Ramberg-Baecklund Rearrangement Approaches to the Synthesis of Natural Bibenzyls

The Ramberg-Baecklund rearrangement has been successfully utilized to convert readily available α-and α‘-hydrogen bearing substituted dibenzyl sulfones into corresponding stilbene derivatives, which is conveniently followed by hydrogenation in the presence of 10% Pd/C to afford the natural bibenzyls.     

不同孔隙率及孔径泡沫铝的力学与吸能特性研究

对三种孔径两种孔隙率共六种泡沫铝试件进行了静态压缩试验,发现对于中孔隙率材料,孔隙率对材料力学性能和吸能性能仍有明显影响:孔隙率越大,其吸能能力越强,但是屈服极限越小.孔径对材料吸能能力也有一定影响.同时,试验中还发现,对于孔隙率为55%的材料,当孔径≤1mm时,泡沫铝材料的孔径对其力学性能及吸能性能影响甚小.     

图的最大二等分问题的低秩可行方向算法

基于图的最大二等分问题的半定规划松弛模型,利用矩阵的低秩分解技巧,给出了该问题的半定规划松弛的一种低秩可行方向算法.在一定的条件下,证明了算法的收敛性.结合0.699随机扰动方法得到原问题的近似最优解.数值实验表明该方法能有效地求解图的最大二等分问题.     

Effects of non-Gaussian noise on the dynamical properties of a logistic system

The dynamical properties of a tumor cell growth system described by the logistic system with coupling between non- Gaussian and Gaussian noise terms are investigated. The effects of the nonextensive index q on the stationary properties and the transient properties are discussed, respectively. The results show that the nonextensive index q can induce the tumor cell numbers to decrease greatly in the case of q 〉 1. Moreover, the switch from the steady stable state to the extinct state is speeded up as the increases of q, and the tumor cell numbers can be more obviously restrained for a large value of q. The numerical results are found to be in basic agreement with the theoretical predictions.     

游标卡尺在测定金属杨氏模量中的应用

根据拉伸法测量金属杨氏模量的原理,利用现有的杨氏模量仪,设计了一套应用游标卡尺测定金属杨氏模量的方法。     

浅析条件概率的计算

<正>条件概率是高中数学统计与概率新增加的一部分内容,考试说明规定:了解条件概率的概念,并能解决一些简单的实际问题.但在学生学习过程中往往会产生理解错误,为此笔者就条件概率的几种情形进行分析,供同学们参考.一、利用条件概率的定义计算例1已知盒中装有3个红球、2个白球、5个黑球,它们大小形状完全相同,甲每次从中任取一个不放回,求他第一次拿到白球的条件下,第二次拿到红球的概率()     

读数显微镜在测量金属线膨胀系数中的应用

本文提出了传统光杠杆法测量金属线膨胀系数的缺点,根据金属线膨胀系数的测量原理,采用读数显微镜测量金属线膨胀系数,并做了可行性分析,在此基础上,设计出一套完整的测量金属线膨胀系数的方法.     

轴对称晶场中d3离子激发态对4A2基态自旋哈密顿参量的影响

采用完全对角化方法，讨论了三角对称和四角对称下d³离子自旋二重态和自旋四重态对基态⁴A₂(⁴F)自旋哈密顿(SH)参量(包括零场分裂(ZFS)和g因子)的影响机理. 并对影响基态SH参量的四种机理(SO机理，SS机理，SOO机理和SO-SS-SOO联合机理)进行了分析. 结果表明，自旋二重态与四重态对d³离子基态零场分裂都具有重要贡献；而基态g因子主要由四重态决定，二重态对g因子贡献很小. 此外，发现SS机理和SOO机理对基态EPR参量的贡献主要由四重态决定，二重态的影响很小.     

Al2O3:V3+晶体局域结构及其自旋哈密顿参量研究

提出了解释掺杂离子局域结构畸变的配体平面移动模型，建立了此模型下晶体微观结构与自旋哈密顿参量之间的定量关系.在考虑自旋与自旋、自旋与另一电子轨道和轨道与轨道作用等微小磁相互作用的基础上，采用全组态完全对角化方法，对Al₂O₃晶体中V³⁺的局域结构和自旋哈密顿参量进行了系统的研究.结果表明，V³⁺掺入Al₂O₃晶体后，上下配体氧平面间距离增大了0.0060 nm.从而成功地解释了Al₂O₃:V³⁺晶体的自旋哈密顿参量.在此基础上，研究了三角晶场下3d²离子自旋哈密顿参量的微观起源.研究发现，自旋三重态对自旋哈密顿参量的贡献是主要的，微小磁相互作用对自旋哈密顿参量的贡献只与自旋三重态有关.     

Noise destroys the coexistence of periodic orbits of a piecewise linear map

The effects of Gaussian white noise and Gaussian colored noise on the periodic orbits of period-5(P-5) and period-6(P-6) in their coexisting domain of a piecewise linear map are investigated numerically.The probability densities of some orbits are calculated.When the noise intensity is D = 0.0001,only the orbits of P-5 exist,and the coexisting phenomenon is destroyed.On the other hand,the self-correlation time τ of the colored noise also affects the coexisting phenomenon.When τcττc,only the orbits of P-5 appear,and the stability of the orbits of P-5 is enhanced.However,when ττc(τc and τc are critical values),only the orbits of P-6 exist,and the stability of the P-6 orbits is enhanced greatly.When ττc,the orbits of P-5 and P-6 coexist,but the stability of the P-5 orbits is enhanced and that of P-6 is weakened with τ increasing.