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61.
Kai Jun LIAO Xiao Hua YAN Dong Yun ZHAO Xue Yi MA* Department of Chemistry National Laboratory of Applied Organic Chemistry Lanzhou University Lanzhou 《中国化学快报》2002,(3)
Lappaconitine (Figure 1) is a diterpenoid alkaloid, naturally occurring in roots and rhizomes of Aconitum and delphinium1. Lap reveals bradycardic and hypotensive activity2. But its application is restrained owing to its poor water solubility, toxicity and side effects on humans. In a number of pharmaceutical studies, b-CD has been reported to interact with many drug molecules to form inclusion complexes for improving the water solubility of drugs, and reducing their toxicity3. We have p… 相似文献
62.
Ruo Jun SUN Hui JIANG Zhi Zhen HUANG* Department of Chemistry Zhejiang University Hangzhou 《中国化学快报》2003,(3)
Wittigreactionisoneofthemostimportantmethodfortheformationofcarbon-carbondoublebondandhasbeenwidelyusedinthesynthesisofnaturalproducts1,2.Recentlyitwasfoundthatalcoholscanundergoinsituoxidation-Wittigreactionwithphosponiumylidestogivecorrespondingolefinationproducts,whichhasgreatpotentialutilitiesinorganicsynthesis3.Tosimplifytheprocedureofthereactionfurther,weconsideredtocombinethedeprotonationofylide,oxidationofalcoholandWittigreactionintoonetandemreaction.Weutilizedphosphoniumorarsoniumsal… 相似文献
63.
IBONACCISEQUENCEANDCANTOR′STERNARYSETTONGJINGCHENGSAMONS,J.ManuscriptreceivedSeptember12,1994.RevisedDecember15,1996.Depar... 相似文献
64.
数值地震预测的关键物理问题* 总被引:2,自引:0,他引:2
数值地震预测是地震物理研究中的一个重要课题,具有基础性的科学意义和潜在的应用价值.文章介绍了数值地震预测的三个关键物理问题——地震发生率与应力变化的关系、地震断层的摩擦函数、地球中应力的传递问题,讨论了这些问题的意义、研究现状和发展趋势. 相似文献
65.
采用共沉淀法制备了不同Eu3+掺杂浓度的Gd2(WO4)3纳米发光材料. 测量了纳米材料样品的X射线衍射谱(XRD) 和场发射扫描电镜, 对样品的结构和形貌进行了表征. 测量了各样品的发射光谱和激发光谱(声子边带光谱), 绘制了浓度猝灭曲线, 确定了最佳的掺杂浓度为20 mol%. 通过声子边带光谱计算了不同掺杂浓度样品的黄昆因子. 测量了不同浓度样品的荧光寿命, 利用Auzel模型对Eu3+ 5D0能级荧光寿命数据进行了拟合, 确定了5D0能级的固有寿命和猝灭过程中生成的声子数. 本文还根据荧光寿命数据计算了Eu3+之间的能量传递速率, 确定了能量传递速率与浓度的关系.
关键词:
钨酸盐
3+')" href="#">Eu3+
黄昆因子
能量传递速率 相似文献
66.
67.
Hydrogen peroxide biosensor based on electrodeposition of zinc oxide nanoflowers onto carbon nanotubes film electrode 总被引:2,自引:0,他引:2
Hui Ping Bai Xu Xiao Lu Guang Ming Yang Yun Hui Yang~* Department of Chemistry Chemical Engineering Yunnan Normal University Kunming China 《中国化学快报》2008,19(3):314-318
A new amperometric biosensor for hydrogen peroxide was developed based on adsorption of horseradish peroxidase at the glassy carbon electrode modified with zinc oxide nanoflowers produced by electrodeposition onto multi-walled carbon nanotubes (MWNTs) film. The morphology of the MWNTs/nano-ZnO electrode has been investigated by scanning electron microscopy (SEM), and the electrochemical performance of the electrode has also been studied by amperometric method. The resulting electrode offered an excellent detection for hydrogen peroxide at -0.11 V with a linear response range of 9.9×10^-7 to 2.9×10^-3 mol/L with a correlation coefficient of 0.991, and response time 〈5 s. The biosensor displays rapid response and expanded linear response range, and excellent stability. 相似文献
68.
Jian Fang Zhong De Liang He~* Zhou Zhou Yi Bin Xu State Key Laboratory of Chemo/Biosensing Chemometrics College of Chemistry Chemical Engineering Hunan University Changsha China 《中国化学快报》2008,19(3):319-323
The similar electrochemical oxidation behaviors of hydroxypivalaldehyde in ionic liquids (ILs) medium, C4MIMPF6, C4MIMBF4 and CsMIMPF6, are investigated using classic electrochemical methods, respectively. Only the product, hydroxypivalic acid is detected by high performance liquid chromatography (HPLC). It can be conferred that the electrochemical oxidation of hydroxypivalaldehyde consists of two successive one-electron irreversible reactions at glass carbon (GC) electrode and the possible reaction mechanism in the ILs is proposed firstly. The diffusion coefficients of hydroxypivalaldehyde are obtained according to the electrochemical characteristics of hydroxypivalaldehyde in C4MIMPF6, C4MIMBF4 and CsMIMPF6. 相似文献
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70.
A SnO2/Ti
electrode prepared by thermal oxidation was used as the anode for galvanostatic
electrolysis in acidic solution containing phenol, the time-dependances of phenol
concentration,chemical oxygen demand in solution(COD)and instantaneous current efficiency
were determined during electrolysis.The results show that with the SnO2/Ti
anode instead of Pt,the COD significantly decreases at the same charge passage, and
average current efficiency of oxidation increases by three times The mechanism for phenol
oxidation at two electrodes was discussed. 相似文献