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Bright blue photoluminescence from a mixed tin and manganese oxide xerogel prepared via solben hydrothermalben gel process
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A new blue photoluminescent material, a mixed tin and manganese oxide xerogel, is prepared via sol-hydrothermal-gel process assisted by citric acid. The composition xerogel exhibits strong blue emission at room temperature, with an emission maximum at 434 nm under short (234 nm) or long-wavelength (343 nm) ultraviolet excitation. The photoluminescent excitation spectrum of the mixed tin and manganese oxide xerogel, monitored at an intensity maximum wavelength of 434 nm of the emission, consists of two excitation peaks at 234 nm and 343 nm. With heat treatment temperature increasing from 110 ℃ to 200 ℃, the blue emission intensity increases remarkably, whereas it is almost completely quenched after being treated at 300 ℃. The carbon impurities in the mixed tin and manganese oxide xerogel, confirmed by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy, should be responsible for the bright blue photoluminescence. 相似文献
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系统介绍了高功率固体激光驱动器中单口径片状放大器(SSA)的模拟和实验研究结果。根据放大器不同层次的设计需求,开发了两级模拟软件,配合实验模拟平台上的研究工作和结构研究,对SSA放大器进行系统设计。 相似文献
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We numerically study thermally induced birefringence and distortion in plasma electrode Pockels cell based on KD*P as the electro-optic material. This device can repetitively operate under the heat capacity mode. Simulation results indicate that the excellent switching performances and low wave-front distortion are achieved within several tens seconds working time at average power in excess of 1 kW. 相似文献
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首先介绍了模拟光参量啁啾脉冲放大(OPCPA)过程的多种计算模型,在此基础上提出了三步走逐步逼近算法,以确定OPCPA过程中最稳输出时所需的非线性晶体长度.这种算法综合利用了上述计算模型,随着计算模型越来越精确,非线性晶体长度的计算范围越来越小.因而利用这种算法能高效、精确地确定最佳非线性晶体长度.最后提出在OPCPA过程引入一定的相位失配量,来调谐最稳输出时所需晶体长度,从而能突破晶体加工精度不够的局限,在实际OPCPA过程中获得稳定输出. 相似文献
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Fe纳米颗粒嵌埋对类金刚石薄膜结构及电学性能的影响 总被引:2,自引:2,他引:0
采用脉冲激光气相沉积方法制备了不同Fe嵌埋浓度的Fe: DLC多层纳米复合薄膜。用X射线光电子能谱仪(XPS)对薄膜的组成成分进行分析。利用透射电子显微镜(TEM)、拉曼光谱、电流-电压曲线研究Fe纳米颗粒嵌埋对薄膜的微观结构及电学性能的影响。XPS和TEM表明,Fe纳米颗粒周期性地均匀地嵌埋在碳薄膜中。拉曼光谱表明薄膜中的C为典型的类金刚石结构,Fe纳米颗粒促进芳香环式结构的形成,薄膜结构的有序度提高。电流 电压曲线表明,Fe纳米颗粒的嵌埋导致薄膜的室温电导率增加。 相似文献
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High temperature thermal behaviour modeling of large-scale fused silica optics for laser facility
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High temperature annealing is often used for the stress control of optical materials.However,weight and viscosity at high temperature may destroy the surface morphology,especially for the large-scale,thin and heavy optics used for large laser facilities.It is necessary to understand the thermal behaviour and design proper support systems for large-scale optics at high temperature.In this work,three support systems for fused silica optics are designed and simulated with the finite element method.After the analysis of the thermal behaviours of different support systems,some advantages and disadvantages can be revealed.The results show that the support with the optical surface vertical is optimal because both pollution and deformation of optics could be well controlled during annealing at high temperature.Annealing process of the optics irradiated by CO2 laser is also simulated.It can be concluded that high temperature annealing can effectively reduce the residual stress.However,the effects of annealing on surface morphology of the optics are complex.Annealing creep is closely related to the residual stress and strain distribution.In the region with large residual stress,the creep is too large and probably increases the deformation gradient which may affect the laser beam propagation. 相似文献