ADSORPTION OF CAFFEINE BY HYDROGEN DONATING ADSORBENTS BASED ON HYDROGEN BONDING

The adsorption isotherms of caffeine from aqueous solution onto three hydrogen donating adsorbents-hydroxypolystyrene,polystryene-azo-pyrogallol,and D72 resin-were measured.The adsorption enthalpies calculated from the isotherms according to the Clausisu-Clapeyron equation were -24-36kJ/mol,-32-37kJ/mol,and -19-24kJ/mol respectively.These values implied that the adsorption processes were based on hydrogen bonding.Furthermore.the mechanism of the adsorption of caffeine onto D72 resin was studied by IR spectra and the small molecular model experiments,and the results showed that the adsorption of caffeine onto hydrogen donating adsorbents was based on hydrogen bonding.     

SORPTION OF PHENOL ONTO GEL—TYPE CROSSLINKED POLYSTYRENEISOCYANURIC ACID RESIN

Spherical crosslinked polystyrene-isocyanuric acid resin was synthesized by reaction of chloromethylated polystryene with isocyanuric acid.The sorption isotherms of phenol from aqueous solution and cyclohexane solution onto the resin were measured.It is of interest to notice that the resin sorbed phenol efficiently though its specific surface area was 0 and did not swell in water,and the sorption capactity from aqueous solution was close to that of phenol onto XAD-4 at the same equilibrium concentration.Sorption enthalpies calculated from the isotherms according to the Clausius-Clapeyron equation were -21-25kJ/mol and -39-41kJ/mol respectively.These values impled that the sorption processes were based on hydrogen bonding.In addition.the details of the hydrogen bonding between the active sites of the resin and phenol were suggested.     

STUDY ON THE TREATMENT OF INDUSTRIAL WASTEWATER CONTAINING TRIETHYLAMINE WITH POLYMERIC ADSORBENTS

The treatment of the industrial wastewater,in which the concentration of triethylamine (TEN) and CODcr was around 3450mg/L and 22400mg/L respectively,was studied by adsorption of macroporous resins,Results demonstrate that the polymeric adsorbent CHA-111 has excellent effect on the adsorption and desorption of TEN.The concentration of TEN in the effluent is less than 30mg/L,and the removal efficiency of TEN and total CODcr exceed 99% and 95% respectively.The accumulation and resource reuse of TEN can be realized in this process.     

Yb：YAG晶体的生长缺陷及位错走向

用同步辐射透射白光形貌和应力双折射法研究了沿（111）方向生长的Yb:YAG晶体的生长缺陷、晶体中的位错起源和走向。Yb:YAG晶体中的生长缺陷主要有：生长条纹、核心和位错等。晶体中的位错主要起源于籽晶、杂质粒子以及生长初期的晶种和固液界面处位错成核。位错的走向垂直于生长界面,符合能量最低原理。采用凸界面生长工艺可以有效的消除晶体中的位错。     

耐热梯度功能材料的热应力研究进展

介绍了梯度功能材料的概念和开发背景：回顾了近些年来在梯度功能材料热应力研究方面所取得的研究成果,并对梯度功能材料的发展趋势作一展望．着重论述了梯度功能材料在热应力分析领域的研究现状及其应用前景     

弯曲梁随机刚度有限元法

弯曲梁的随机材料参数和随机几何参数可结合为一个随机参数-弯曲刚度。以位移的均值和协方差函数的变分原理为基础,根据基本方程推导出具有随机刚度的静定弯曲梁的有限元法。这种方法不再采用摄动技术,可直接建立位移的均值和协方差函数。     

压电复合材料层合板自适应结构的振动控制

本文针对板壳型自适应结构,研究了压电材料作为作动器的自适应结构的振动控制。利用四节点压电复合材料层合板单元进行自适应结构的有限元动力分析;采用模态控制方法,将结构的各阶模态的阻尼比作为控制目标,并以此计算出各压电片的控制电压,达到控制结构振动的目的。算例给出了数值计算的结果。     

慢变参数系统分叉混沌问题的映射延拓综合法

在点映射和延拓法基础上,提出一种适于求解慢变参数非线性动力系统分叉混沌问题的新算法-映射延拓综合法。用本方法对含慢变参数的杜芬方程试算,绘制稳态解随参数变化的准稳态解图,分析了解随参数变化的演化规律。与多初值点映射法相比,它具有计算精度高、速度快、分析处理方便等优点;新算法更适于作高维慢变参数非线性系统振动特性的研究。     

碳酚醛各向异性本构关系和波传播

通过理论和实验研究相结合的方法,建立了碳酚醛材料的横观各向同性粘塑性本构关系,并对其一维应变波的传播问题进行了典型的数值计算,总结和揭示了其本构方程和应力波传播的若干规律和特点。     

关于线图上的等距图和次泛圈

给定一个图Ｇ,且满足min{d(u) d(v):u,v∈Ｅ（Ｇ）}≥８。有下结论：若Ｃ是Ｇ中的圈且满足dc(u,v)=d(u,v),任意{u,v}包含于Ｖ（Ｃ）。当任一这样的圈Ｃ的长度不超过△（Ｇ）＋１时,线圈Ｌ（Ｇ）是次泛圈的且所给的条件都是最好可能的。