逆流色谱分离镅(Ⅲ)和铕(Ⅲ)的研究

选择0.1 mol/L NaC lO4为流动相,以二氯苯基二硫代膦酸的二甲苯溶液为固定相,研究了萃取剂浓度、流动相pH及流动相流率对逆流色谱(CCC)分离Am3 和Eu3 效果的影响。结果表明,在实验条件下,两者的分离系数随着固定相中的萃取剂浓度增加、流动相的pH升高而增大;降低流动相流率后可明显改善分离效果。通过改变分离条件,Am3 和Eu3 可基本上实现相互分离,两者间的分离系数和分离效率分别达到2.87和0.74。     

丙型病毒性肝炎感染者头发中部分微量元素的研究

为探讨丙型肝炎病毒(HCV)感染者头发部分微量元素含量的变化,用原子吸收分光光度计分别测定了HCV感染者和正常人头发中的微量元素Zn、Fe、Se含量。结果表明,抗-HCV阳性组及HCV患者组发Zn含量低于正常对照组,经统计学检验,具有高度显著性差异(P<0.01);而丙肝患者组的Fe含量显著高于健康对照组。丙肝患者组头发Se含量低于健康对照组,具有显著性差异(P<0.01)。提示微量元素Zn、Fe、Se与病毒性肝炎存在密切关系。     

The mechanism of asymmetric reduction catalyzed by a C_2 symmetric bis-amino alcohol catalyst——In situ NMR study of the structure of new type of dual-centered catalyst

By means of 1H, 13C, 11B NMR, polar transfer DEPT135, DEPT90 and 2D NMR experiments, IR, etc, the structure of the diaminodihydroxyl ligand and its derivatives used in the asymmetric reduction of prochiral ketones were detected. The catalysts derived from the ligand and bo-rane formed in situ were also studied and the structure transformations in solution were monitored.The structure of the catalyst was proved to be a new type of dual-centered catalyst——bis-oxazaborolidine.     

一个有关圆的问题向椭圆的拓展

茫茫的题海中，有许多题目虽说不同，却结合“似曾相似”的感觉．现有一例．     

热驱动室温行波热声制冷机的实验研究

本文报道了热声驱动的室温行波热声制冷机的实验研究。以氦气为工质研究了平均充气压力、工作频率等参数对制冷性能的影响。实验达到的最好结果为:最低温度为-47℃,在-20℃的制冷量为80W,按输入制冷机的P-V功计算,相应的制冷系数COP达到1.6左右。     

理想气体分子按平动能分布的极值问题

推导了分子按平动能分布律,绘图讨论了分子按速率分布及按平动能分布,并讨论了分子出现概率极大的问题。     

可储能原则在一类岩爆问题中的研究和应用

从能量的角度对一类岩爆问题--应变型岩爆进行一些探讨.对此类岩爆能量的来源、能量的去处及能量释放的原因和大小进行了完整的论述.提出了岩体的可储能原则--岩体可存储的能量并非定值,而是随应力状态的变化而改变,当应力发生突变,岩体内实际存储的能量大于可储能时,多余的能量必将以各种形式瞬间释放,其中包括动能.根据此准则对简化了的一维、三维模型进行了详细的分析和计算,并结合离散元软件3DEC再现了三维卸载岩爆的破坏过程.     

Effect of Al Doping on Properties of SiC Films

Undoped and Al-doped 3C-SiC films are deposited on Si（100） substrates by low-pressure chemical vapour deposition. Effects of aluminium incorporation on crystallinity, strain stress, surface morphology and growth rate of SiC films have been investigated. The x-ray diffraction patterns and rocking curves indicate that the crystallinity is improved with aluminium doping. Raman scatting patterns also demonstrate that the strain stress in SiC films is released due to the incorporation of Al ions and the increase of film thickness. Furthermore, due to the catalysis of surface reaction which is induced by trimethylaluminium, the growth rate is increased greatly and the growth process varies from three-dimensional island-growth mode to step-flow growth mode.     

多方过程的TS方程及T—S曲线

导出了用多方指数ｎ温度Ｔ及熵Ｓ表示的多方过程方程，得出Ｔ－Ｓ图中多方过程曲线所斜率与多方指数ｎ的关系式，讨论了各等值过程的Ｔ，Ｓ关系式及在Ｔ－Ｓ图中过程曲线的斜率表达式。