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71.
锌镉汞苯并咪唑配合物合成及生物活性杨鲁勤,阎世平,廖代正,姜宗慧,王耕霖,申泮文(南开大学化学系,天津300071)近年随着医药化学的发展,过渡金属配合物的生物活性及药用价值正引起人们重视 ̄[1,2].本文首次报道Zn、Cd、Hg与羟乙基三苯并咪唑甲... 相似文献
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本文合成了以邻苯二甲酸二价阴离子为桥基的3个新型的环上含4个锰(Ⅱ)离子的十六元大环配合物。化合物的组成用元素分析确定,并用IR、磁天平等手段对配合物进行了表征,测定了[Mn_4(μ-Phth)_2(bpy)_8](ClO_4)_4·3H_2O的晶体结构,空间群,a=14.276(6),b=14.369(9),c=15.54(1),α=70.22(5)°,β=61.73(6)°,γ=66.38(5)°,Z=1.对[Mn_4(μ-Phth)_2(bpy)_8](ClO_4)_4·3H_2O和[Mn_4(μ-Phth)_2(Phen)_8](ClO_4)_4·2H_2O进行了变温磁化率测量(4—300K),用最小二乘法可使其实验值与从自旋Hamilton算符,导出的磁化率理论曲线很好拟合,求得J=0.53cm~(-1)(bpy)和J=0.23cm~(-1)(Phen)。表明Mn—Mn间有弱的铁磁性交换作用。 相似文献
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{Cu2(tacn)2[μ-(MeN)2C2O2]}[(MeNH)2C2O2](ClO4)2的合 成、结构及性质研究 总被引:1,自引:0,他引:1
合成了双核配合物{Cu2(tacn)2[μ-(MeN)2C2O2]}[(MeNH)2C2O2](ClO4)2(tacn=1,4,7-三氮杂环壬烷)。通过元素分析、红外光谱、ESR谱和电子光谱对配合物进行表征,并利用单晶X射线衍射法测定其结构,晶体属单斜晶系,空间群为P21/n,a=0.72572(16)nm,b=2.5616(6)nm,c=0.9128(2)nm,β=90.096(5)°,V=1.6969(7)nm^3,Dcald=1.590Mg.m^-^3,Z=2,F(000)=840,R1=0.0529,wR2=0.1341,Gof=1.028,△ρ=632~390e.nm^-^3。晶体由对称的双核Cu单元、中性草酰胺分子及高氯酸根堆积而成。两个铜原子配位数为五,处于变形四方锥的配位环境中。在5~300K范围内磁性测定表明:配合物中存在反铁磁偶合相互作用,经理论拟合:g=1.98,J=-219cm^-^1。 相似文献
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1 INTRODUCTION Galactose oxidase is a monomeric enzyme that catalyzes the stereospecific oxidation of a broad range of primary alcohol substrates and possesses a unique mononuclear copper site essential for catalyzing a two-electron transfer reaction during the oxidation of primary alcohol to corresponding aldehydes[1]. The catalytic reaction is shown in Eq. 1. RCH2OH + O2 RCHO + H2O2 (1) A recent report on the crystal structure of galactose oxidase reveals a unique mo… 相似文献
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The trinuclear Cu(Ⅱ) and Zn(Ⅱ) complexes [(CuTPA)_3(μ3-CO_3)] (ClO_4)_4(1) and [(ZnTPA)_3(μ_3-CO_3)] (ClO_4)_4 (2) (TPA=tri(pyridylmethyl) amine) have been synthesized. X-ray structure analysis of the two complexes proves that CO_3~(2-) anion has an unusual triply bridging ligand, bridging three CuTPA and ZnTPA units respectively, and assembles new trinuclear complexes. The CO_3_(2-) comes from atmospheric CO_2. The structure of each trinuclear unit consists of three copper or zinc atoms in a five-coordinate triangular bipyramidal environment. The [(CuTPA)_3 (μ_3-CO_3)] (ClO_4)_4 compound shows a very weak antiferromagnetic coupling. 相似文献
79.
Two new trinuclear copper(Ⅱ) complexes bridged with N,N′-Bis(2-pyridylmethyl)-Dithiooxamidate, [Cu3L2](ClO4)2(1) and [Cu3L2](NO3)2(2) (H2L=N,N′-Bis(2-pyridylmethyl)-Dithiooxamide), have been synthesized, and characterized by elemental analyses, IR, UV-visible spectra, conductance and EPR spectra. The variable temperature magnetic susceptibility for complex (1) has been measured in the range of 1.5~298K. Experimental data of magnetic susceptibility are successfully fit to theoretical value based on the spin Hamiltonian operator: H=-2J(S1S2+S2S3)-2J′S1S3, S1=S2=S3=1/2, giving the magnetic exchange parameters of 2J=-170 cm-1 and 2J′=-7.2 cm-1. This result indicates the presence of a strong antiferromagnetic spin exchange interaction between the Cu(Ⅱ) ions. 相似文献
80.
Two novel adducts of formula Mn(hfac)2( NITPhCl )2 (1) and [Mn(hfac)2(IMHPhCl)]2(NIT-PhCl)·0.5H2O (2), where hfac = hexafluoroacetylacetonate, NITPhCl = 2-(3-chlorophenyl)-4,4,5,5-tetram-ethylimidazolyl-1-oxyl-3-oxide, IMHPhCl = 2-(3-chlorophenyl)-4, 4, 5, 5-tetramethylimidazolyl-3-oxide, have been prepared by the reaction of Mn(hfac)2·2H2O with NITPhCl. Compound 1 is triclinic, space group P-1with a = 1.3003(3) nm, 6 = 1.3138(3) nm,c = 1.4931 (3) nm, α = 83.74(3)°, β = 77.77(3)°, γ = 60.59(3)°, V=2.171(1)nm3, Z = 2. Compound 2 is triclinic, space group P-1 with a = 1.2994(3) nm, b = 1.4841(3) nm, c = 2.1031 (4) nm, a = 92.30(3)° ,p = 98.68(3)°, γ = 97.89(3)°, V= 3.964(2)nm3, Z = 2. Each manganese atom is hexacoordinated in both compounds and compound 2 is organized inchains by hydrogen bonds between neighboring pairs of NITPhCl and IMHPhCl. 相似文献