新型三维超分子化合物{[Co(H2bptc)(ptcp)(H2O)2]·H2O}n的水热合成和晶体结构

A novel cobalt(Ⅱ) complex with biphenyl-3,3′,4,4′-tetracarboxylic acid (H₄bptc) and 2-phenyl-1,3,7,8-tetraazacyclopenta[l]-phenanthrene (ptcp), {[Co(H₂bptc)(ptcp)(H₂O)₂]·H₂O}_n(1), has been synthesized by hydro-thermal method and was characterized by elemental analysis, single crystal X-ray diffraction and thermal gravimetry (TG). It crystallizes in monoclinic, space group Pn with a=0.719 44(14) nm, b=1.259 4(3) nm, c=1.681 9(3) nm, β=93.30(3)°, V=1.521 5(5) nm³, Z=2, C₃₅H₂₆CoN₄O₁₁, M_r=737.53, D_c=1.610 g·cm^-3, μ(Mo Kα)=0.639 mm^-1, F(000)=758, S=1.024, R₁=0.076 7 and wR₂=0.120 6. The structural analyses reveal that the title complex is a 1D zigzag chain strcture along the c axis, which is stacked to furnish a three-dimensional supramolecular net structure via hydrogen bonding interactions. CCDC: 793796.     

4-酰代双吡唑啉酮及其与La(Ⅲ),Pr(Ⅲ),Eu(Ⅲ),Tb(Ⅲ),Tm(Ⅲ)和Y(Ⅲ)固体配合物的合成及性质的研究(Ⅰ)

合成了1,4-双(1′-苯基-3′-甲基-5′-氧代吡唑-4′-基)-1,4-苯二酮(H_2L)及其与La(Ⅲ),Pr(Ⅲ),Eu(Ⅲ),Tb(Ⅲ),Tm(Ⅲ),Y(Ⅲ)的固体配合物,进行了元素分析、电子光谱、红外线光谱和摩尔导电测量,确定了化合物的组成,推测出了可能的配位式。     

二维石墨相氮化碳纳米片的制备及其在光催化领域的研究进展

二维(2D)层状石墨型氮化碳纳米片(CNNS)由于具有各向异性的2D几何形态和芳香族p-π共轭骨架,高度开放的平面结构、超高的比表面积、增强的电子迁移速率和与层厚度相关可调的半导体带隙等特征,是目前2D层状材料的研究热点之一。 本文综述了近年来氮化碳纳米片的各种制备方法、功能化改性和应用,涉及环保、能源转换及生物传感等领域。 最后指出进一步探索制备高质量氮化碳纳米片的新方法以及拓展其在光催化领域的应用是未来研究的重点。     

直接探测系统中两种单边带光信号调制与恢复方法的研究

从理论上阐释了基于独立双驱动马赫-曾德尔调制器(DDMZM)和同相正交调制器的两种单边带光信号调制原理。通过研究100 Gbit/s速率75 km标准单模光纤传输系统中的16-正交幅度调制单边带信号,分析了两种方法的参数调优原理。接收端使用Kramers-Kronig(KK)算法恢复单边带信号并消除信号与信号间的拍频串扰。结果表明,由于调制器的非线性以及单边带信号的载波信号功率比的影响,在误比特率为3.8×10~(-3)的7%硬判决前向纠错门限上,使用基于KK算法的接收机的虚载波方法与DDMZM方法相比,能够降低接收光功率约2.3 dB。     

大片单层低缺陷MXene的制备及其膜材料的电磁屏蔽性能

采用原位生成氢氟酸法刻蚀Ti₃AlC₂制备了单片层二维过渡金属碳化物(MXene), 用扫描电子显微镜(SEM)、 透射电子显微镜(TEM)及原子力显微镜(AFM)等表征了MXene的微观形貌. 结果表明, 所制备的MXene材料具有大片、 单层及低缺陷等特点. 通过抽滤MXene分散液制备的MXene膜材料具有导电性高(3280 S/cm)及韧性优异等特点. MXene膜的屏蔽性能测试结果表明, 8 μm厚的MXene膜屏蔽效能为60.6 dB, SSE/t值则高达19531.1 dB·cm ²·g ^-1. 推测MXene膜的屏蔽机理是一种以吸收为主的电磁干扰屏蔽机制.     

水中悬浮颗粒的三维体散射函数测量

提出了一种水中悬浮颗粒的三维体散射函数测量方法,采用抛物面镜结合传感器探测方式,同时获取了半球空间内多个散射面所对应的体散射函数。搭建了三维体散射函数测量装置,采用粒径为57~954nm的标准聚苯乙烯颗粒作为样本,获得了方位角0°~180°对应的多个散射面内的水中颗粒体散射函数,测量的散射角范围为18°~160°。实验结果与计算结果吻合,验证了利用该装置对水体中粒径小于1μm的悬浮颗粒的体散射函数进行测量的可行性。     

Glueball spectrum from N_f=2 lattice QCD study on anisotropic lattices

The lowest-lying glueballs are investigated in lattice QCD using N_f = 2 clover Wilson fermions on anisotropic lattices. We simulate at two different and relatively heavy quark masses, corresponding to physical pion masses of mπ～938 MeV and 650 MeV. The quark mass dependence of the glueball masses has not been investigated in the present study. Only the gluonic operators built from Wilson loops are utilized in calculating the corresponding correlation functions. In the tensor channel, we obtain the ground state mass to be 2.363(39) GeV and 2.384(67)GeV at mπ～938 MeV and 650 MeV, respectively. In the pseudoscalar channel, when using the gluonic operator whose continuum limit has the form of ∈_ijkTrB_iD_jB_k, we obtain the ground state mass to be 2.573(55) GeV and 2.585(65) GeV at the two pion masses. These results are compatible with the corresponding results in the quenched approximation. In contrast, if we use the topological charge density as field operators for the pseudoscalar, the masses of the lowest state are much lighter(around 1 GeV) and compatible with the expected masses of the flavor singlet qq meson. This indicates that the operator ∈ijk TrBiDjBk and the topological charge density couple rather differently to the glueball states and qq mesons. The observation of the light flavor singlet pseudoscalar meson can be viewed as the manifestation of effects of dynamical quarks. In the scalar channel, the ground state masses extracted from the correlation functions of gluonic operators are determined to be around 1.4-1.5 GeV, which is close to the ground state masses from the correlation functions of the quark bilinear operators. In all cases, the mixing between glueballs and conventional mesons remains to be further clarified in the future.     

应用超声干涉特征识别微小缺陷

航空用金属材料中允许存在的缺陷越来越小,有时需要识别几十微米的夹渣缺陷.由于微小缺陷对声波的反射能力弱,常用的超声脉冲反射法的识别能力遇到瓶颈.该文利用超声干涉原理对微小缺陷进行识别.首先,理论分析入射波与微缺陷散射波的干涉机理;其次,采用有限元仿真方法分析了入射波经过微小缺陷后的波形变化,归纳出入射波与微缺陷散射波干...     

碘稳频中红外差频激光光谱技术

为实现中红外波段的高精度线型研究,建立了一套在2.5～5um波段连续可调谐的中红外差频激光光谱测量系统.基于宽带连续可调谐钛宝石激光器(700 ～900 nm)和单频连续Nd:YAG激光器(1064 nm),利用碘多普勒展宽吸收和频率调制技术,对Nd:YAG激光的频率进行反馈控制,使1064 nm的Nd:YAG激光的波长稳定性好于1X10-5 cm-1由此差频输出的波长稳定性达到1×10-1cm-1水平,适合高精度的线形研究.并通过对CH4分子在2927 cm-1附近吸收谱线的测量,表明该系统可以结合频率调制方法,进行高灵敏的光谱检测.     

一种应用在航天回路热控系统上的二氧化碳两相冷凝器防冻设计的数值模拟

在航天回路热控系统的设计过程中,由于涉及到复杂的太空热流环境,以及真空,微重力等因素,仅仅依靠地面试验,有时难以真实模拟太空环境,此时就需要利用数值模拟的方法为设计提供参考依据.本文介绍了利用SINDA/FLUINT模拟的方法,对一种应用在主动式热控回路上的冷凝器进行流向择优设计和散热分析,得出对这种冷凝器/辐射器防冻的较优方法.