固相萃取-高效液相色谱法同时测定牛组织中三氮脒和氯化氮氨菲啶残留

建立了固相萃取-高效液相色谱同时检测牛组织中三氮脒(DIM)和氯化氮氨菲啶(ISM)残留的分析方法。针对不同的组织样品采用不同比例的水-乙腈溶液提取药物,结合Oasis WCX固相萃取小柱净化富集。采用Spherisorb CN柱(250 mm×4.6 mm,5μm)对药物进行分离,以乙腈和0.05 mol/L甲酸铵溶液(pH 2.4)为流动相,梯度洗脱,紫外检测波长为380 nm。牛组织中DIM和ISM的检出限(S/N≥3)为0.01 mg/kg,定量限(S/N≥10)为0.025 mg/kg。牛组织中DIM和ISM在各自的线性范围内线性关系良好(r≥0.999 3)。DIM和ISM在低、中、高添加水平下的回收率为82.2%~97.6%,日内精密度和日间精密度分别为0.3%~5.2%(n=5)和1.3%~5.2%(n=15)。结果表明,建立的方法重复性好,灵敏度高,操作简便,适用于牛组织中DIM和ISM的残留检测。     

顶点代数V_(l,0)的极小生成问题

设g是有限维单李代数,是相应于g的无扭仿型Kac-Moody代数的导代数.讨论了相应于的顶点代数V_(l,0)的极小生成问题,证明了V_(l,0)作为顶点代数由a,h两个元素生成,其中a,h∈g.     

堆积的胸腺嘧啶体系光物理失活的动力学模拟

采用半经典动力学方法模拟了π堆积的胸腺嘧啶体系最低激发态的光物理失活过程.设置激光脉冲仅作用于一个胸腺嘧啶分子T,另一胸腺嘧啶分子T’保持基态.模拟发现由于T与T’之间存在π堆积相互作用,导致电荷转移,形成T带负电荷、T’带正电符的激基复合物.由于相邻分子的空间效应阻碍了激发的T分子到达圆锥相交所必需的强烈扭曲,激基复合物的寿命比单体增长.当分子间距离缩短至0.3 nm后,T分子C₅—C₆键扭曲程度最大,此时发生电荷重组,两个胸腺嘧啶分子均恢复电中性.电荷重组诱导T’分子发生畸变,并在C₅’—C₆’扭曲最大时避免相交,体系衰减至基态,T和T’分子均恢复平面构型.     

Cu(Ⅱ)、Zn(Ⅱ)Schiff碱配合物的合成及其光热性质

用5-硝基水杨醛与色氨酸缩合制备了一种Schiff碱配体,将其与过渡金属Cu(Ⅱ)、Zn(Ⅱ)进行作用合成出两种新型的配合物.采用元素分析、差热-热重、IR、UV、摩尔电导率等对配体和配合物进行了表征,并测定了化合物的荧光性质和对超氧离子的催化歧化作用.     

竞争情形下服务商质量保证策略研究

质量保证策略是服务商获取竞争力的重要手段之一。本文在考虑服务商及其竞争对手的质量承诺水平和质量承诺补偿对其服务需求影响的基础上,构建了质量承诺水平、质量承诺补偿、质量承诺水平和质量承诺补偿三种竞争情形下的博弈模型,并系统分析了不同模型下的质量保证策略。研究发现:一旦有服务商提高质量承诺水平或质量承诺补偿,在质量承诺水平竞争模型下,其他服务商可适当地降低质量承诺水平,而在质量承诺补偿竞争模型下,其他服务商会同时提高质量承诺补偿。此外,在质量承诺水平和质量承诺补偿竞争模型下,若质量承诺水平的成本系数满足一定条件,各个服务商之间会存在纳什均衡。本文对服务市场竞争情形下服务商质量保证策略的制定具有一定的实践意义。     

用相似三角形面积比证 a/b=c~2/d~2

在平面几何中,常会遇到证明关于某两条线段比等于另两条线段平方比的问题。下面介绍利用相似三角形面积比定理处理这类问题的方法。一、属于直角三角形的线段问题例1:在△AEC中,∠A=90°,AD⊥BC,DE⊥AB于E,求证BE/AE=AB~2/AC~2     

Particle-core coupling in 141Nd

High-spin states in 141Nd have been studied using in-beam γ-ray spectroscopic techniques via the 130Te(16O, 5nγ)141Nd reaction. The level scheme of 141Nd has been extended up to an excitation energy of 7614.5 kev including 12 new γ rays deexciting 15 new levels. According to particle-vibrator coupling and semi-empirical shell model calculations, the level structure of 141Nd can be well interpreted by coupling an h11/2 neutron-hole to the respective excited states in 142Nd core.     

A Numerical Study of Vortex and Precipitating Cloud Merging in Middle Latitudes

We mainly focus on the study of precipitating cloud merging associated with vortex merging. The vortex and precipitating cloud merging are simulated by the cloud resolving model from 0000 21 to 1800 23 July 2003. The results show that the model well simulates vortex circulation associated with precipitating clouds. It is also proven that the vortex merging follows the precipitating cloud merging although vortices show the spatial and temporal differences. The convection vorticity vector is introduced to describe the merging processes. Two merging cases are identified during the 42-h simulation and are studied.     

Nitrogen Adatom Diffusion on a Ga－Rich GaN （0001） Surface

The diffusion of N adatoms on a Ga-rich GaN(O001) surface has been studied using density-functional theory.The configuration of Ga adatoms on a Ga-rich GaN surface has been identified. The first adlayer Ga adatoms are on top of the terminating substrate Ga atoms, and the outmost adlayer Ga adatoms exist randomly at the T4 or H3 sites. A very different diffusivity of N adatoms on a Ga-rich GaN(0001) surface has been found. The excess Ga adatoms on a GaN(0001) surface reduce the diffusion barrier by 0.75eV and influence the migration path. It seems that bilayer Ga adatoms are helpful for N atom diffusion.