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111.
A thorough investigation by means of X-rays has been carried out with the purpose to determine the nature of the ternary phase τ in Al-Cu-Ni alloys. In contrast with the conventional concept of alloy phase which is characterized by a definite type of crystal structure, systematic structure changes are found in the single phase field of τ which occupies quite an extensive area in the isothermal section of the phase diagram at room temperature. There are eight types of structures altogether, all derived from a basic rhombohedron with corners occupied by Al atoms and centres either occupied by the heavy atoms or remaining vacant. The basic rhombohedron is the building stone in the crystal architecture. By transforming the basic rhombohedron into a hexagonal prism in the usual way, all structures may be considered to be built up by stacking together a number of these hexagonal prisms along the triad. The transformation of one structure into another is quite systematic in the way that the number of the stacking stories in the unit cell increases according to the order 10, 11, 12, 13, 14, 15, 16, 17. The atomic arrangements in the different structures are closely related too, in the respect that they are all superstructures due to the presence of ordered vacancies in the rhombohedral centres.The principal factor controlling the formation of these structures has been fully considered. In view of the fact that the change of structure types follows closely with the content of Ni or Cu for alloys of constant Al content, the atomic size factor appears to be unimportant in the formation of these alloys. It has been shown that for alloy phases of the defect lattice type as the r-phase, the most fundamental factor is the average number of valency electrons per structural unit which is the basic rhombohedron in the present case. By assuming Hume-Rothery's valencies, the average number of valency electrons remains remarkably constant throughout the entire phase field, while the electron concentration varies with compositions. It has also been pointed out that for alloy phases where there is no unit cell change, the average number of electrons per structural unit is equivalent to the number of electrons per unit cell, and for alloy phase where there is no defect, this is in effect equivalent to the electron concentration. 相似文献
112.
大家知道,物体按其导电性能的不同,可以分成导体、絕緣休、半导体。按其磁性的不同則可分为鉄磁体、逆磁体、順磁体。对于多数的有机物质來讲,它們都是不导电的絕緣体和逆磁体、少部分的有机物质的电磁性能則与此相反,它們具有明显的半导体性能和一定的順磁性。对这部分有机物质的半导体性能的研究,早在本世紀初就已开始。但比較大量、系統、深 相似文献
113.
流动注射光纤动力学荧光法测定锰—锰—二元荧光配合物—高碘… 总被引:1,自引:1,他引:0
对二元荧光配合物作为动力学反应指示剂的可行性进行了考察,以8-羟基喹啉-5-磺酸铝高碘酸钠为指示反应,建立起流动注射光导纤维光谱技术测定痕量锰(Ⅱ)的动力学荧光分析新体系,此法线性范围为5-200ng/mL,检出了为1ng/mL锰(Ⅱ)进行11次测定的相对标准偏差为0.5%。分析速度为45样次/h。 相似文献
114.
115.
利用函数列的极限理论方法,研究函数列积分极限中积分和极限可交换次序的问题.对一致收敛的可积函数列给出积分的极限定理,对一致有界局部一致收敛函数列给出积分控制收敛定理,通过大量实例表明该理论的意义所在. 相似文献
116.
The characteristics of a nitrogen arc using a graphite cathode and a melting anode in a pilot-scale plasma furnace are investigated. The voltage is examined as a function of current and apparent plasma length. The voltage increases non-linearly with the increase of apparent plasma length, with the current fixed. The experimental data so obtained are compared with the predictions of the Bowman model for the electric arc, and with numerical simulations as well. The level of agreement between the experimental data at the melting anode and the numerical predictions confirms the suitability of the proposed the Bowman model. These characteristics are relevant to the engineering design and evaluation of a DC plasma furnace and reactor for the treatment of hazardous fly ash waste. 相似文献
117.
L-Shell X-Ray Yields and Production Cross Sections of Zr and Mo Bombarded by Slow Highly Charged Ar16+ Ions
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The L-shell x-ray yields of Zr and Mo bombarded by slow Ar16+ ions are measured. The energy of the Ar^16+ ions ranges from about 150 keV to 350 keV. The L-shell x-ray production cross sections of Zr and Mo are extracted from these yields data. The explanation of these experimental results is in the framework of the adiabatic direct- ionization and the binding energy modified BEA approximation. We consider, in the slow asymmetric collisions such as Ar and Mo/Zr, the transient united atoms (UA) are formed during the ion-surface interaction and the direct-ionization is the main mechanism for the inner-shell vacancy production. Generally, the theoretical results are in good agreement with the experimental data. 相似文献
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119.
分别将磺胺间甲氧嘧啶及磺胺噻唑与一水合乙酸铜(Ⅱ)在水(溶剂)热条件下反应,获得了其相应的金属配合物单晶。用元素分析、红外光谱、紫外光谱和X-射线单晶衍射对其结构进行了表征,结果表明两配合物均为双核化合物,中心Cu原子均采用二配位的直线型几何构型。用密度泛函理论方法对配合物进行了计算,结果表明配合物中金属Cu以+1价存在,这与晶体结构及光谱分析的结果一致,进一步的电荷布局分析结果与晶体结构中的配位情况相符,轨道密度等值面的分析推测配合物具有较好的抑菌活性。 相似文献
120.