Reversal current observed in micro-and submicro-channel flow under non-continuous DC electric field

In practical applications of biochips and bio-sensors, electrokinetic mechanisms are commonly employed to manipulate and analyze the characteristics of single bio-molecules. To accurately and flexibly control the movement of single molecule within micro-/submicro-fluidic channels, the characteristics of current signals at the initial stage of the flow are systematically studied based on a three-electrode system. The current response of micro-/submicro-fluidic channels filled with different electrolyte solutions in non-continuous external electric field are investigated. It is found, there always exists a current reversal phenomenon, which is an inherent property of the current signals in micro/submicro-fluidics Each solution has an individual critical voltage under which the steady current value is equal to zero The interaction between the steady current and external applied voltage follows an exponential function. All these results can be attributed to the overpotentials of the electric double layer on the electrodes. These results are helpful for the design and fabrication of functional micro/nano-scale fluidic sensors and biochips.     

长试验时间激波风洞测力技术研究

中国科学院力学研究所复现飞行条件高超声速激波风洞JF12的落成突破了毫秒级试验时间的瓶颈,有效试验时间超过100ms.因此,对于JF12长试验时间激波风洞的测力试验,基于应变天平技术较为成熟、结构简单等优点,我们考虑采用传统的应变计天平.但是,激波风洞来流冲击所带来的惯性力干扰导致天平测力系统产生低频振动,传统内置应变天平的结构刚度很难保证信号有足够的处理周期,这大大限制了激波风洞测力模型的尺寸和重量.针对这个难题,基于JF12激波风洞的运行特点及对测力天平刚度特性的特殊要求,优化设计了应变天平的测力单元结构以适用于这种脉冲动态测力试验,相应加工制造了大刚度、低干扰、高灵敏度的系列脉冲型应变天平,结构形式包含了杆式和盒式,最大载荷(法向力)从1kN到30kN,以满足不同尺度飞行器的测力试验需求.同时,我们应用不同尺度的测力模型对研制的脉冲型天平在JF12激波风洞进行了一系列动态气动力测量试验,以进一步评估JF12系列脉冲型应变天平的结构特性和测力性能.      

采用ATRP合成天然橡胶接枝共聚物——Ⅲ.NR-g-PMMA的制备

N-溴代丁二酰亚胺与天然橡胶(NR)反应合成了大分子引发剂——溴代天然橡胶[NR-Br(1)].通过原子转移自由基聚合(ATRP),以CuBr/PMDTA为催化体系,1引发甲基丙烯酸甲酯(MMA)接枝共聚制得新型天然橡胶-g-聚甲基丙烯酸甲酯[NR-g-PMMA(2)],其结构经1H NMR和IR表征.初步聚合反应动力学研究结果表明,NBS与NR在高温下反应容易伴随双键加成和环化反应,于室温反应所得1具有较高的引发活性;接枝聚合符合一级动力学反应,即2的分子量随MMA单体转化率的提高而增加.     

基于权值矩阵的模糊自适应卡尔曼滤波在组合导航中的应用

针对自主驾驶车辆长时间导航精度要求难以满足的问题,建立了GPS与微惯性导航系统的组合导航滤波模型,在位置观测的同时引入姿态信息,提高了导航精度。在此基础上提出了基于权值矩阵的模糊自适应卡尔曼滤波算法,该算法通过模糊控制器自适应地改变每个观测量的权值,得到权值矩阵引入卡尔曼滤波器实现自适应滤波。仿真和实验结果表明,所提出的权值矩阵模糊卡尔曼滤波性能优于衰减因子自适应卡尔曼滤波,特别是在GPS信号失真及噪声先验统计特性不可知的情况下,其定位精度能够保证在1m之内。     

采用ATRP合成天然橡胶接枝共聚物——Ⅰ. ATRP大分子引发剂的制备

通过环氧化反应在天然橡胶分子链上引入环氧基制得环氧化天然橡胶(2);利用环氧基的反应活性,2与2-溴-2-甲基丙酸发生开环反应合成了原子转移自由基聚合(ATRP)大分子引发剂——天然橡胶-g-(2-溴-2-甲基丙酸),其结构经1H NMR和IR表征.     

Visible light induced photocatalytic reaction of rhodamine B dye via 12-tungstosilicic acid in water

Using 12-tungstosilicic acid (SiW124-) as the catalyst, rhodamine B (RhB) dye in an aerated aqueous solution can undergo an effective photocatalytic stepwise N-deethylation process under visible light irradiation, and dioxygen is reduced to hydrogen peroxide by the reducedSiW12 4-. This provides the potential for moving polyoxometalate-based photocatalytic processes from the near-UV into the visible region of the spectrum.     

An efficient continuous-wave YVO_4/Nd:YVO_4/YVO_4 self-Raman laser pumped by a wavelength-locked 878.9 nm laser diode

We report an efficient continuous-wave self-Raman laser at 1176 nm based on a 20-mm-long composite YVO_4/Nd:YVO_4/YVO_4 crystal and pumped by a wavelength-locked 878.9 nm diode laser.A maximum output power of 5.3 W is achieved at a pump power of 26 W,corresponding to an optical conversion efficiency of 20%and a slope efficiency of 21%.The Raman threshold for the diode pump power was only 0.92 W.The results reveal that in-band pumping by a wavelength-locked diode laser significantly enhances output power and efficiency of self-Raman lasers by virtue of improved pump absorption and relieved thermal loading.     

中孔载体上组装Ti催化活性中心的研究Ⅲ. 中孔分子筛与钛化合物键合作用的红外光谱表征

FT-IR表征了中孔分子筛(HMS)载体与钛酸异丙酯、四氯化钛、酒石酸的键合作用, 这种键合作用均会诱导载体的硅氧四面体发生弱的畸变, 而在960 cm-1附近出现吸收谱带.键合温度、溶剂以及钛源均会影响谱带的位置和强度.测得的钛负载量与该谱带强度成正比.催化苯乙烯环氧化结果表明, 键合温度、钛源、钛中心配位环境对键合催化剂的活性和环氧化选择性均有较大的影响.     

Y2(Fe1-x-y,Coy,Crx)17化合物的结构及居里温度

通过x射线衍射及磁测量手段研究了Y2(Fe1-y-x,Coy,Crx)17化合物的结构及居里温度.研究结果表明Y2(Fe1-y-x,Coy,Crx)17化合物具有六角相的Th2Ni17型结构.随着x的增加,Y2(Fe1-y-x,Coy,Crx)17化合物的单胞体积呈现先小后大的非线性减小.通过Y2(Fe1-y-x,Coy,Crx)17化合物居里温度的变化,研究了Y2Fe17化合物中哑铃晶位上的Fe原子对之间的交换作用,从而在实验上证明了在Y2Fe17化合物中,哑铃晶位上的Fe原子对之间存在反铁磁交换作用,研究结果表明在Y2Fe17化合物中,Cr,Co同时少量替代Fe时,化合物的居里温度有显著提高.     

碱提猴头发酵菌丝体水溶性多糖HPP的结构确定

从猴头发酵菌丝体水提后残渣中用碱提出了水溶性粗多糖,对其分级纯化得到纯样HPP,SepharoseCL-6B柱层析测得其相对分子质量约为6 53×104,G C 分析表明,其单糖组成为Glc;经部分酸水解、高碘酸氧化、Smith降解和甲基化分析确定此多糖为多分枝结构,其中(1→6)Glc构成主链的核心结构;分支点为O-3;支链部分由(1→3)Glc构成,并连接一端基Glc.