气相色谱-三重四极杆串联质谱检测尿样中神经性毒剂代谢产物烷基膦酸类化合物

建立了气相色谱-三重四极杆串联质谱检测尿样中有机磷毒剂代谢产物烷基膦酸类化合物含量的方法。选用DB-17MS色谱柱(30 m×0. 25 mm×0. 25μm),化学离子源,在负离子模式下,选择反应监测模式扫描,对暴露于有机磷毒剂下的人尿样中的烷基膦酸类化合物含量进行测定。在优化条件下,5种烷基膦酸类化合物可在30 min内完成同时测定,检测方法的线性关系良好,检出限为0. 1μg/L,定量下限为0. 5μg/L,加标回收率为97. 3%~98. 9%,重复性RSD为5. 3%~10%,日内相对标准偏差(RSD)为2. 4%~4. 3%,日间RSD为2. 5%~4. 5%。该法准确、灵敏度高、专属性强、重复性好,适用于染毒尿样中烷基膦酸类化合物的含量测定,可为有机磷毒剂人体内代谢产物烷基膦酸类化合物提供有效的检测手段。     

调制掺杂GaAs/AlGaAs 2DEG材料持久光电导及子带电子特性研究

在掺Si的GaAs/AlGaAs二维电子气(2DEG)结构中，得到μ_2K=1.78×10^{6cm2/(V·s)的高迁移率.在低温(2K)和高磁场(6T)的条件下，对样品进行红 光辐照，观察到持久光电导(PPC)效应，电子浓度在光照后显著增加.通过整数量子霍尔效应 (IQHE)和Shubnikov-de Haas (SdH)振荡的测量，研究了2DEG的子带电子特性.样品在低温光 照后2DEG中第一子带和第二子带的电子浓度同时随电子总浓度的增加而增加；而且电子迁移 率也明显提高.同时，通过整数霍尔平台的宽度对光照前后电子的量子寿命变短现象作了理 论分析. 关键词： 二维电子气 量子霍尔效应 SdH振荡 持久光电导效应}     

Luminescent Characteristics of Near Ultraviolet InGaN/GaN MQWs Grown on Grooved Sapphire Substrates Fabricated by Wet Chemical Etching

InGaN/GaN multiple quantum wells （MQWs） are grown on planar and maskless periodically grooved sapphires by metal organic vapour phase epitaxy （MOCVD）. High-resolution x-ray rocking curves and transmission electron microscopy （TEM） are adopted to characterize the film quality. Compared with the MQWs grown on planar sapphire, the sample grown on grooved sapphire shows better crystalline quality： a remarkable reduction of dislocation densities is achieved. Meanwhile, the MQWs grown on grooved sapphire show two times larger PL intensity at room temperature. Temperature-dependent PL measurements are adopted to investigate the luminescence properties. The luminescence thermal quenching based on a fit to the Arrhenius plot of the normalized integrated PL intensity over the measured temperature range suggests that the nonradiative recombination centres （NRCs） are greatly reduced for the sample grown on grooved sapphire. We assume that the reduction of dislocations which act as NRCs is the main reason for the sample grown on pattern sapphire having higher PL intensity.     

由一道赛题想到的

问题1 四边形ABCD内接于⊙O,AB与DC相交于P,AD与BC相交于Q,AC与BD相交于R.求证:O为△PQR的垂心. (2001年东北三省数学邀请赛试题) 由问题1,我想到下面两个问题: 问题2 四边形ABCD内接于圆,以B与DC延长线交于P点,AD、BC延长线交于Q     

Double-pass ytterbium-doped fiber amplifier with high gain coefficient and low noise figure

We have proposed and demonstrated a double-pass ytterbium-doped fiber amplifier using an optical circulator and a fiber Bragg grating as reflector. When the signal has passed through the ytterbium-doped fiber once, it reflects off a 0.2-nm passive fiber Bragg grating filter. This reduces amplified spontaneous emission (ASE) noise from the first pass. The input signal light is amplified both forward and backward through ytterbium-doped fiber. With this double-pass configuration, 1053.15-nm unsaturated signal gain of 28 dB, gain coefficient of 1.1 dB/mW, and noise figure of less than 4 dB are achieved at 977-nm pump power of 68 mW. It is also found that this double-pass configure provides enhancing gain coefficient and improving noise figure by comparison with single-pass configuration.     

Isospin Effect of Coulomb Interaction on Momentum Dissipation in Intermediate Energy Heavy Ion Collisions

We investigate the isospin effect of Coulomb interaction on the momentum dissipation or nuclear stopping in the intermediate energy heavy ion collisions by using the isospin-dependent quantum molecular dynamics model. The calculated results show that the Coulomb interaction induces obviously the reductions of the momentum dissipation. We also find that the variation amplitude of momentum dissipation induced by the Coulomb interaction depends sensitively on the form and strength of symmetry potential. However, the isospin effect of Coulomb interaction on the momentum dissipation is less than that induced by the in-medium nucleon-nucleon cross section.In this case, Coulomb interaction does not change obviously the isospin effect of momentum dissipation induced by the in-medium two-body collision. In particular, the Coulomb interaction is preferable for standing up the isospin effect of in-medium nucleon-nucleon cross section on the momentum dissipation and reducing the isospin effect of symmetry potential on it, which is important for obtaining the feature about the sensitive dependence of momentum dissipation on the in-medium nucleon-nucleon cross section and weakly on the symmetry potential.     

一类逐段决定风险模型罚金函数的期望(英)

本文主要考虑了一类逐段决定的风险模型的罚金函数.利用建立的积分-微分方程,我们得出了此类风险模型罚金函数期望的一般解.     

二阶含阻尼项椭圆型方程的区域振动准则

籍用平均函数和积分算子, 对二阶含阻尼项椭圆型微分方程∑^N_{i,j=1}{D_i[a_{ij}(x)D_j{y}]+∑^N_{i=1}b_i (x)D_i{y}+q(x)f(y)=0建立了一些区域振动准则, 这些准则不同于已知的依赖于整个区域Ω(1)的性质的结果,而是仅依赖于区域Ω(1)的一列子区域的性质.     

柠檬酸单月桂醇酯二钠盐的合成过程及光谱分析

简述了柠檬酸月桂醇单酯二钠盐的合成过程。以乙酸酐、柠檬酸为原料 ,合成柠檬酸酐中间体 :柠檬酸∶乙酸酐 =2 0∶1 0 ,温度 36℃～ 37℃ ,反应时间 18h ,产率为 71 0 % ;酯化反应 :柠檬酸酐∶月桂酸=1 0∶1 1,温度 85℃～ 90℃ ,反应时间 2 0h ,单酯的产率为 83%～ 84 %。并采用红外光谱对合成过程中的原料、中间体及产物进行了研究。通过柠檬酸 ,柠檬酸酐及柠檬酸单酯二钠盐的红外光谱比较分析 ,证实了环状柠檬酸酐的形成。证明了直接制备高纯度的柠檬酸单月桂醇酯二钠盐工艺路线的合理性及可行性。同时表明可以用红外光谱对反应的中间体及产物进行验证。     

塑胶预埋件力学性能的试验研究

塑胶预埋件是由塑胶材料制作的新型预埋件。通过对埋设在混凝土中的塑胶预埋件进行抗拉、抗剪和拉力疲劳荷载性能试验,考察了塑胶预埋件的极限承载力和破坏形态,研究了拉力疲劳荷载对预埋件抗拉性能的影响。针对M10型预埋件的塑胶-锥体复合拉伸破坏形态,得出极限拉伸荷载的简化计算公式。研究结果表明塑胶预埋件力学性能较好,具有很好的应用前景。