双峰双波长分光光度法测定Fe(Ⅲ)和Fe(Ⅱ)混合组分的研究

提出一种测定Fe（Ⅲ）和Fe（Ⅱ）混合组分的新方法,即双峰双波长分光光度法。该方法选择性好、灵敏度高、操作简便,对于混合体系中Fe（Ⅲ）Fe和（Ⅱ）及全铁的测定可以同时进行。该方法用于模拟混合试测定,结果令人满意,标准加入法测得其回收率可达95％－97％,相对标准偏差均小于1．5％。     

Nonlinear dynamics in sliding processes： the single-particle case

Dynamical behaviours of the motion of particles in a periodic potential under a constant driving velocity by a spring at one end are explored. In the stationary case, the stable equilibrium position of the particle experiences an elasticity instability transition. When the driving velocity is nonzero, depending on the elasticity coefficient and the pulling velocity, the system exhibits complicated and interesting dynamics, such as periodic and chaotic motions. The results obtained here may shed light on studies of dynamical processes in sliding friction.     

2D hydrodynamic simulation of a line-focused plasma in Ni-like Ag x-ray laser research

In most collisional schemes of x-ray laser (XRL) experiments, a bow-like intensity distribution of XRL is often observed, and it is generally ascribed to the two-dimensional hydrodynamic behaviour of expanding plasma. In order to better understand its essence in physics, a newly developed two-dimensional non-equilibrium radiation hydrodynamic code XRL2D is used to simulate a quasi-steady state Ni-like Ag XRL experiment on ShenGuang-II facility. The simulation results show that the bow-like distribution of Ni-like ions caused by over-ionization in the central area of plasma is responsible for the bow-like shape of the XRL intensity distribution observed.     

二乙三胺五乙酸二氢吡啶衍生物的合成及Gd(Ⅲ),Fe(Ⅲ),Mn(Ⅱ)配合物的弛豫性能研究

用二乙三胺五乙酸(DTPA)酸酐与二氢吡啶类化合物反应,合成了4种新型的含二氢吡啶基的二乙三胺五乙酸非离子型配体,并进一步合成了其Gd(Ⅲ),Fe(Ⅲ),Mn(Ⅱ)的顺磁性金属配合物.配体和配合物的结构用IR,¹HNMR及元素分析表征.研究了配合物的体外弛豫性能,结果表明,Fe(Ⅲ)和Mn(Ⅱ)配合物弛豫效率R₁ 低于Gd(Ⅲ)配合物的R₁ ,Gd(Ⅲ)配合物的弛豫效率较高,具有作为MRI造影剂的条件.     

反应时间、温度和溶剂对缬氨酸自组装成聚合肽反应的影响

寡肽类化合物一般具有较强的生物活性,多数可作为药物或药物前体,因此成为人们的研究热点之一．目前寡肽的合成方法主要有液相法、固相法及酶促合成法,这些合成方法往往需要对氨基酸的活性基团进行选择性保护,步骤繁琐．近期研究发现,在水-醇体系中α-氨基酸被磷酰化为N-磷酰-α-氨基酸后,可发生自组装聚合肽反应;在无水条件下,N,O-二(三甲基硅基)-α-氨基酸可与磷酰化试剂如O,O-亚苯基磷酰氯反应生成N-磷酰-α-氨基酸,后者也可通过自组装反应得到二～八肽,但这些N-磷酰-α-氨基酸的制备均需使用有机磷试剂．我们发现,在无机磷试剂如PCl5等辅助下,α-氨基酸同样可以发生自组装反应,得到一系列寡聚肽,这既可为寡聚肽的合成提供一种新的方法,同时,因无机磷试剂在原始地球条件下更可能存在,因而对于揭示多肽及蛋白质的起源具有重要意义．氨基酸的自组装反应具有链锁反应的特点,因此必须控制反应条件实现对反应的控制。     

On temporal evolution of precipitation probability of the Yangtze River delta in the last 50 years

The monthly precipitation observational data of the Yangtze River delta are transformed into the temporal evolution of precipitation probability (PP), and its hierarchically distributive characters have been revealed in this paper. Research results show that precipitation of the Yangtze River delta displays the interannual and interdecadal characters and the periods are all significant at a confidence level of more than 0.05. The interdecadal is an important time scale, because it is on the one hand a disturbance of long period changes, and on the other hand it is also the background for interannual change. The interdecadal and 3－7y oscillations have different motion laws in the data-based mechanism self-memory model (DAMSM). Meanwhile, this paper also provides a new train of thought for dynamic modelling. Because this method only involves a certain length of data series, it can be used in many fields, such as meteorology, hydrology, seismology, and economy etc, and thus has a bright perspective in practical applications.     

人造金刚石晶体中微观杂质的TEM分析

本文成功地利用透射电子显微术探讨了高温高压条件下于Fe-Ni-C系统中生长的人造金刚石单晶内部的微观杂质.分析了金刚石晶体中杂质的微观结构、化学成分组成、晶体结构及其可能形成的原因.研究结果表明,金刚石晶体中微观杂质与原材料、传压介质和高温高压过程密切相关,主要由面心立方(FeNi)23C6,正交结构的FeSi2,面心立方SiC和非晶态石墨组成.     

光纤同轴电缆混合网技术

阐述了光纤同轴电缆混合网 (HFC)网络的主要工作原理 ,给出了 HFC网络的基本结构模型 .对 HFC网络媒体存取控制 (MAC)层中的 3个重要问题 ,即上行通道访问模式、同步问题、碰撞解决方案及其解决方案进行了讨论 ,并对 HFC技术中存在的噪声干扰问题以及解决办法进行了初步的探讨 .     

在非对称光腔中利用CRIB技术进行光量子态存储

本文提出了一个在光腔中利用可控逆非均匀展宽技术实现高效的量子存储方案.当光场在光腔中每次往返的吸收与透射到光腔中光场强度完全一样时(阻抗匹配条件),发现进入光腔中的光场可以完全被非均匀展宽原子系综吸收.通过计算得到无论是向前读取还是向后读取的方案,量子存储效率在光深度很小时都可以达到1.若没有光腔100％的存储效率仅仅只有在光深度无穷大时才能得到.在光深度很小时就能达到高效的量子存储在实验上非常容易实现.因此该方案为实验上实现高效的量子存储提供一个确实可行的方法.     

Failure of the free non-Markovian heat energy relation under a bath temperature change

We investigate the free energy relation for a system contacting with a non-Markovian heat bath and find that the validity of the relation sensitively depends on the non-Markovian memory effect, which is especially related to the initial preparation effect. This memory effect drives the statistical distribution of the system out of the initial preparation, even if the system starts from an equilibrium state. This leads to the violation of the free energy relation. A possible way of eliminating this memory effect is proposed.