等离子体技术的固氮应用

空气中的氮气由于其牢固的N≡N三键,不易被植物直接吸收.等离子体固氮为高效实现将氮分子(N2)转化为可吸收的含氮化合物(NOx,NH3等)提供了新途径.相比传统Haber-Bosch(H-B)工艺,等离子体技术可以使用间歇性可再生能源,成本低廉,并且理论能耗仅为H-B工艺的0.5倍,因而在固氮领域受到广泛关注.本篇综述...     

染料敏化太阳能电池TiO2电极的制备及电解质的影响

采用溶胶-凝胶水热法制备了锐钛矿型纳米晶TiO₂薄膜电极,在乙二醇碳酸酯(EC)/1,2-丙二醇碳酸酯(PC)电解液体系中,研究了I₂和KI含量对电极光电性能的影响,发现随着电解液中I₂含量的增加,电池的短路光电流呈现先增加后减小的趋势,但光电流增加和减少的幅度并不大,同时体系的暗电流不断增加,光电压不断下降;随着电解液中KI含量的增加,电池的短路光电流也不断增加,当KI的含量大于0.2 mol/L时,电池的短路光电流的增加的趋势减缓.并对电解液中I₂和KI含量对电池光电性能影响的原因进行了初步的探讨.     

基于特征正交分解的一类瞬态非线性热传导问题的新型快速分析方法

提出了一种基于特征正交分解(POD)和有限元法的瞬态非线性热传导问题的模型降阶快速分析方法,建立了导热系数随温度变化的一类瞬态非线性热传导问题有限元格式的POD降阶模型.在隐式时间推进方法的基础上有效结合单元预转换方法和多级线性化方法发展了一种加速求解瞬态非线性热传导降阶模型的新型计算方法,并通过二维和三维算例验证了该方法的准确性和高效性.研究结果表明:(1)降阶模型解的均方根误差在经过初始时段轻微的脉动后稳定于0.01%以下,而其计算效率比有限元全阶模型提高2～3个数量级,并且自由度数量(DOFs)愈大提高的幅度也愈加显著;(2)新型算法解决了常规算法在计算非线性降阶模型时加速性能差的问题,即使是在DOFs比较小的时候也能够明显提高计算效率;(3)常数边界条件下得到的POD模态可以用来建立相同求解域在各种复杂时变边界条件下的瞬态非线性热传导降阶模型,并对其传热过程和温度场进行快速准确的分析与预测,具有很好的工程应用价值.     

三种不同组合的统一计数公式

三种不同组合的统一计数公式环伟成林昆明（江苏省如皋中学２２６５００）ｎ个不同元素的集记为从小到大写的自然数集Ｎ＝｛１，２，３，…，ｎ｝．从此集中选出ｒ个元素的集记为｛ｊ１，ｊ２，ｊ３，…，ｊｒ｝，其中自然数仍依从小到大排列．取定非负整数ｋｉ，１ｉ?..     

Fabrication and Magnetic Properties of Co-Doped TiO2 Powders Studied by Nuclear Magnetic Resonance

Co0.04 Ti0.96O2 powders are fabricated by sol-gel method. The structure and magnetic properties are investigated under different annealing conditions systematically with emphasis on the influence of oxygen pressure. Pure anatase structure was acquired for all the samples annealed at 450℃ for one hour. The samples annealed in air exhibit evident room-temperature ferromagnetism (RTFM) with a small magnetic moment of 0.029μB per Co atom and coercivity Hc of 26 Oe, while the samples annealed in vacuum have strong RTFM with a larger magnetic moment of 1.18μB per Co atom and Hc of 430 Oe. The zero-field spin echo nuclear magnetic resonance spectrum of ^59Co is obtained to prove the existence of Co dusters in the latter samples, implying that the Co dusters are responsible for the strong RTFM in the samples annealed in vacuum. No Co cluster could be observed using both XPS and NMR techniques in the samples annealed in air, implying that the RTFM found in these sample sis intrinsic.     

Numerical Study on a Lateral Double-Gate Tunnelling Field Effect Transistor

A novel lateral double-gate tunnelling field effect transistor （DG-TFET） is studied and its performance is presented by a two-dimensional device simulation with code ISE. The result demonstrates that this new tunnelling transistor allows for the steeper sub-threshold swing below 60mV/dec, the super low supply voltage （operable at VDD 〈 0.3 V） and the rail-to-rail logic （significant on-state current at the drain-source voltage VDS = 50mV） for the aggressive technology assumptions of the availability of high-k/metal stack with equivalent gate oxide thickness EOT =0.24 nm and the work function difference 4.5 eV of materials.     

茉莉酮及二氢茉莉酮的新合成

以3-硅基环戊-2-烯酮为原料,用连串的烷基共轭加成-亲核烷基化方法,可方便地制得茉莉酮及二氢茉莉酮.     

Jump Conditions of a Shock with Current in Cylindrical Non-Neutral Plasma

jump conditions of the parameters （mass flow, momentum flow and energy flow） of a shock with current （thereby, electric and magnetic field） in cylindrical non-neutral plasma are presented and derived from Maxwell＇s equations and two fluid equations for electron and ion fluid. The critical Mach number for the shock existence is calculated, which depends on the shock carried current, the ion charge, and the composition of the magnetic and thermal pressure. The numerical results show that both the strength and profiles of the downstream shock parameters will be affected obviously by the shock carried current, electric and magnetic field in the two-dimensional shock.     

Electron Correlation in the Final Continuum of Ionization Hydrogen by 150-eV Electron Impact

Electron correlation in triple differential cross sections for ionization of atomic hydrogen by electron impact is analysed for the case of coplanar asymmetric geometry within the framework of the two-potential formulae. Based on the approximations of projectile and faster-electron plane wave, the transition matrix element is analytically expressed to be a product of two factors: the correlation factor of two electrons in the final channel and the structure-scattering factor. The contribution of both the factors to the angular distribution of the triple differential cross section is calculated. The present results are compared with the experimental data and the other theoretical calculations for the incident energy of 150eV.