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81.
用ESR方法对MgCl2负载的钛系Ziegier-Natta催化剂进行了研究,获得了分辩率较好的谱图,并结合前人的工作将信号的归属同钛原子在MgCl2上的负载情况对应起来.同时考察了内外给电子化合物对ESR谱图的影响,探讨了它们可能的作用机理. 相似文献
82.
It is demonstrated that in all types of hydrogen bonds (X—H…Y) there is a balance between the long-range attractive orbital interactions and short-range Pauli/nucleus repulsions. When the proton acceptor approaches the proton donor from distance, the hydrogen bonding energy becomes more negative at relatively large distance, goes through a minimum, and then starts to become less negative when the short-range repulsive forces come into effect.Meanwhile, the X--H bond length increases at relatively large distances, goes through a maximum and starts to shorten when the short-range repulsive forces come into effect. Whether the hydrogen bond is red or blue shifted is dictated by the energy minimum position. If at the energy minimum position the X—H bond length is shorter than that for the free monomer, the hydrogen bond is blue shifted and vice versa. Further studies demonstrate that the recent report about the correlation of C—H bond lengths with proton donor-acceptor distance in F3C—H…OH2 and F3C—H…Cl^- is not fully correct because the authors conducted an inappropriate comparison. Furthermore, it is shown for the first time that the Pauli/nucleus repulsion theory is applicable to the blue-shifted hydrogen bonds in the X—H…π complexes and the blue-shifted lithium bonds in the X—Li…Y complexes. 相似文献
83.
The thermodynamic properties of proton transport along hydrogen-bonded systems at finite temperatures have been studied by our model. We first derive the dynamic equations of the proton transport and find the solutions and the free energy of the systems. Finally, we obtain the specific heats of the hydrogen bonded systems, resulting from the motion of the soliton, by using transfer integral way. The theoretical value is basically consistent with the experimental data. 相似文献
84.
新型无机离子交换剂的研究Ⅴ.偏磷酸铈的离子交换色谱法应用苏政权(广东药学院预防医学系卫生化学教研室广州510224)封惠侠(河南信阳教育学院化学系河南464000)张秀莲(广东教育学院化学系广州510303关键词离子色谱偏磷酸铈分离中图分类号O657... 相似文献
85.
Fabrication and Characterization of ZnO-Based Film Bulk Acoustic Resonator with a High Working Frequency 下载免费PDF全文
We report on the fabrication and characterization of a ZnO-based film-bulk acoustic-resonance device utilized as biosensor. The device has a multilayer structure which consists of piezoelectric element (Au/ZnO/Pt) and a Bragg-reflection-layer acoustic isolation consisting of multilayers of ZnO/Pt. Dielectric measurements have revealed that the device has a very high working frequency (up to -3.1 GHz), meaning that the device may have a higher sensitivity than the devices reported in the literature. 相似文献
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87.
Switching Characteristics of Phase Change Memory Cell Integrated with Metal-Oxide Semiconductor Field Effect Transistor 总被引:2,自引:0,他引:2 下载免费PDF全文
A Ge2Sb2Te5 based phase change memory device cell integrated with metal-oxide semiconductor field effect transistor (MOSFET) is fabricated using standard 0.18 #m complementary metM-oxide semiconductor process technology. It shows steady switching characteristics in the dc current-voltage measurement. The phase changing phenomenon from crystalline state to amorphous state with a voltage pulse altitude of 2.0 V and pulse width of 50ns is also obtained. These results show the feasibility of integrating phase change memory cell with MOSFET. 相似文献
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带延时光学双稳装置分岔点处的光放大效应 总被引:1,自引:0,他引:1
调节在倍周期分岔第一个分岔点处的带延时光学双稳装置(OBD),对与系统谐振的光学小信号具有放大作用.本文对此作了理论分析. 相似文献