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11.
Yunhui Liu 《中国物理 B》2021,30(10):108102-108102
Although lead-based perovskite solar cells have achieved more than 25% power conversion efficiency, the toxicity of lead and instability are still urgent problems faced in industrial application. Lead-free halide double perovskite (DP) materials are promising candidates to resolve these issues. Based on the density functional theory, we explore the geometric stability, thermodynamic stability, mechanical stability, electronic structures, and optical properties of the Cs2B'BiI6 (B' =m Li, Na and K) DP materials. By analyzing the tolerance factor and octahedral factor, we find the geometric stabilities of Cs2NaBiI6 and Cs2KBiI6 DPs are better than Cs2LiBiI6. By calculating the total energy, formation energy and decomposition energy, we propose that the most favorable structure of Cs2B'BiI6 is the orthorhombic phase, and Cs2LiBiI6 is less stable relative to the other two counterparts from an energetic viewpoint. Mechanical stability evaluations reveal that the orthorhombic Cs2LiBiI6 material is less stable relative to the isostructural Cs2NaBiI6 and Cs2KBiI6 DPs. The mechanical property calculations indicate that the Cs2B'BiI6 DPs possess good ductility, which can be used as flexible materials. Electronic structures and optical property calculations show that the orthorhombic Cs2B'BiI6 DPs have suitable band gap values, weaker exciton binding energies, and excellent optical absorption performance in the visible-light range. Based on the above comprehensive assessments, we can conclude that the orthorhombic Cs2NaBiI6 and Cs2KBiI6 DPs with good stability are promising candidates for solar cell applications. 相似文献
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完全人工光控植物生长技术的快速发展对光源的要求精益求精,发光强度高、热稳定性良好的蓝紫色荧光粉是植物生长的关键材料。本文采用固相法合成了非稀土Bi3+激活耐高温蓝紫色Zn3B2O6∶xBi3+(0≤x≤0.03)荧光粉。X射线衍射和能谱分析结果表明Bi3+成功进入Zn3B2O6基质晶格。荧光光谱观察到Zn3B2O6∶xBi3+荧光粉在430 nm(3P1~1S0)处呈现窄带蓝紫光,半峰全宽仅为56 nm,最佳Bi3+掺杂浓度为0.02。依据激发光谱峰形和寿命衰减行为,证明了Bi3+在Zn3B2O6基质中仅占据Z... 相似文献
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Observation of Electromagnetically Induced Transparency in a Zeeman—Sublevel System in Rubidium Atomic Vapour 总被引:1,自引:0,他引:1
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We observed electromagnetically induced transparency (EIT) in a Zeeman-sublevel system using rubidium atomic vapour at the temperature of 75~C, in which the width of the EIT signal is only 0.6 MHz. Two different methods were performed to observe the EIT signal in our experiment. 相似文献
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The influence of the linewidth of coupling laser on the electromagnetically induced transparency (EIT) spectral width is theoretically investigated. The model to describe the EIT spectral width is based on the standard semi-classical theory. The result shows that the effect of the linewidth of coupling laser is equivalent to an additional relaxation between two ground states in the A-type configuration. A broadening linewidth of coupling laser implies the increasing relaxation between the two ground states, which will make the wider EIT spectral linewidth. 相似文献
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Tunable microwave signal generation based on an Opto-DMD processor and a photonic crystal fiber
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Frequency-tunable microwave signal generation is proposed and experimentally demonstrated with a dual-wavelength single-longitudinal-mode (SLM) erbium-doped fiber ring laser based on a digital Opto-DMD processor and four-wave mixing (FWM) in a high-nonlinear photonic crystal fiber (PCF). The high-nonlinear PCF is employed for the generation of the FWM to obtain stable and uniform dual-wavelength oscillation. Two different short passive sub-ring cavities in the main ring cavity serve as mode filters to make SLM lasing. The two lasing wavelengths are electronically selected by loading different gratings on the Opto-DMD processor controlled with a computer. The wavelength spacing can be smartly adjusted from 0.165 nm to 1.08 nm within a tuning accuracy of 0.055 nm. Two microwave signals at 17.23 GHz and 27.47 GHz are achieved. The stability of the microwave signal is discussed. The system has the ability to generate a 137.36-GHz photonic millimeter signal at room temperature. 相似文献
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We have realized integration of evanescent wave coupled photodetector (ECPD) and multi-quantum well (MQW) semiconductor optical amplifier (SOA) on MOCVD platform by investigating butt-joint regrowth method of thick InP/InGaAsP waveguides to deep etched SOA mesas. The combination of inductively coupled plasma etching and wet chemical etching technique has been studied to define the final mesa shape before regrowth. By comparing the etching profiles of different non-selective etchants, we have obtained a controllable non-reentrant mesa shape with smooth sidewall by applying one step 2HBr:2H3PO4:K2Cr2O7 wet etching. A high growth temperature of 680 ℃ is found helpful to enhance planar regrowth. By comparing the growth morphologies and simulating optical transmission along different directions, we determined that waveguides should travel across the regrowth interface along the [110] direction. The relation between growth rate and mask design has been extensively studied and the result can provide an important guidance for future mask design and vertical alignment between the active and passive cores. ECPD-SOA integrated device has been successfully achieved by this method without further regrowth steps and provided a responsivity of 7.8 A/W. The butt-joint interface insertion loss is estimated to be 1.05 dB/interface. 相似文献
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We performed an experimental study on the dependence of the linewidth of electromagetically induced transparency (EIT) on the temperature of medium in a Λ-type configuration using caesium vapour. We found that the transparent window is narrowed in the EIT whose two ground levels are composed of two hyperfine levels, and broadened in the case when the two ground levels are degenerated Zeeman sublevels, as the temperature of vapour cell is increased. The explanation for the phenomena is given qualitatively. 相似文献
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设计了一种新型多孔压电分流超材料构型,以单、双孔元胞构型为例,研究了其带隙特性和有限周期振动传递特性,并与未开孔压电分流超材料板进行了对比分析.计算结果表明:与未开孔压电超材料相比,两种构型在低频处的压电局域共振带隙频率更低,带宽变窄,且均会在高频范围内出现额外带隙,随着孔宽δ的增大,额外带隙数量逐渐增多;对应特定的孔宽δ的两种元胞构型均产生带宽大于1kHz的超宽带隙.该构型结合了压电分流超材料和声子晶体的特点,与传统未开孔压电分流超材料相比,具备低频和高频同时抑振的特性. 相似文献
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We propose and theoretically analyze a plasmonic corrugated horn structure for enhanced optical transmission. It makes use of the enhancement of unidirectional propagating surface plasmon polaritons at oblique incidence. Geometric parameters such as the groove depth and width are optimized. Analysis shows that it presents a better performance than the bull's eye structure for a small number of grooves. 相似文献