洗涤时pH值对纳米级β-Ni(OH)2的团聚程度和电化学性能的影响

Nano-scale nickel hydroxide was prepared by precipitate transformation method in the paper. Effect of rinse pH on the agglomeration degree and electrochemical performance of nano-scale Ni(OH)₂ was investigated. The mea-surement results of XRD and TEM indicate that the prepared nano-scale Ni(OH)₂ is β(Ⅱ)-phase,the grain size is in the rang of 10～50nm,and rinse pH exerts a great influence on the agglomeration degree of nano-scale Ni(OH)₂. The agglomeration of material becomes very obvious when rinse pH=11, and the density of nano-scale Ni(OH)₂ is enhanced obviously.Cyclic voltammetry(CV) and simulate cells experiment show that nano-scale Ni(OH)₂ with suitable agglomeration degree have better electrochemical CV performance than those with ideal disperse Ni(OH)₂ and micron Ni(OH)₂, and its proton diffusion coefficient is also the highest. It can elevate the discharge potential platform and prolongs discharge time, so the utilization ratio of Ni(OH)₂ is raised.     

一种新型中高温热泵非共沸工质的理论与实验分析

针对工业生产中存在大量可资利用的余热资源,以能够利用余热资源的中高温热泵系统为研究对象,对绿色非共沸混合工质及其循环特性展开了理论和实验分析.通过理论计算筛选出非共沸混合工质ZM1(R125/R152a/R245fa),进行了多工况的实验研究,并与已经使用的由R22和R142b组成的混合工质ZM2在同等工况下进行了对比.结果表明,在满足用户需求这一层面上, ZM1和ZM2水平相当,加上其绿色环保的特性,达到了替代工质的要求,具有成为中高温热泵工质的潜质.     

D^0-D^0 mixing and other charm decays at Belle

The D^0-D^0 mixing at Belle in different modes with corresponding methods is reported in this paper, there is a clear evidence for non-zero y D^0 mixing parameter, and the measurement of D^0 mixing parameter x is still a challenge. CP violation in the decays is not observed. Branching fractions of other charm decays are presented.     

Growth and transport features of electron-doped superconductor Pr1-xLaCexCuO4-δ thin films

<正>T’-phase electron-doped superconductor Pr_1-xLaCe_xCuO_4-δ（PLCCO） thin films are successfully prepared on SrTiO₃（100） substrates by using the dc magnetron sputtering method.It is found that the films each have a highly oriented structure along the c-axis.For optimally doped films with x≈0.10,the superconducting transition temperature T_c is 23.5 K,which is similar to that of a single crystal.The quadratic temperature dependence of the resistivity is observed when T > T_c,which can be attributed to the two-dimensional Fermi liquid behaviour.Besides,the optimal conditions for preparing the T’-phase PLCCO thin films are also discussed in detail.     

非共沸工质有机朗肯循环的热力学分析

通过热力学推导,给出了基于Jacob数和蒸发冷凝温度之比来预测理想非共沸工质有机循环热效率和输出功的理论公式,同时与利用Matlab编程计算的数值计算模型进行了对比.同时以空气作为热源,采用水冷的方式,以R227ea/R245ca作为工质,研究了不同的冷却水温升和冷却水进口温度对其不同质量分数下的输出功的影响.结果发现,当冷却水温升小于工质的温度滑移时,二者相等时存在输出功的当地最大值;当冷却水温升大于工质的温度滑移时,温度滑移最大时存在输出功的最大值。在相同的冷却水温升下,冷却水的进口温度越低,工质相同质量分数下输出功越高,同时最大输出功对应的工质质量分数不变。     

光反射材料对飞行时间探测器性能的影响

在北京正负电子对撞机直线加速器试验束上测试TOF闪烁体在不同光反射材料下(tyvek, teflon, millipore, ESR及镀铝薄膜)的性能, 包括时间分辨率, 衰减长度及光在闪烁体中的有效传播速度. 就时间分辨率来说镀铝薄膜较好达到95.6±2ps, 就衰减长度来说ESR最好, 对于光在闪烁体中的有效传播速度几种光反射材料大致相同.     

水泥窑余热发电辅助碳捕集系统分析

本文提出一种应用于水泥厂的基于余热发电技术的醇胺法碳捕集系统,针对余热发电系统和乙醇胺(MEA)碳捕捉系统建立模型,利用Visual Basic软件编程模拟余热发电系统,利用Aspen Plus软件模拟MEA法CO_2捕集系统。探讨了废气负荷、低压蒸汽温度、压力对余热发电系统性能的影响,废气负荷和解析塔操作压力对MEA碳捕捉系统中解析塔耗能的影响,并分析了系统的耦合和匹配关系。结果表明,该系统碳捕获率范围为8.6%~15.0%。     

基于棱镜模型多次折射法的海水盐度检测系统

为了提高光学折射法海水盐度检测精度,综合分析现有检测方法,认为其海水盐度检测精度低的主要原因是其检测光路为平行平板模型.由此,提出了棱镜模型多次折射法检测方案.利用棱镜模型而不是平行平板模型,提高了光线的偏折角;通过设置多个棱镜模块,进一步扩大偏折角,从而大大提高系统的分辨力.设计了光路并进行仿真分析,研制了样机并进行...     

Development of the liquid level meters for the PandaX dark matter detector

The two-phase xenon detector is at the frontier of dark matter direct search. This kind of detector uses liquid xenon as the sensitive target and is operated in two-phase (liquid/gas) mode, where the liquid level needs to be monitored and controlled in sub-millimeter precision. In this paper, we present a detailed design and study of two kinds of level meters for the PandaX dark matter detector. The long level meter is used to monitor the overall liquid level while short level meters are used to monitor the inclination of the detector. These level meters are cylindrical capacitors that are custom-made from two concentric metal tubes. Their capacitance values are read out by a universal transducer interface chip and are recorded by the PandaX slow control system. We present the developments that lead to level meters with long-term stability and sub-millimeter precision. Fluctuations (standard deviations) of less than 0.02 mm for the short level meters and less than 0.2 mm for the long level meter were achieved during a few days of test operation.     

采用归一化补偿变换的与文本无关的说话人识别

在噪声环境下,特别是当说话人识别最常用的模型——高斯混合模型(GMM)失配的情况下,需要对其输出帧似然概率的统计特性进行补偿。文章根据说话人识别的声学特性,提出了一种非线性变换方法——归一化补偿变换。理论分析和实验结果表明:与常用的最大似然(ML)变换相比,该变换能够提高系统识别率,最大可达3．7％,同时可降低误识率,最大可达45．1％。结果说明归一化补偿变换方法基本克服了在与文本无关说话人识别系统中,当说话人的个性特征不断变化、语音与噪声不能很好地分离或者降噪算法对语音有损伤、模型不能很好地匹配时,需要对模型输出的似然概率(得分)进行补偿的局限。这也说明对模型输出的似然概率进行处理是降低噪声和干扰的影响、提高说话人识别率的有效方法。