一锅三步由硝基芳烃合成邻氨基酚衍生物

硝基的选择性还原,羟胺的选择性保护,以及[3,3]-σ重排都是有机化学的基础内容。本实验将此三个基本反应融入于3.5 h的紧凑一锅法化学反应中,反应现象丰富且便于观察,利用薄层色谱能方便监测反应的进程。反应可以从简单的硝基芳烃一锅获取高官能化邻氨基酚衍生物,同时三步反应可以分解为三个单独的反应,且均能高收率得到相应化合物。产物可由硅胶柱层析纯化,化合物结构通过质谱、核磁共振波谱的解析进一步确定。该反应立足有机化学硝基官能团基础知识,适用于本科生学习官能团转化知识,观测多种实验现象,同时反应操作多样,用时紧凑,产率高,在邻氨基酚类衍生物制备中具有广泛的应用潜力。     

三［（S）-α，α-二（4-甲基苯基）-2-吡咯烷甲醇］膦酰胺催化链状酮酯化合物的不对称还原反应

报道了三［（S）-α,α-二（4-甲基苯基）-2-吡咯烷甲醇］膦酰胺催化剂催化链状酮酯化合物的不对称还原反应。 研究发现,该方法对碳链长为5~11的链状酮酯具有较好的催化效果,在物质的量分数为5%手性膦酰胺催化作用下,产物手性羟基酯化合物的收率最高可达89%,对映体过量（ee）值最高可达95%。 此方法为手性链状羟基酯衍生物的合成提供了新选择。     

PROBABILITY MODEL AND SOLUTION ON EARTHQUAKE EFFECTS COMBINATION IN ALONG WIND RESISTANT DESIGN OF TALL-FLEXIBLE BUILDINGS

A model on the earthquake effects combination in wind resistant design of high-rise flexible structures is proposed in accordance with the probability method. Based on the Turkstra criteria, the stochastic characters of wind velocity, earthquake ground acceleration and excitations occurrence probability are taken into account and then the combination of the earthquake effects in structure wind resistant design is analyzed with the convolution approach. The results indicate that as for the tall flexible buildings whose lateral force is governed by wind loading, the maximum lateral loads verification with respect to the wind resistant design combined with earthquake effects may be more unfavorable compared with that in terms of the earthquake resistant design involving wind effects.     

活性炭固相萃取/胶束电动色谱联用技术用于雷公藤3种有效成分的测定

建立了活性炭固相萃取/胶束电动色谱法同时测定中药雷公藤中的雷公藤甲素、雷公藤内酯酮和雷酚内酯的方法。优化了萃取p H值、乙醇洗脱体积、电泳运行缓冲溶液p H值与浓度、胶束SDS的浓度及进样时间、电压等条件。进行电泳分离之前,分析物用活性炭进行吸附后用2.0 m L乙醇洗脱。在214 nm波长处,分离电压20 k V,20 mmol/L硼酸-10 mmol/L硼砂(p H 8.0)-20 mmol/L SDS运行缓冲溶液条件下,3种成分在8 min内得到完全分离,雷公藤甲素、雷公藤内酯酮在4.0×10-5~4.0×10-3mol/L,雷酚内酯在4.0×10-5~1.0×10-3mol/L浓度范围内线性关系良好,其回收率为81.0%~102.9%,方法的检出限分别为1.42×10-6,7.90×10-7,2.96×10-7mol/L,相对标准偏差(RSD)分别为3.2%,5.4%,3.5%。所建立的方法简单、快速、准确,成功用于雷公藤片样品的测定。     

Dynamics of erbium-doped fibre laser with optical delay feedback and chaotic synchronization

The dynamical behaviour of the erbium-doped fibre single-ring laser with an optical delay feedback is discussed. Simulation shows that as the delay rate increases, the lasing light displays period-doubling which leads to chaos and via reverse period-doubling route returns from chaos to periodic. At a particular delay rate the intermittently chaotic route to chaos is also observed. The identical synchronization based on chaos in this ring laser is demonstrated by numerical simulation.     

自由电子激光振荡器中电子束能量跳跃对增益的影响

 微脉冲中电子束能量、电流的跳跃会影响电子束的质量, 从而也影响激光的增益。在CAEP FIR FEL 理论设计模型参数的基础上,利用一维定态程序对电子束能量跳跃对增益的影响进行了数值研究,并与非定态程序计算结果进行比较,给出可容许的能量跳跃范围。     

Reconstruction of baryon number distributions

The maximum entropy method(MEM) and Gaussian process(GP) regression,which are both wellsuited for the treatment of inverse problems,are used to reconstruct net-baryon number distributions based on a finite number of cumulants of the distribution.B ary on number distributions across the chiral phase transition are reconstructed.It is deduced that with the increase of the order of cumulants,distribution in the long tails,i.e.,far away from the central number,would become increasingly important.We ...     

氮稀释气体氧碘化学激光3维喷管流动模拟

 应用改进的3维化学反应流程序,对基于RADICL装置、以氮气为稀释气体的化学氧碘激光喷管流动做了数值模拟。给出了达到合适副气流穿深的主副气流匹配条件,考虑了提高水汽流量、改变主副气流总温对增益系数的影响,比较了与以氦气为稀释气体的不同特点。结果发现：氮气作为稀释气体条件下,混合气体的流速低,静压大,在亚声速区驻留时间长,碘分子离解快,使得增益系数峰值增大,且下降快。模拟结果提示：改变喷管结构,将副气流喷孔下移,增益分布得到了改善。