全文获取类型
收费全文 | 3668篇 |
免费 | 465篇 |
国内免费 | 819篇 |
专业分类
化学 | 2133篇 |
晶体学 | 35篇 |
力学 | 587篇 |
综合类 | 76篇 |
数学 | 404篇 |
物理学 | 1717篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2020年 | 1篇 |
2018年 | 2篇 |
2017年 | 3篇 |
2016年 | 4篇 |
2015年 | 2篇 |
2014年 | 85篇 |
2013年 | 1篇 |
2012年 | 1篇 |
2011年 | 2篇 |
2010年 | 2篇 |
2009年 | 2篇 |
2008年 | 1篇 |
2007年 | 2篇 |
2006年 | 2篇 |
2005年 | 1篇 |
2003年 | 324篇 |
2002年 | 1404篇 |
2001年 | 1190篇 |
2000年 | 367篇 |
1999年 | 289篇 |
1998年 | 227篇 |
1997年 | 60篇 |
1996年 | 115篇 |
1995年 | 170篇 |
1994年 | 112篇 |
1993年 | 151篇 |
1992年 | 107篇 |
1991年 | 92篇 |
1990年 | 125篇 |
1989年 | 104篇 |
1985年 | 1篇 |
1965年 | 1篇 |
排序方式: 共有4952条查询结果,搜索用时 31 毫秒
211.
使用射频磁控溅射方法在不同衬底温度下(ts=室温,350,500℃)于Si(001)衬底上沉积了CNx膜,并利用拉曼(Raman)光谱、傅里叶变换红外光谱(FTIR)及X射线衍射光电子能谱(XPS)对CNx膜的化学结合状态与温度的关系进行了研究。Raman光谱结果表明,随衬底温度(ts) 增加,D带向低频方向移动,G带向高频方向移动;它们的半高宽分别由375和150cm^-1减小至328和142cm^-1;ID/IG由3.76减小至2.88。FTIR谱中除无序D带(1400cm^-1)和石墨G带(1570cm^-1)外,还有-700cm^-1,~2210cm^-1(C=N),2330cm^-1(C-O)及3255-3351cm^-1(N-H)等峰。XPS测试结果表明:随衬底温度增加,N与C的物质的量比由0.49下降至0.38,sp^2(C-N)组分与sp^3(C-N)组分强度比呈增大趋势。低温(350℃)退火并未对CNx膜的化学结合状态产生较大影响;高温(900℃)退火样品则显示出较好的结晶化程度。 相似文献
212.
213.
The atom transfer radical polymerization(ARP)of (-)-menthyl methacrylatc((-)-MnMA) mediated by CuCl/bipyridine and ethy1 2-bromopropionate or 1-phenylethyl bromide in THF system has been studied.The dependence of the specific rotation on molecular weight and the CD of Poly((-)-MnMA) thus obatined was investigated. 相似文献
214.
Emulsifier-free emulsion polymerization of styrene in the presence of β-hydroxy propyl acrylate was studied.The emulsifier-free self cross linked polystyrene latex microspheres was obtained.Monomer conversion is higher than 90% when [St],[β-HPA],[KPS] is 2.66,0.228,and 5.8×10^-3mol/L respectively under 80℃ for 5h.The mono-dispersed latex particle diameter and colloidal particle concentration were given as D=0.23um,N=3.13×10^13/cm^3 by TEM analyse,The factors of influencing latex stability were discussed.Thecopolymer was characterized by IR and dissolution experiment.The apparent activation energy of polymerization and polymerization rate constant were obtained to be 78.7KJ/mol and 514.4/mol.s respectively. 相似文献
215.
216.
Ab initio valence bond method is employed to quantitatively study the concepts of ionic resonance energy and ionicity of a chemical bond in the cases of hydrides XH(X=Li,Be,B,C,N,O,F) and fluorides XF(X=Li,Be,B),By establishing the relationship between resonance and stability,and comparing the calculated ionicities with Pauling‘s earlier estimations in the above diatomic molecules,the merits of Pauling‘s classical resonance theory were demonstrated at the ab initio level. 相似文献
217.
Phosphonium or arsonium salt 1 can undergo the tandem reaction of deprotonation -oxidation-Wittig reaction with alcohol 2 in the presence of sodium hydroxide and manganese dioxide,which affords a general simplified method for the stereoselective synthesis of (E)- α-β-unsaturated esters 3. 相似文献
218.
SYNTHESIS AND STRUCTURE OF A NEW TYPE OF COORDINATION COMPOUND OF Tb(Ⅲ)WITH BENZOIC ACID 总被引:1,自引:0,他引:1
<正> The synthesis and crystal structure of a novel rare earth coordination compound are reported. [TbL3(HL)H2O]2 (HL=henzoic acid) Mr=1324. 81, triclinic, space group P1, a=9. 148(1), b=11. 4 60(2), c=13. 506(2) A ;a=112. 76(1), B=91.83(1),y=91. 99(1) ;Z=1 ;V=1303. 3(4)A3;Dc=1.69g.cm-3;F(000)= 656;u=28. 4cm-1(MoKa). The final R is 0. 024. Each rare-earth ion in the title complex is nine-coordinated by seven oxygen atoms from five benzoate groups, one benzoic acid, and one aqua molecule, forming a distorted monocapped square antiprism. 相似文献
219.
本文综述了茂型稀土金属有机配合物的研究现状和最新进展,系统地介绍了茂型稀土金属有机配合物的特征,合成,以及结构表征方法,并着重介绍了典型三茂型,二茂型,含茚基,含芴基稀土金属有机配合物的晶体结构。最后,展望其发展趋势和研究方向。 相似文献
220.
Two new isobutyltartrate monoesters,coelovirin A (1) and B(2),were isolated from the rhizomes of Coeloglossum viride (L.) Hartm. var. bracteatum (Willd.) Richter (Orchidaceae). Their structures were elucidated as (2R,3S)-2-isobutyltartrate-1-(4-β-D-glucopyranosyloxybenzyl) ester 1 and (2R,3S)-2-isobutyltartrate-4-(4-β-D-glucopranosyloxybenzyl) ester 2 on the basis of physical constants and spectroscopic methods including 2D NMR techniques. 相似文献