超声提取-高效液相-原子荧光联用测定温州海产品中不同形态的汞

建立了超声酸提取-高效液相-原子荧光联用测定温州海产品中无机汞[Hg(Ⅱ)]、甲基汞(MeHg)和乙基汞(EtHg)含量的方法,并优化了实验条件.实验采用5mol/L盐酸溶液,超声3.0h提取汞化合物,硫代硫酸钠络合,最后经C18柱(4.6mm×150mm)分离,流动相为5％乙腈-0.06mol/L乙酸铵-0.12％ L-半胱氨酸.在最佳条件下,3种汞化合物在0-20μg/L范围内线性良好,相关系数(r)均优于0.9990,检出限分别为1.04、1.09和1.29μμg/L,相对标准偏差(RSDs)均小于5％(n=10),温州海产品的汞加标回收率达到90.1％-107.3％.该方法操作简便,精密度高,干扰少,适用于各地海产品中汞化合物的形态分析测定.     

可变摆长的单摆运动的MATLAB仿真

文章对可变摆长的单摆运动进行了详细的理论分析和推导,并根据不同的摆长将运动分成八种情况。     

信息与计算科学专业建设的探索与实践

培养社会适用型人才是各高校信息与计算科学专业建设的目标.石家庄经济学院在专业建设方面突出夯实专业知识、拓展实训技能,实现双证结合.在大类招生专业分流基础上,根据学生的兴趣、特长设计不同的实训环节和实践项目.     

剩余格蕴涵代数中多重模糊结合滤子的研究

在剩余格蕴涵代数中,首先提出了多重模糊结合滤子的概念,研究了其性质.然后,讨论了多重模糊结合滤子与模糊滤子之间的关系;接着,讨论了多重模糊结合滤子与多重模糊关联滤子之间的关系;最后,得到了在格H蕴涵代数中,不同的多重模糊结合滤子之间等价的结论.     

Research on characterization of frequency chirp in RSOA

Light chirp is a major issue in optical fiber links. This letter deals with precise characterizations of the frequency chirp parameters of reflective semiconductor optical amplifiers （RSOAs）. The RSOA chirp properties are represented by transient and adiabatic chirps, whose parameters are characterized utilizing a ratio between the phase and the amplitude modulation depths of the RSOA when modulated with sine waves. Utilizing a high-resolution optical spectrum analyzer, a RSOA linewidth enhancement factor a and an adiabatic factork are obtained experimentally, based on which the influence of chirp parameters on the transmission performance of non-return-to-zero （NRZ） signals can be analyzed.     

Angular distributions of CH3I fragment ions under the irradiation of a single pulse and trains of ultrashort laser pulses

The angular distribution of CH3I is investigated experimentally using a single Fourier transform-limited laser pulse and a pulse train, where a 90-fs 800-nm linearly polarized laser field with a moderate intensity of 2.8×1013 W/cm2 is used. The dynamic alignment is demonstrated in a single pulse experiment. Moreover, a pulse train is used to optimize the molecular alignment, and the alignment degree is almost identical to that with the single pulse. The results are analysed by using chirped femtosecond laser pulses, and it demonstrates that the structure of pulse train rather than its effective duration is crucial to the molecular alignment.     

Structural changes concurrent with ferromagnetic transition

Ferromagnetic transition has generally been considered to involve only an ordering of magnetic moment with no change in the host crystal structure or symmetry, as evidenced by a wealth of crystal structure data from conventional X-ray diffractometry (XRD). However, the existence of magnetostriction in all known ferromagnetic systems indicates that the magnetic moment is coupled to the crystal lattice; hence there is a possibility that magnetic ordering may cause a change in crystal structure. With the development of high-resolution synchrotron XRD, more and more magnetic transitions have been found to be accompanied by simultaneous structural changes. In this article, we review our recent progress in understand- ing the structural change at a ferromagnetic transition, including synchrotron XRD evidence of structural changes at the ferromagnetic transition, a phenomenological theory of crystal structure changes accompanying ferromagnetic transitions, new insight into magnetic morphotropic phase boundaries (MPB) and so on. Two intriguing implications of non-centric symmetry in the ferromagnetic phase and the first-order nature of ferromagnetic transition are also discussed here. In short, this review is intended to give a self-consistent and logical account of structural change occurring simultaneously with a ferromagnetic transition, which may provide new insight for developing highly magneto-responsive materials.     

Quantum metrology

The statistical error is ineluctable in any measurement. Quantum techniques, especially with the development of quantum information, can help us squeeze the statistical error and enhance the precision of measurement. In a quantum system, there are some quantum parameters, such as the quantum state, quantum operator, and quantum dimension, which have no classical counterparts. So quantum metrology deals with not only the traditional parameters, but also the quantum parameters. Quantum metrology includes two important parts： measuring the physical parameters with a precision beating the classical physics limit and measuring the quantum parameters precisely. In this review, we will introduce how quantum characters （e.g., squeezed state and quantum entanglement） yield a higher precision, what the research areas are scientists most interesting in, and what the development status of quantum metrology and its perspectives are.     

电容去离子脱盐装置构型的研究进展

电容去离子(CDI)技术是一种新型的海水淡化技术,因其具有环境友好、操作简单和能耗低等优势而受到广大研究者的关注。在CDI技术中,电吸附的性能与装置的构型有着密切的联系。本文综述了目前常见的几种CDI装置,包括膜电容去离子(MCDI)、流动电极电容去离子(FCDI)、杂化电极电容去离子(HCDI)、反式电极电容去离子(i-CDI)以及脱盐电池(DB),对这几种装置的发展历程和装置构型进行介绍,最后,对CDI的装置构型在未来的研究发展方向进行了展望,以期为CDI装置在电脱盐领域的研究和应用提供参考。     

PW11M(M=Cu、Co)@TiO2多相催化剂的制备及氧化脱硫性能

摘要：以过渡金属(Cu, Co)取代磷钨酸为模板剂,硫酸钛为钛源,通过一步模板法合成出一类多酸基PW11M(M=Cu、Co)@TiO2材料,采用FT-IR、XRD、XPS、Raman、SEM和TEM表征手段对材料进行了结构表征. 结果表明,PW11M(M=Cu、Co)被引入到TiO2中,形成了球形核壳结构. N2吸附-脱附测试表明,PW11Co@TiO2具有介孔结构:孔径大小为3.3 nm,比表面积为72.4 m2/g. 在以H2O2为氧化剂,乙腈为溶剂的氧化脱硫反应体系中考察了其催化活性,结果表明：复合材料PW11M(M=Cu、Co)@TiO2表现出良好的催化性能. 其中催化剂PW11Co@TiO2在投入量为40 mg,反应底物为500 ppm,反应温度60 oC,反应40 min后,DBT的脱硫率达到99.7%. 中断和循环实验表明,催化剂PW11Co@TiO2具有良好的稳定性,在相同的反应条件下,循环反应5次后,催化剂的催化活性没有明显下降.