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Stability and optoelectronic property of lead-free halide double perovskite Cs2B'BiI6 (B' = Li,Na and K) 下载免费PDF全文
Yunhui Liu 《中国物理 B》2021,30(10):108102-108102
Although lead-based perovskite solar cells have achieved more than 25% power conversion efficiency, the toxicity of lead and instability are still urgent problems faced in industrial application. Lead-free halide double perovskite (DP) materials are promising candidates to resolve these issues. Based on the density functional theory, we explore the geometric stability, thermodynamic stability, mechanical stability, electronic structures, and optical properties of the Cs2B'BiI6 (B' =m Li, Na and K) DP materials. By analyzing the tolerance factor and octahedral factor, we find the geometric stabilities of Cs2NaBiI6 and Cs2KBiI6 DPs are better than Cs2LiBiI6. By calculating the total energy, formation energy and decomposition energy, we propose that the most favorable structure of Cs2B'BiI6 is the orthorhombic phase, and Cs2LiBiI6 is less stable relative to the other two counterparts from an energetic viewpoint. Mechanical stability evaluations reveal that the orthorhombic Cs2LiBiI6 material is less stable relative to the isostructural Cs2NaBiI6 and Cs2KBiI6 DPs. The mechanical property calculations indicate that the Cs2B'BiI6 DPs possess good ductility, which can be used as flexible materials. Electronic structures and optical property calculations show that the orthorhombic Cs2B'BiI6 DPs have suitable band gap values, weaker exciton binding energies, and excellent optical absorption performance in the visible-light range. Based on the above comprehensive assessments, we can conclude that the orthorhombic Cs2NaBiI6 and Cs2KBiI6 DPs with good stability are promising candidates for solar cell applications. 相似文献
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The influence of the linewidth of coupling laser on the electromagnetically induced transparency (EIT) spectral width is theoretically investigated. The model to describe the EIT spectral width is based on the standard semi-classical theory. The result shows that the effect of the linewidth of coupling laser is equivalent to an additional relaxation between two ground states in the A-type configuration. A broadening linewidth of coupling laser implies the increasing relaxation between the two ground states, which will make the wider EIT spectral linewidth. 相似文献
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Observation of Electromagnetically Induced Transparency in a Zeeman—Sublevel System in Rubidium Atomic Vapour 总被引:1,自引:0,他引:1 下载免费PDF全文
We observed electromagnetically induced transparency (EIT) in a Zeeman-sublevel system using rubidium atomic vapour at the temperature of 75~C, in which the width of the EIT signal is only 0.6 MHz. Two different methods were performed to observe the EIT signal in our experiment. 相似文献
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Tunable microwave signal generation based on an Opto-DMD processor and a photonic crystal fiber 下载免费PDF全文
Frequency-tunable microwave signal generation is proposed and experimentally demonstrated with a dual-wavelength single-longitudinal-mode (SLM) erbium-doped fiber ring laser based on a digital Opto-DMD processor and four-wave mixing (FWM) in a high-nonlinear photonic crystal fiber (PCF). The high-nonlinear PCF is employed for the generation of the FWM to obtain stable and uniform dual-wavelength oscillation. Two different short passive sub-ring cavities in the main ring cavity serve as mode filters to make SLM lasing. The two lasing wavelengths are electronically selected by loading different gratings on the Opto-DMD processor controlled with a computer. The wavelength spacing can be smartly adjusted from 0.165 nm to 1.08 nm within a tuning accuracy of 0.055 nm. Two microwave signals at 17.23 GHz and 27.47 GHz are achieved. The stability of the microwave signal is discussed. The system has the ability to generate a 137.36-GHz photonic millimeter signal at room temperature. 相似文献
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We performed an experimental study on the dependence of the linewidth of electromagetically induced transparency (EIT) on the temperature of medium in a Λ-type configuration using caesium vapour. We found that the transparent window is narrowed in the EIT whose two ground levels are composed of two hyperfine levels, and broadened in the case when the two ground levels are degenerated Zeeman sublevels, as the temperature of vapour cell is increased. The explanation for the phenomena is given qualitatively. 相似文献
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We propose and theoretically analyze a plasmonic corrugated horn structure for enhanced optical transmission. It makes use of the enhancement of unidirectional propagating surface plasmon polaritons at oblique incidence. Geometric parameters such as the groove depth and width are optimized. Analysis shows that it presents a better performance than the bull's eye structure for a small number of grooves. 相似文献
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