Transport properties and anomalous fatigue effect of Ag/Bi0.9La0.lFeO3/La0.7Sr0.3MnO3 heterostructures

The transport properties and fatigue effect of Ag/Bi0.9La0.lFeO3/La0.7Sr0.3MnO3 heterostructures are described. By examining the I-V curves, an anomalous fatigue effect was found and its influences on resistive states were studied. I-V curves combined with C-f spectra were used to directly analyze the transport properties and fatigue effect. Compared to the first I-V cycle state, this structure shows more than one order increase of resistance after 100 cycles of ＂I-V curve training＂. The redistribution of oxygen vacancies in the depletion layer of Ag/Bi0.9La0.lFeO3 is believed to be responsible for the different resistance mechanisms and tenfold magnitude drop in resistance. The resistive switching is understood to be caused by electric field-induced carrier trapping and detrapping, which changes the depletion layer thickness at the Ag/Bi0.9La0.lFeO3 interface.     

非挥发性溶质对共沸物沸点的影响

测定了 10种非挥发性溶质对甲醇 -四氢呋喃共沸物沸点的影响 .发现与共沸物平衡的气相组成因非挥发性溶质不同发生了不同的变化 ,但所有非挥发性溶质都引起共沸物沸点升高。运用热力学原理对实验结果进行了讨论 .理论分析及对分析结果的实验检验表明 ,少量非挥发性溶质总引起共沸物沸点升高是一个具有普遍意义的结论     

超空化条件下液体射流热稳定性研究

基于线性稳定性理论,建立了描述超空化条件下液体射流热稳定性的数学模型,并对数学模型及其求解方法进行了验证;在此基础上,对超空化条件下液体射流与周围气体间的温差对射流稳定性的影响进行了研究。研究结果表明,液体射流与周围气体间存在温差时,射流稳定性变差,扰动波波数范围拓宽,且拓宽的程度随温差的增加有明显加大的趋势;温度扰动对射流稳定性的影响与扰动模式关系不大;温度扰动会在一定程度上削弱超空化对射流稳定性的作用,并有可能完全抑制超空化对扰动波最大波数的作用,只有当超空化达到一定程度后,才能克服温度扰动的抑制作用,使扰动波最大波数变大。     

以水作载流的氢化物发生原子荧光光谱法测定畜禽养殖场土壤中的砷

为监测畜禽养殖场对周围土壤环境的污染程度,选择重庆市50个养殖场作为样本,对其附近的土壤进行采样分析.将新鲜的土壤样品加入适量的硝酸、盐酸、氢氟酸、高氯酸高温消解后赶酸,最后定容至50 mL,利用以水作载流的氢化物发生-原子荧光光谱仪(WC-HG-AFS)测定了其中的砷(As)含量.结果表明,在5.000～100.00...     

基于水平集方法的二维Stokes多工况流动的拓扑优化EI北大核心CSCD

本文采用水平集方法进行了多工况条件下Stokes流动问题的拓扑优化,研究了进出口边界变化对流体拓扑优化结果的影响。在拓扑优化过程中,采用无需样条参数化的重新网格划分方法来实现物理场和水平集类方程交替求解。以最小能量耗散为目标,通过对三工况条件下流动通道的拓扑优化设计,表明多工况条件下的流动拓扑优化比单工况条件下获得的拓扑优化设计结果更为合理。     

High Temperature Melting Curve of Basaltic Glass by Laser Flash Heating

Basalt is an igneous rock originating from the cooling and solidification of magma and covers approximately 70% of Earth’s surface. Basaltic glass melting in the deep Earth is a fundamental subject of research for understanding geophysics, geochemistry, and geodynamic processes. In this study, we design a laser flash heating system using two-dimensional, four-color multi-wavelength imaging radiometry to measure the basaltic glass melting temperature under high pressure conditions in diamond anvi...     

无序碳单层的电子结构及氢原子吸附的第一性原理

本研究运用第一性原理计算方法,系统地研究了无序碳单层材料不同位点的电子结构及其析氢性能.计算结果显示无序结构中的C-C键相比于石墨烯中的C-C键在26.7%的范围内有不同程度的拉伸或压缩,使得C原子电荷在-0.17～+0.16个电子范围内变化,导致部分C原子电子局域化.电子的局域化增强了C原子的化学活性,从而表现出了较强的吸附性能.我们发现H原子与C原子的键合及析氢性能与C原子间的键角相关.对于三配位的碳原子,其中三个价电子通过sp~2杂化轨道与最邻近的碳原子结合形成较强的共价键,而余下的一个p_z轨道电子可以与H原子在垂直于原子层的方向形成较弱的化学键.无序结构可以打破三个sp~2杂化轨道的对称性,进而影响p_z轨道与氢的成键.本研究在一定程度上揭示了单层无序碳材料结构-性能的构效关系,为实验上设计特定性能的无序碳功能材料提供理论指导.     

Quantum phase transitions in CePdAl probed by ultrasonic and thermoelectric measurements

CePdAl has been recently recognized as a frustrated antiferromagnetic heavy-fermion compound with a pressure- or field-tuned, extended quantum critical phase at zero temperature. Identifying characteristic signatures of the emerging quantum critical phase, which are expected to be distinct from those near a quantum critical point, remains challenging. In this work, by performing ultrasonic and thermoelectric measurements down to very low temperatures in a ³He-⁴He dilution refrigerator in the presence of magnetic field, we are able to obtain some crucial thermodynamic and thermal transport features of the quantum critical phase, including a frustration-related elastic softening detected by ultrasound and a Fermi-surface change probed by thermoelectric effect.     

考虑压力作用的煤吸附/解吸CH_4变形试验研究

气体压力是煤吸附/解吸瓦斯的重要影响因素之一。因此,在实验室通过改变压力差,进行了一次升压/降压和等梯度逐次升压/降压方式吸附/解吸试验。通过比较分析了两种吸附/解吸方式煤变形量大小,研究了两种吸附/解吸方式下煤残余变形量的变化规律。研究结果表明,等梯度逐次升压吸附煤膨胀变形量大于同一压力水一次升压吸附煤膨胀变形量,而两种解吸试验中煤收缩变形量大小关系与之相反,残余变形量大小关系与之相同;同一压力水平下,变压力梯度降压解吸好于等梯度逐次降压解吸。     

双-2-萘甲酸烷基酯的分子内类立方烷光二聚体的手性拆分

双-2-萘甲酸多亚甲基二醇酯(N-Mn-N,n=2,3,4,5)在环己烷中进行光二聚反应的效率和产物的结构明显受链节长度的影响.N-M3-N生成反式-头头和顺式-头头两种结构的类立方烷,而N-M4-N和N-M5-N高产率、高区域选择性地生成反式-头头结构的类立方烷.更有意义的是,我们利用高效液相色谱成功拆分了反式-头头结构的分子内光二聚产物.