RPC)进行研究. 通过改进的表面处理工艺, 开发了一种新的阻性板材料, 并在不同温度下对多块样板的电阻率进行了测量. 对比了基于此新型阻性板的不同电阻率RPC模型室的探测效率、计数率和暗电流. 利用¹³⁷Cs γ源和实验束流研究了流光模式RPC的抗辐照性能. 结果表明此新型阻性板RPC满足BESⅢ μ探测器的要求.     

氨功能化介孔MCM-41固载锰卟啉作为萘羟基化多相催化剂

将不同含量的四(五氟苯基)卟啉锰固载于表面氨基功能化的MCM-41介孔分子筛,所得样品通过粉末X射线衍射、氮气吸附脱附、傅里叶变换红外光谱、X射线光电子能谱、扫描电子显微镜、漫反射紫外-可见光谱、热重和差示扫描量热、电感耦合等离子体进行了表征.结果表明,四(五氟苯基)卟啉锰通过Mn与氨基的轴向配位固载于MCM-41.所制备的样品作为多相催化剂在以间氯过氧苯甲酸为氧化剂选择氧化萘反应中表现出良好的催化性能,且多次使用后没有明显的活性损失.     

真空退火处理对纳米氮化硅电子自旋共振谱的影响

用微米级SiO2、Si和碳黑混合粉末为原料, 以氮气为反应气,采用碳热还原法合成了氮化硅纳米粉体.测量了300～1273K退火温度下纳米氮化硅的电子自旋共振(ESR)谱,研究了测量温度、纳米氮化硅退火温度对ESR谱线型、g因子、线宽的影响.结果证实退火影响纳米氮化硅的磁性.