高效液相色谱法测定萨拉沙星

采用高效液相色谱法测定了萨拉沙星。色谱柱为μ－BondapakTMC18柱（3．9mm×300mm）,流动相为V（乙腈）：V（甲醇）：V（2mmol／L磷酸,用三乙胺调pH3．5）＝30：5：65,用二极管阵列检测器检测,检测波长278nm,得到了满意的分离效果。     

Terahertz imaging using an optical frequency comb source

Optical frequency combs, which are generated by the cascade of a phase modulator and a Mach–Zehnder intensity modulator, are used as a polychromatic signal source in the terahertz imaging system to improve imaging quality. The interference effect caused by the monochromatic wave has been greatly suppressed.The required optical power in the presented system is as low as～30% of that in the system using the Er-doped fiber amplifier as a source, which can reduce cost and protect photodiodes from damage. This work provides an effective, low power consumption, low cost, and easy way to realize terahertz imaging with high quality and can be used in future security inspections.     

量子密钥分发实验中的符合测量方法

采用符合测量方法提高全光纤量子密钥分发系统的数据采集速度，寻求更高的密钥生成率。主要论述了光路中的改进和符合测量的步骤、方法以及在密钥分发实验中的应用。     

IR AND ESR STUDIES OF THE REDUCED HETEROPOLYMOLYBDOVANADOPHOS PHORIC ACIDS H_(3+n)PMo_(12-n)V_nO_(40) (n=0,2,4)

The reducibility and isotope exchange ability of different oxygen bonds (O_b, O_p, O_t) in the Keggin structure of heteropolymolybdates (H_(3+n)PMo_(12-n)V_nO_(40)) containing zero, two or four vanadium atoms as well as the changes of structure of heteropolyacids during reduction were investigated by IR, ESR and ~(18)O isotope exchange. The results obtained showed that the order in the reducibility of different oxygen bonds is O_b>>O_p≈O_t, the replacement of Mo by V affects obviously the reducibility of various oxygen bonds: O_b increases while O_p and O_t decrease. ~(18)O exchange rate of O_b, O_p, O_t is not different, comparatively speaking, the isotope exchange of oxygen of the heteropolyacids containing vanadium atoms is more difficult than PMo_(12). The ESR spectra indicate that two kinds of Mo~(5+) ions with different coordinations are present in PMo_(12) (n=0) during reducing process, their g values are g_⊥~A=1.971, g_(?)~A=1.912 and g_⊥~B=1.965, g_(?)~B=1.861 belonging respectively to the d     

Luminescence Properties of Ca4GdO（BO3）3：RE （RE=Eu^3＋,Tb^3＋） under VUV Excitation

We experimentally investigated the VUV excitation luminescence properties of Ca4 GdO(B03)3 :RE (RE=Eu^3 , Tb^3 )Ca4GdO(BO3)3:Eu3 and Ca4GdO(BO3)3:Tb^3 emitted bright red and green colour light, respectively, under 172 nm excitation, resulting from the favorable position of the host absorption band (186 nm) and efficient energy transfer from Gd^3 to activators (e.g. Eu^3 or Tb^3 ) by means of secondary absorption in the Ca4GdO(BO3)3 matrix. The f-d transitions of Eu^3 and Tb^3 in the host lattice are depicted.     

中考数学新题型评析

综观近几年各地中考数学试题 ,涌现出一批立意新 ,设计巧 ,个性独特 ,富有创意 ,发人深思的好题型 ,由于这类题型不仅有效地考查学生适应新问题 ,接受新知识 ,综合运用各学科知识 ,解决实际问题的能力 ,而且有利于改革教学、更新教学理论 .因此在中考中是一个命题热点 ,引起师生的广泛关注 .下面就以近几年各省市中考数学试题为例进行分类简析 ,以利对初三数学复习参考 .(一 )设计新情景的基础题 :例 1　 ( 2 0 0 2年北京 )根据下图的程序计算函数值 ,若输入x的值为 32 ,则输出的结果为 (　 ) .A .72 　　　B .94　　　C .92 　　　D .12…     

19F+93Nb耗散反应产物不重复截面的分析

完成了¹⁹F+⁹³Nb耗散反应产物激发函数的两次独立测量,入射束流的能量从102MeV到108MeV,步长250keV.实验结果在一些相同能量点两次测量的截面不能重复.分析表明:能量自关联函数的离散程度大约相当于随机计数率引起的离散程度的3倍;激发函数曲线相对于能量平均本底的几率分布,有大约21髎超出了标准高斯分布宽度的3倍;两次测量得到的截面之差的几率分布大约有18髎也超出了标准高斯分布宽度的3倍.可见,两次测量的¹⁹F+⁹³Nb耗散反应产物激发函数的截面不重复性具有明确的统计意义,其来源不是计数率的随机涨落.     

ISOLATION AND PROPERTIES OF MOLYBDE-NUM SERIES OF HETEROPOLY BLUE WITH KEGGIN STRUCTURE

The present paper reports the methods for preparing and isolating 8 kinds of 1:12 molyb-denum series of heteropoly blue complexes K_yH_zXMo_(22)O_(40)·nH_2O (X=Si, P, As, Ge). Theproducts were characterized by elemental analyses, potential titration, polarograms, cyclicvoltammetry, IR spectra, visible--UV spectra, X--ray powder diffraction, XPS and ~(31)P NMR.The single crystal structure of 4-electron molybdenum--silicon heteropoly blue was measuredand the positions of reduced molybdenum atoms were determined, i.e. they were located atMo(3), Mo(7), Mo(8) and Mo(10). The experimental results show that the heteropoly blueremains Keggin structure. ESR spectra of heteropoly blue solids were first studied, fromwhich it was found that the delocalization extent of 2-electron heteropoly blue and 4--electronheteropoly blue is smaller than that of 1-electron heteropoly blue. The study of thermal prop-erties shows that the thermal stability increases with the increase of the reduction extentof heteropoly blue. Th     

还原态磷钼钒杂多酸H_(3+n)PMo_(12-n)V_nO_(40)(n=0,2,4)的IR和ESR研究

本文用IR,ESR和~(18)O同位素交换研究了磷钼钒杂多酸Keggin结构中不同氧键(O_b,O_p,O_t)的可还原度和可交换性以及还原过程中杂多酸结构的变化。结果表明,氧键的可还原度按O_b>>O_p≈O_T变化,V取代Mo对不同氧键的可还原度有明显影响:O_b增大,而o_P和O_T降低。O_b,O_p,O_t同~(18)O的交换没有区別,相对地说,含钒杂多酸中的氧不如PMo_(12)中的那样易于进行同位素交换。ESR谱指出,PMo_(12)(n=0)在还原过程中生成二种配位不同的Mo~(5+)离子,g值各为此g_⊥~A=1.971,g_∥~A=1.912和g_⊥~B=1.965,g_∥~B=1.861,分别属于畸变八面体和四方锥体。V取代Mo后只有V的ESR谱,还原起始阶段形成VO~(2+)或V~(4+)(OH)配位状态。畸变八面体的g值为g⊥=1.983,g∥=1.932;最后生成含V~(4+)的畸变四面体,g∥=1.932。根据实验结果认为在气相催化反应中端氧(O_t,M=O)对还原电子起定域作用,而O_b则具有传递电子的作用。