QuEChERS-液相色谱-串联质谱法测定植物性食品中30种氨基甲酸酯类农药残留

基于欧洲标准化委员会标准方法(EN 15662)对食品基质的分类,选择6种代表性植物性食品作为基质,系统优化了QuEChERS样品前处理方法;在此基础上,建立了30种氨基甲酸酯类农药的液相色谱-串联质谱分析方法。实验结果表明,除涕灭威砜的线性范围为2~100 μg/kg,其他29种氨基甲酸酯类农药的线性范围均为1~100 μg/kg;6种样品基质在3个添加水平(5、20、100 μg/kg)下的回收率为56.13%~127.6%,相对标准偏差为0.47%~16%;以信噪比(S/N)≥10计,30种农药的定量限(LOQ)为0.041~1.9 μg/kg。本文方法灵敏、有效,适用于植物性食品基质中30种氨基甲酸酯类农药残留的测定。     

Fluorocarbon- containing hydrophobically modified poly(N-isopropylacrylamide)

A fluorocarbon-modified poly(N-isopropylacrylamide) has been synthesized by copolymerization of N-isopropyl acrylamide with a small amount of acrylate or methacrylate containing a perfluoroalkyl group. It was found that the hydrophilicity of macromolecular backbone is an important factor to the solution properties of the copolymers and that hydrophobic association between fluorocarbon groups is stronger than that between the corresponding hydrocarbon analogies. The viscosity of some of the copolymer solutions was very sensitive to temperature. It was dilatant at higher fluorocarbon comonomer content ( > 0.20-1.0 mol%) and was Newtonian at very low fluorocarbon comonomer content (0.03-0.2 mol% ) . Evidence for hydrophobic association of the fluorocarbon groups was obtained from the effects of adding Nad and surfactants on the solution viscosity. The LC-ST properties of these copolymers were studied by DSC method and this was also found to be consistent with hydrophobic association between the fluorocarbo     

亚微米NaY分子筛的合成

通过合成含有促进剂A的新型导向剂,开发成功了亚微米NaY分子筛(介于纳米与微米之间)合成工艺技术,并对实验室合成的不同粒径NaY分子筛进行了性能研究,结果表明比表面积、酸量随着粒径的减小而增加,应用于FCC催化剂的合适的分子筛粒径为500nm～800nm,粒径太小的分子筛其稳定性、活性低,不能满足FCC催化剂的使用要求.     

Surface characteristics of SiO_2-TiO_2 strip fabricated by laser direct writing

SiO_2-TiO_2 sol-gel films are deposited on SiO_2/Si by dip-coating technique.The SiO_2-TiO_2 strips are fabricated by laser direct writing using an ytterbium fiber laser and followed by chemical etching.Surface structures,morphologies and roughness of the films and strips are characterized.The experimental results demonstrate that the SiO_2-TiO_2 sol-gel film is loose in structure and a shrinkage concave groove forms if the film is irradiated by laser beam.The surface roughness of both non-irradiated and laser irradiated areas increases with the chemical etching time.But the roughness of laser irradiated area increases more than that of non-irradiated area under the same etching time.After being etched for 28 s,the surface roughness value of the laser irradiated area increases from 0.3 nm to 3.1 nm.     

五元芳杂环的芳香性和亲电取代活性顺序

本文简要介绍了五元芳杂环芳香性强弱顺序和它们进行芳香族亲电取代反应的难易顺序是两种不同性质的顺序，并指出应怎样来判断这两种顺序。     

不等式“|a|-|b|≤|a+b|≤|a|+|b|”应用例析

不等式“|a|- |b|≤ |a b|≤ |a| |b|[1] ”(以下简称 [1])是高中数学的一个重要知识点 ,考试大纲说明中对此有明确要求 :会应用不等式“|a|- |b|≤ |a b|≤ |a| |b|”.事实上 ,如何有效地、灵活地应用不等式 [1]证明有关综合性代数推理题是高中数学的难点 .以下简述知识要点     

揭开庐山真面目 认识问题的本质特征

某天,孙晓琪同学来问我她在解析几何初步的学习过程中遇到的如下试题：题目设直线系M∶xcosθ＋（y-2）sinθ=1（0≤θ≤2π）,对于下列四个命题：（A）M中所有直线均经过一个定点.（B）存在定点P不在M中的任一条直线上.（C）对于任意整数n（n≥3）,存在正n边形,其所有边均在M中的直线上.（D）M中的直线所能围成的正三角形面积都相等。