基于真实情境下问题探究的分析化学课程设计——以"一元弱酸、弱碱及多元酸碱的滴定"为例

以建构主义理论为指导,沿着情境线、问题线和知识线3条线索开展教学,让学生在真实的教学情境中,通过对一系列问题进行探究,自主完成知识体系的构建,并概括提炼可迁移的学习策略,形成学习能力。通过总结性评价与形成性评价相结合的方式反映学生的学习情况,促进学生全面发展和进步。     

La_(2)ATiO_(6)(A=Mg,Zn)∶Er^(3+)荧光材料的上转换发光特性及温度传感特性调控EI北大核心CSCD

Er^(3+)的上转换性能强烈依赖局部位置对称畸变。在本研究中,采用高温固相法制备了La_(2)Mg_(1-w)Zn_(w)TiO_(6)∶xEr^(3+)(x=0,0.02,0.04,0.06,0.08,0.10;w=0,0.3,0.5,0.7,1.0)系列荧光粉。基于XRD精修,Zn^(2+)的掺杂改变了La_(2)Mg⁃TiO_(6)晶体的配位环境,晶相由Pbnm转变为P2_(1/n)。在980 nm激光激发下,样品上转换荧光强度随Er^(3+)离子浓度改变,当Er^(3+)离子浓度为x=0.06时样品的上转换荧光强度最强。基于荧光强度比技术研究了样品La_(2)Mg_(1-w)ZnwTiO_(6)∶xEr^(3+)(x=0.06;w=0,0.3,0.5,0.7,1.0)在303~583 K温度范围内的上转换荧光温度传感特性。实验结果表明,灵敏度随着Mg^(2+)和Zn^(2+)掺杂浓度比例的改变而改变,在w=1.0时达到最大绝对灵敏度0.90%·K^(-1),说明Zn^(2+)的掺杂提高了La_(2)MgTiO_(6)的灵敏度。     

Microcrack localization using a collinear Lamb wave frequency-mixing technique in a thin plate

A novel Lamb wave frequency-mixing technique is proposed for locating microcracks in a thin plate,which does not require the resonance condition of Lamb wave mixing and can accurately locate the microcracks through only one-time sensing.Based on the bilinear stress-strain constitutive model,a two-dimensional finite element(FE)model is built to investigate the frequency-mixing response induced by the interaction between two primary Lamb waves and a microcrack.When two primary Lamb waves of A0 and S0 modes with different frequencies excited on the same side of the plate simultaneously impinge on the examined microcrack,under the modulation of the contact acoustic nonlinearity,the microcrack itself can be deemed as the secondary sound source and it will radiate the Lamb waves of new combined frequencies.Based on the time of flight of the generated A0 mode at difference frequency,an indicator named normalized amplitude index(NAI)is defined to directly locate the multi-microcracks in the given plate.It is found that the number and location of the microcracks can be intuitively visualized by using the NAI based frequency-mixing technique.It is also demonstrated that the proposed frequency mixing technique is a promising approach for the microcrack localization.     

The 50 nm-thick yttrium iron garnet films with perpendicular magnetic anisotropy

Yttrium iron garnet (YIG) films possessing both perpendicular magnetic anisotropy (PMA) and low damping would serve as ideal candidates for high-speed energy-efficient spintronic and magnonic devices. However, it is still challenging to achieve PMA in YIG films thicker than 20 nm, which is a major bottleneck for their development. In this work, we demonstrate that this problem can be solved by using substrates with moderate lattice mismatch with YIG so as to suppress the excessive strain-induced stress release as increasing the YIG thickness. After carefully optimizing the growth and annealing conditions, we have achieved out-of-plane spontaneous magnetization in YIG films grown on sGGG substrates, even when they are as thick as 50 nm. Furthermore, ferromagnetic resonance and spin pumping induced inverse spin Hall effect measurements further verify the good spin transparency at the surface of our YIG films.     

Al2O3/TiC基陶瓷刀具材料的高温摩擦磨损性能研究

采用UMT-2球-盘式高温摩擦磨损试验机,考察了A l2O3/TiC基陶瓷刀具材料在200℃至600℃范围内的高温摩擦磨损性能,并分别使用大景深显微镜,白光干涉仪和扫描电镜观察试验后磨痕的轮廓和微观形貌.结果表明：A l2O3/TiC陶瓷刀具的摩擦系数随环境温度的升高先升高,在600℃时开始降低,摩擦系数的数值在0.1~0.4之间;磨损量随着摩擦滑动速度的升高而降低,随着摩擦环境温度的升高而升高,磨损量的数值在4×10-7~9×10-7mm3/（N.m）之间;随着摩擦温度的升高,磨痕轮廓两侧具有明显的材料转移现象,A l2O3/TiC陶瓷材料主要磨损机理是裂纹的产生与材料的脱落.     

硅溶胶-纳米金修饰金电极电化学发光法测定苦参碱的研究

基于苦参碱对联吡啶钌电化学发光的增敏作用,利用溶胶-凝胶固定化稳定的优点和纳米金对苦参碱的电催化作用,建立了硅溶胶-纳米金修饰金电极电化学发光检测苦参碱的新方法,考察了苦参碱在该修饰电极上的电化学及其发光行为。结果表明,此修饰电极表现出很好的电化学活性和电化学发光(ECL)响应,在最佳实验条件下,苦参碱浓度在1.5×10-7～1.5×10-4mol/L范围内与相对发光强度呈线性关系(r2=0.998 4),检出限(S/N=3)为7.3×10-9mol/L。连续平行测定1.5×10-5mol/L的苦参碱溶液8次,发光强度的相对标准偏差(RSDs)为1.4%。样品回收实验得到苦参碱的加标回收率为98%～102%,RSD(n=5)为1.8%。该方法具有较高的选择性和灵敏度,样品处理简单快速,用于苦参碱栓中苦参碱的测定,结果满意。     

油脂和木质纤维素催化转化制备生物液体燃料

世界范围能源短缺和环境恶化的双重压力促使可再生生物质资源的能源化利用成为当前研究的一个重要方向。生物质种类多样,但考虑到粮食安全等因素,其中油脂和木质纤维素适合替代化石资源用于制备液体燃料。本文概述了油脂和木质纤维素通过不同催化转化途径制备液体燃料的一些研究进展。油脂可以通过催化热裂解、加氢和酯交换方法制备生物液体燃料,而木质纤维素制备液体燃料的可行途径包括气化-费托合成、液化-精炼和经历平台化合物的选择性合成。在介绍这些催化途径的同时,特别讨论了其中所使用的催化剂和工艺等方面的研究进展,分析了存在的问题和可能的解决措施,以期能为生物质能源化利用的研究提供参考。     

共圆点及其应用

共圆点及其应用四川师范大学邓安邦四川民政干校濮青一、基础知识在同一个圆上的一些点，称为共圆点，或者说这些点共圆。要证明一些点共圆，关键在于会证明四点共圆。证明四点共圆，主要根据：１、圆的定义：证明这四点到某一定点的距离都相等。２、角的关系：证明这四点...     

DIFFERENTIABILITY FOR THE HIGH DIMENSIONAL POLYNOMIAL-LIKE ITERATIVE EQUATION

This paper studies the smoothness of solutions of the higher dimensional polynomial-like iterative equation. The methods given by Zhang Weinian^[7] and by Kulczycki M, Tabor J.^[3] are improved by constructing a new operator for the structure of the equation in order to apply fixed point theorems. Existence, uniqueness and stability of continuously differentiable solutions are given.     

高斯光束通过非线性介质后的远场衍射图样的研究

 利用菲涅尔－基尔霍夫衍射积分公式，对发散和会聚高斯光束通过薄非线性介质时形成的远场衍射图样进行了研究。模拟计算结果表明：当发散高斯光束通过自散焦介质或会聚高斯光束通过自聚焦介质时，远场均会出现中央较暗、向外围逐渐增强、分布尺度较大的粗衍射环；当发散高斯光束通过自聚焦介质或会聚高斯光束通过自散焦介质时，远场均会出现中心强度最大、向外围逐渐减弱、分布尺度较小的细衍射环。不同远场衍射图样归根结底是入射高斯光束因介质折射率变化造成的空间自相位调制及其波前曲率共同作用的结果。