植物油酸新戊二醇对苯二甲酸复合酯的合成及性能

用新戊二醇(NPG)和对苯二甲酰氯(TPA)反应生成“低聚物”中间体,当n(NPG)/n(TPA)由2.4增加至3.0时,中间体的聚合度(m)在3.5~1.45之间,收率75.5%。再将中间体与油酸、菜籽油酸进行酯化得到复合酯,收率88.5%。结果表明,复合酯的粘度随着分子量的增大而增大,粘度指数大于125,凝点低于－27℃,氧化稳定性随分子量的增大而提高,生物降解率＞70%,最大无卡咬负荷(PB)为784N,磨斑直径0.41mm,热分解温度＞250 ℃,因此植物油酸新戊二醇对苯二甲酸复合酯是性能良好的绿色润滑剂。     

The analysis of complex behaviours of a novel three dimensional autonomous system

This paper introduces a new three dimensional autonomous system with five equilibrium points.It demonstrates complex chaotic behaviours within a wide range of parameters,which are described by phase portraits,Lyapunov exponents,frequency spectrum,etc.Analysis of the bifurcation and Poincar’e map is used to reveal mechanisms of generating these complicated phenomena.The corresponding electronic circuits are designed,exhibiting experimental chaotic attractors in accord with numerical simulations.Since frequency spectrum analysis shows a broad frequency bandwidth,this system has perspective of potential applications in such engineering fields as secure communication.     

Synthesis,Crystal Structure and Fluorescent Properties of a 1D Europium Coordination Polymer with 2,5-Furandicarboxylic Acid

By using solvothermal method,a one-dimensional chain compound[KEu₂（FDCA）₃（H₂O）₉·0.5（FDCA）]（1） was synthesized.Single-crystal X-ray diffraction data reveal that 1 crystallizes in monoclinic system,space group P2₁/n with a=12.1996（1）,b=18.6454（2）,c=17.7123（2）?,β=98.8460（10）°,Dc=1.753 g/cm³,Z=2,V=3981.03（7）?³,R=0.0544 and wR=0.1511 for 7886 observed reflections with I>2σ（I）.In1,three FDCA^2– ligands construct ...     

雾对无线激光通信系统的影响

从雾的物理特性出发,对激光在雾媒质中的传播衰减特性进行了理论研究。分别给出了无线激光通信系统的信号模型、噪声模型和透过率,并给出了不同激光波长、能见度、测量距离和接收器视场角对无线激光通信系统的影响。最后,以工作波长为10.6μm的激光为例,利用衰减率与透过率之间的关系,给出了平流雾及辐射雾中激光雾衰减随能见度、接收器视场角等的变化关系。数值分析表明：激光波长、雾的能见度、测量距离和接收器视场角对无线激光通信系统均有较大的影响。     

非均匀光栅的振幅分布和光强特性分析

从光栅自身的空间结构出发,用菲涅尔衍射公式推导了非均匀光栅的振幅分布公式(θi)和光强特性公式I(θi),用Maple程序给出了算例之不规则光栅衍射光强I(θi)随sinθi变化曲线,得到了非均匀光栅的衍射特性。一维透射平面光栅的振幅分布(θ)和光强分布I(θ)不仅与非均匀光栅的平均光栅常量有关,还与每个单元单缝的缝宽a有关。这一特性,补充完善了平面光栅衍射性质,同时,也为通过调整光栅空间结构,设计、研制、测试非线性光栅提供了理论依据。     

单扫描示波极谱法测定药物中的卡托普利

报道了卡托普利 Cu+络合物的极谱吸附波。在 0 .0 2mol LH3 PO4溶液中 ,卡托普利与Cu2 +发生氧化还原反应 ,生成卡托普利 Cu+络合物 ,在单扫描示波极谱仪上于 - 0 .44V(vs.SCE)处产生一灵敏的吸附还原波。该吸附还原波二阶导数峰电流与卡托普利浓度在 1.8× 10 - 7～ 1.8× 10 - 5mol L范围内呈线性关系 ;方法的检出限为 8.0× 10 - 8mol L ;回收率在 98.0 %～ 10 3%。     

泡沫铝填充薄壁圆管的三点弯曲实验的数值模拟

泡沫金属填充薄壁结构的应用日趋广泛,建立合理的数值计算模型对结构设计和工程应用非常重要.该文通过对泡沫铝填充薄壁铝合金圆管的三点弯曲实验的数值模拟,研究了它的力学行为.采用ABAQUS软件,建立了空管和泡沫铝全填充管的有限元模型,并对这两种结构在三点弯曲下的力学行为进行了数值模拟,所得结果与实验结果符合得较好.通过数值模拟分析了结构的承载机理和不同压头直径对结构承载能力的影响.此外,还研究了泡沫铝部分填充圆管的三点弯曲行为,分析了不同填充长度对结构承载能力的影响.     

Electromagnetic scattering from two-layer rough interfaces in the Kirchhoff approximation

Electromagnetic wave scattering from multilayers consisting of two two-layer Gaussian rough surfaces with lossless media is investigated in the Kirchhoff approximation (KA), with consideration of the shadowing effects. The tapered incident wave is introduced into the classic KA, and the bistatic scattering coefficient is redetermined. The advantage of this method is that it is faster in computation than the exact numerical methods. The numerical results show that the bistatic scattering coefficient calculated in the KA is in good agreement with that obtained by using the method of moment (MOM) over a most angular range, which indicates the validity of the KA proposed in our paper. Finally, the effects of the relative permittivity, the root-mean-square (RMS) height, the correlative length, and the average height between the two interfaces on the bistatic scattering coefficient are discussed in detail.     

UV-B辐射对2种海洋微藻生长和生理生化特征的影响

通过实验生态学和生物化学的方法,研究了UV-B辐射对杜氏盐藻、小角毛藻的生长、叶绿素含量、可溶性蛋白含量、超氧化物歧化酶活力的影响.结果表明：（1）UV-B辐射对小角毛藻的生长起促进作用,高剂量UV-B辐射对盐藻的生长具有一定抑制作用.（2）2种微藻叶绿素含量均低于对照组,UV-B辐射使盐藻叶绿素含量先下降后升高,而小角毛藻则随辐射剂量的增加呈现下降趋势.（3）2种微藻可溶性蛋白含量均低于对照组,且随辐射剂量的增加而下降;2种微藻超氧化物歧化酶活力较对照组呈现出升高的趋势.     

An iterative analytic–numerical method for scattering from a target buried beneath a rough surface

An efficiently iterative analytical-numerical method is proposed for two-dimensional （2D） electromagnetic scattering from a perfectly electric conducting （PEC） target buried under a dielectric rough surface. The basic idea is to employ the Kirchhoff approximation （KA） to accelerate the boundary integral method （BIM）. Below the rough surface, an iterative system is designed between the rough surface and the target. The KA is used to simulate the initial field on the rough surface based on the Fresnel theory, while the target is analyzed by the boundary integral method to obtain a precise result. The fields between the rough surface and the target can be linked by the boundary integral equations below the rough surface. The technique presented here is highly efficient in terms of computational memory, time, and versatility. Numerical simulations of two typical models are carried out to validate the method.