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41.
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Aluminum samples have been analyzed by femtosecond polarization-resolved laser-induced breakdown spectroscopy (fs-PRLIBS). We compare the obtained spectra with those obtained from nanosecond PRLIBS (ns-PRLIBS). The main specific features of fs-PRLIBS are that a lower plasma temperature leads to a low level of continuum and no species are detected from the ambient gas. Furthermore, signals obtained by fs-PRLIBS show a higher stability than those of ns-PRLIBS. However, more elements are detected in the ns-PRLIBS spectra.  相似文献   
42.
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The main characteristics of the third harmonic emission generated byfemtosecond laser pulses propagating in air are investigated by numericallysolving the coupled nonlinear Schr?dinger equations. Strong thirdharmonic emission is observed with a maximum conversion efficiency as highas 0.43%. The on-axis phase difference between fundamental beam and thirdharmonic is investigated. The result is in good agreement with thephase-locking mechanism. Dependence of the conversion of third harmonicemission on focusing conditions is also studied. The results are alsocompared with those of experiments.  相似文献   
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