关于氢键的几个问题

氢键或称氢桥(hydrogen bridge),指在分子内或分子间两个电负性很强的原子,经过一个氢原子而相互连接起来;这是1887年俄国化学家М.А.Ильинский和Н.Н.Бекетов研究隣-亚硝基苯酚、吡啶醌的时候首先提出的。     

高温电位-pH图及其应用实例

电位-pH 图可应用于腐蚀和防腐的研究,对分析化学、化学电源和湿法冶金等也是有用的工具。在湿法冶金过程中,虽然热力学远不如动力学研究那样重要,但它是动力学研究的前提。因此,25℃的电位-pH 图早已在湿法冶金中得到应用。近年来,湿法冶金中采用压热法,提高了温度,使反应速度加快好多倍。如若用电位-pH 图对高温反应进行热力学研     

混合溶剂中标准pH参考值的研究——KHPh(0.05 mol/kg)+KCl+异丙醇+水体系

应用电动势法在10%、14.93%和20%异丙醇+水混合溶剂中测定了0.05mol/kg邻苯二甲酸氢钾(KHPh)缓冲溶液在278.15～318.15K范围内的标准pH参考值,根据Pitzer理论,提出了确定各离子活度系数的新方法,计算了邻苯二甲酸的第二级热力学解离常数和相应的热力学量。     

在中等技术学校中讲授余弦定理的一个教案

前言:这个讲稿是在我校数学科公开教学中的教案.写这教案时,曾征求了许多同志的意见;在公开教学后,又采纳了各位老师所提出的意见,作了适当的修改.但由于本人数学水平所限,缺点必然很多.本文的目的,一方面为了供教师们参考,一方面也为了取得更多同志的帮助.     

怎样在六年级讲授“惯性”这个课题

在物理教學中帮助學生建立真正科學的唯物主義的世界觀乃是一個長期的過程,這個過程從六年級起就應當開始。特别重要的是對於運動和物質的不可分離性,對於運動的永恆性,對於力是物體之間的     

介质对配合物稳定性的影响I.Cu(SCN)^+-NaNO3-C2H5OH-H2O体系

本文用分光光度法测定了25℃时配阳离子Cu(SCN)^+在乙醇-水介质中的稳定常数.乙醇在混合溶剂中的重量百分数为0,5,10,15,20和25.用NaNO3调节溶液离子强度I=0.2--2.0mol.dm^-^3.实验的pH=1.5--1.6.本文提出了基于Pitzer方程式的曲线拟合法,确定混合溶剂中配合物的热力学稳定常数.讨论了该常数和一级介质效应与溶液组成和介电常数的关系.     

Circular Shallow Spherical Shells with Central Circular Hole Under Simultaneous Actions of Arbitrary Unsteady Temperature Field and Arbitrary Dynamic Normal Load

In this paper,under assumption that tempeature is linearly distributed along the thickness of theshell,we deal with problems as indicated in the title and obtain general solutions of them which areexpressed in analytic form.In the first part,we investigate free vibration of circular shallow spherical shells with circularholes at the center under usual arbitrary boundary conditions.As an example,we calculate fundamen-tal natural frequency of a circular shallow spherical shell whose edge is fixed(m=0).Results we get areexpressed in analytic form and check well with E.Reissner’s[1].Method for calculating frequencyequation is recently suggested by Chien Wei-zang and is to be introduced in appendix3.In the second part,we investigate forced vibration of shells as indicated in the title under arbitr-ary harmonic temperature field and arbitrary harmonic dynamic normal load.In the third part,we investigate forced vibration of the above mentioned shells with initialconditions under arbitrary unsteady temperature     

Synthesis,Chemistry and Applications of Heterocyclic Cage Compounds (V)

The synthesis and chemistry of polycyclic cage compounds have attracted considerable attention in recent years.¹ The vast majority of the work reported in this area has dealt with caybocyclic cage compounds. On the other hand, the synthesis and chemistry of heterocyclic cage compounds have received less attention. Recently, we have accomplished the synthesis of a series of oxa-cage compounds and performed the chemical transformations of these oxa-cage compounds.² As part of a program that involves the synthesis,chemistry and applications of heterocyclic cage compounds we report here the synthesis of heterocyclic cage compounds 1-12. We also wish to report the applications of compounds 7-12 on the π-facial selectivities. Studies on the cation-binding properties of compounds 1 and 2 and other oxa-cages are undertaken.     

KCl在甲醇-非电解质的混合溶剂中溶解度和溶剂化

本文测定了5、15、25和35 ℃时KCl在甲醇-苯、甲醇-甲苯、甲醇-环己烷和甲醇-四氯化碳中的溶解度S, 并得到经验公式: logS=a+bT, 其中T为绝对温度。同时计算了KCl由甲醇到甲醇混合溶剂的标准迁移自由能ΔG_(tr)~°-, 并得到它和组成x_(Ne)的经验关系式; ΔG_(tr)~°-=CX_(Ne)。同时指出在本实验范围内,温度的变化不影响单纯溶剂化模型和第二介质常数公式的适用性。     

pH值对水热合成磷酸铋的光催化性能的影响

利用水热法通过调节溶液的pH值合成了不同物相和形貌的磷酸铋.用X射线衍射仪(XRD)和扫描电子显微镜(SEM)对样品进行了物相和形貌表征,并以10 mg·L-1的亚甲基蓝溶液为目标降解物,对材料的光催化降解性能进行了评价.结果表明:前驱物溶液的pH值对磷酸铋的形貌、物相和光催化性能都有较大影响.前驱物溶液pH值为1.3时制得的磷酸铋的光催化性能最高,室温汞灯照射20 min,亚甲基蓝的降解率可达到99.61;.