Synthesis and Crystal Structure of Mn（phen）（PhCOO）2（H2O）

1 INTRODUCTION During the last decade the manganese che- mistry has aroused great interest due to its diverse redox functions of enzymes in photosystem Ⅱ and its specially structural, magnetic and spectroscopic properties[1, 2]. A lot of manganese complexes involving carboxylate ligands have been reported, and their properties been fully explored[3, 4]. The coordination environment of the manganese site in biosystem often consists of oxygen and nitrogen atoms from the carboxylate groups…     

二核Fe/S化合物(Et4N)2[Fe2S2Br4]的合成与结构

标题化合物(Et_4N)_2[Fe_2S_2Br_4](1)在VS_4~(3-)/FeBr_2/imnt~(2-)/Et_4NCI的反应体系中获得,它属于单斜晶系,空间群P2_1/n,主要晶胞参数为:α=0.91193(2)nm,b=1.03874(3)nm,c=1.54360(1)nm,β=105.090(1)°,V=1.41177(5)nm~3,Z=2, ρ=1.778g/cm~3,μ=6.841cm~(-1),F(000)=748,结构精修结果为:R_1=0.0287,wR_2=0.0640.簇阴离子[Fe_2S_2Br_4]~(2-)含有一个菱形Fe_2S_2单元,铁的配位几何构型明显偏离了理想的T_d对称性,导致整个阴离子的对称性降低为D_(2h).同时观察到它的Fe-Br键呈现反常加长倾向.     

STUDIES ON SYNTHESES OF MoFe_3S_4 CUBANE-LIKE CLUSTER COMPOUNDS

The features of synthetic processes are described on the basis of the studies of the syntheses of MoFe_3S_4 cubane-like cluster compounds either by self-assembly reactions or by the conversion of linear clusters. The redox properties and the structure of ligands as well as the stoichiometry of reactants have obvious effects upon the core oxidation state and the structure of products. It is indicated that the self-assembly reaction may pass through a combination process oflinear cluster intermediates having structural unit (M,M'=Mo) Fe).     

He/C3H8(60/40)气体增益的实验研究

利用正比计数管测量了氦基混合气体He/C3H8(60/40)在55Fe 5.9keV X射线下的气体增益，并对气体增益随高压、温度、气压及气体比分的变化作了研究. 作为比较还对He/CH4(60/40)及Ar/CO2/CH4(89/10/1)混合气体进行了相应的测量.     

探测低动量粒子的高精度中心漂移室性能的估算

分析估算了用于探测低动量带电粒子的高精度中心漂移室(CDC)的动量分辨率与电离能损,对低动量带电粒子的动量测量以及利用dE/dx识别粒子的能力进行了讨论,并探讨了CDC对两个典型过程的探测性能.     

L3强子量能器第一个模块正比室的研制

本文报导L3强子量能器第一个模块60个正比室的研制和性能测试.在充以Ar(80%)+CO₂(20%)混合气条件下,室计数率坪长125V,坪坡度3.4%/100V.输出脉冲具有良好的均匀性.长时间的高压"锻炼"能使暗电流减小.由正比室装配成的强子量能器模块,在CERN SPS试验束上进行了性能测试.取得了满意的结果.     

Synthesis and structure of linear hexanuclear manganese (Ⅱ)benzoate cluster

From a reaction system including benzoic acid and Mn(NO3)2 in alkali medium, two hexanuclear manganese benzoate cluster compounds have been synthesized. A compound [Et4N]2[Mn6(PhCOO)14] has been structurally characterized, which contains hexanuclear Mn11 moieties extending unlimitedly to form one-dimensional linear structure. Carboxyl oxygen atoms are bridged in variety of modes to the Mn atoms, forming an arrangement like a sinusoid for the Mn atoms. The structural parameters of these compounds were compared with the data obtained from EXAFS determination for the Mn cluster in the OEC of PS11, supporting that the coordination sphere of the Mn site in the OEC may contain carboxyl bridges. The possible combination modes between the carboxyl group and the Mn atoms have been suggested. The NMR signals exhibit widening and shift produced by the influence of the paramagnetic Mn" sites. The red-shift of the absorption in IR spectrum was observed to be attributed to the coordination of the carboxyl group to the Mn     

含有环己巯基配体的钨簇合物的合成及晶体结构研究

C6H11Na, Et4NBF4, FeCl2, (NH4)2WS4在20mL CH3OH溶剂的反应中, 标题簇合物(Et4N)3[W2Fe6S8(SC6H11)6(OCH3)3]被分离得到, 对其进行X-ray 单晶衍射和结构解析。 该化合物属正交晶系,空间群 Pmmn, 晶胞参数 a = 17.370(5), b = 15.986(4), c = 17.858(3), V = 4958.6(6)3, Z = 2,C63H135N3O3S14Fe6W2, Mr = 2134.47, Dc = 1.43g/cm3, F(000) = 2172.0, m(MoKa) = 3.49 mm-1, T = 293(2)K。 采用2966个I > 2.0s (I) 的衍射点对所有非氢原子参数进行结构修正。 得到最后的偏离因子为R = 0.072, Rw = 0.091。 这是一个双类立方烷的结构, 2个单类立方烷的端基金属钨原子通过3个甲氧基桥联。 [WFe3S4] 与 [MoFe3S4]簇核结构比较说明, 两者存在一定的相似性。     

新奇的Mo/Fe/S原子簇的合成及[Me_3PhCH_2N]_2[MoFe_4S_4(SC_6H_(11))_7]的结构表征

在 (NH4) 2 MoS4,FeCl2 ,NaSC6 H1 1 (C6 H1 1 为环己基 )的甲醇反应体系中得到一种新型的 [Me3PhCH2 N] 2 [MoFe4S4(SC6 H1 1 ) 7]的钼铁硫立方烷原子簇 ,并进行了结构表征 .它的晶体属三斜晶系 ,空间群P 1,a =1.5 2 3 1( 3 )nm ,b =1.610 5 ( 3 )nm ,c=1.83 83 ( 4 )nm ,α =77.18( 3 )° ,β =75 .17( 3 )° ,γ =64 .60 ( 3 )° ,Z =2 .讨论了由于环烷巯基参与而引起的反应产物及其结构变化